IP Library › Granted Patent US 9,791,794
Granted Patent B2
US 9,791,794 · App. 15/052,160 · Granted Oct 17, 2017

Toner, developer, and image forming apparatus

Inventors: Junichi Watanabe (Shizuoka, JP); Kenji Yoneda (Shizuoka, JP); Kohsuke Satoh (Shizuoka, JP); Tsuneyasu Nagatomo (Shizuoka, JP); Keiji Makabe (Shizuoka, JP); Daichi Hisakuni (Shizuoka, JP)
Assignee: Ricoh Company, Ltd.
G03G9/0819G03G9/0821G03G9/0827G03G9/08755G03G9/09725
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Quick Facts
Patent No.
US 9,791,794
App. No.
15/052,160
Granted
Oct 17, 2017
Kind
B2
Abstract

A toner includes a base particle comprising a crystalline polyester resin; and an external additive which is a group of silica particles having a number-average particle diameter of from 0.01 μm to 0.11 μm on the surface of the toner. A number ratio of the silica particles having a circularity not less than 0.8 is 20% or more in the total number of the silica particles.

Claims (12)

1. A toner, comprising:

a base particle comprising a crystalline polyester resin; and

an external additive which is a group of silica particles having a number-average particle diameter of from 0.01 μm to 0.11 μm on the surface of the toner,

wherein a number ratio of the silica particles having a circularity not less than 0.8 is from 20% to 49% in the total number of the silica particles.

2. The toner of claim 1 , wherein the toner has a glass transition temperature at a first temperature rising (Tg1st) of from 20° C. to 50° C. in differential scanning calorimetry (DSC), and wherein a storage modulus of a tetrahydrofuran-insoluble matter of the toner at 100° C. [G′ (100) (tetrahydrofuran-insoluble)] is from 1.0×10 5 Pa to 1.0×10 7 Pa, and a ratio [G′ (40) (tetrahydrofuran-insoluble)]/[G′ (100) (tetrahydrofuran-insoluble)] of a storage modulus of a tetrahydrofuran-insoluble matter of the toner at 40° C. [G′ (40) (tetrahydrofuran-insoluble)] to the tetrahydrofuran-insoluble matter of the toner at 100° C. [G′ (100) (tetrahydrofuran-insoluble)] is not greater than 3.5×10.

3. The toner of claim 1 , wherein the base particle comprises an amorphous polyester resin.

4. The toner of claim 3 , wherein the amorphous polyester resin comprises an amorphous resin having at least one of a urethane bond and a urea bond.

5. The toner of claim 3 , wherein the amorphous polyester resin comprises an amorphous resin having neither a urethane bond nor a urea bond.

6. A developer comprising the toner according to claim 1 .

7. The toner of claim 1 , wherein a number ratio of the silica particles having a circularity not less than 0.8 is from 20% to 42% in the total number of the silica particles.

8. The toner of claim 1 , wherein a number ratio of the silica particles having a circularity not less than 0.8 is from 20% to 41% in the total number of the silica particles.

9. The toner of claim 1 , wherein a number ratio of the silica particles having a circularity not less than 0.8 is from 20% to 40% in the total number of the silica particles.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 24, 2016
From: WATANABE, JUNICHI; YONEDA, KENJI; SATOH, KOHSUKE; NAGATOMO, TSUNEYASU; MAKABE, KEIJI; HISAKUNI, DAICHI
To: RICOH COMPANY, LTD.
Reel/Frame 037815/0322 →
Priority Claims (1)
JP 2015-047984 · Mar 11, 2015 · national
Continuity (1)
Related Publication 20160266507A1 · Sep 15, 2016