Liquid-crystal optical modulation element
The liquid crystal light modulator includes a first substrate ( 10 ) and a second substrate ( 20 ) disposed between two polarizers, and a pair of electrode structures ( 24, 24 ). The substrates include homeotropic alignment films ( 12 ) and ( 22 ), and at least one of the substrates has a function of aligning C-directors of liquid crystal molecules along one direction. The one direction forms an azimuth angle in the range of 35 to 55 degrees with the direction of the electric field generated by the pair of electrode structures ( 24, 24 ). A liquid crystal composition layer ( 31 ) contains a ferroelectric liquid crystal composition having a chiral smectic C phase or a liquid crystal composition that has an achiral smectic C phase and negative dielectric anisotropy. Light transmittance is modulated by the electric field generated by the electrode structures ( 24, 24 ) changing the birefringence index of the liquid crystal composition layer ( 31 ).
1. A liquid crystal light modulator, comprising:
two polarizers that have planes of polarization perpendicular to each other;
a first substrate and a second substrate disposed between the polarizers and holding a liquid crystal composition layer therebetween, the liquid crystal composition layer containing a liquid crystal composition at least one of the first and second substrates being transparent; and
a pair of electrode structures that generate an electric field generally parallel to a substrate face of said at least one of the first substrate and the second substrate,
wherein at least one of the first substrate and the second substrate has a homeotropic alignment film and has a function of aligning C-directors of liquid crystal molecules along one direction,
the one direction forms an azimuth angle in the range of 35 to 55 degrees with the direction of the electric field generated by the pair of electrode structures,
the liquid crystal composition is a liquid crystal composition having an achiral smectic C phase having a negative dielectric anisotropy, and
C-directors of liquid crystal molecules are aligned by the alignment function along the one direction at contact portions between the liquid crystal composition layer and the first substrate and between the liquid crystal composition layer and the second substrate, the C-directors of the liquid crystal molecules are parallel to each other between the first substrate and the second substrate, the C-directors of the liquid crystal molecules are aligned at an azimuth angle in the range of 35 to 55 degrees with the electric field direction generally parallel to the substrate face, and light transmittance is modulated by the electric field generated by the electrode structures changing the birefringence index of the liquid crystal composition layer.
2. The liquid crystal light modulator according to claim 1 , wherein retardation saturated due to the electric field ranges from 225 to 330 nm.
3. The liquid crystal light modulator according to claim 1 , wherein the chiral smectic C phase or the achiral smectic C phase in the liquid crystal composition layer has a substantially completely loosened helix axis in the absence of an electric field and has a layer structure parallel to the substrate face, and the C-directors of the liquid crystal molecules are aligned along the one direction.
4. The liquid crystal light modulator according to claim 1 , wherein the liquid crystal composition is the ferroelectric liquid crystal composition having the chiral smectic C phase, and the ferroelectric liquid crystal composition has a phase sequence of at least an isotropic phase, a chiral nematic phase, a smectic A phase, and the chiral smectic C phase from a high-temperature side or a phase sequence of at least an isotropic phase, a chiral nematic phase, and the chiral smectic C phase from the high-temperature side.
5. The liquid crystal light modulator according to claim 1 , wherein the liquid crystal composition is the ferroelectric liquid crystal composition having the chiral smectic C phase, and the chiral nematic phase has a helical pitch of 50 μm or more at a temperature 2° C. higher than the lower limit temperature of the chiral nematic phase, the lower limit temperature being the temperature of a phase transition from the chiral nematic phase to the smectic A phase or chiral smectic C phase during temperature decrease in the phase sequence of the ferroelectric liquid crystal composition.
6. The liquid crystal light modulator according to claim 1 , wherein the liquid crystal composition is said another liquid crystal composition, wherein the achiral smectic C phase has a phase sequence of at least an isotropic phase, a nematic phase, a smectic A phase, and the smectic C phase from a high-temperature side or a phase sequence of at least an isotropic phase, a nematic phase, and the smectic C phase from the high-temperature side.
7. The liquid crystal light modulator according to claim 1 , further comprising an optical phase compensation film.