Separator and rechargeable lithium battery including the same
Disclosed are porous substrate and a coating layer positioned on one side or both sides of the porous substrate, wherein the coating layer includes a filler (A) having an average particle diameter of about 0.3 μm to about 2 μm; and a binder (B) including an organic polymer and an inorganic particle, an organic particle, or a combination thereof, wherein an average particle diameter of each of the inorganic particle and the organic particle is about 5 nm to about 200 nm, and a rechargeable lithium battery including the separator.
1. A separator comprising:
a porous substrate, and
a coating layer on one side or both sides of the porous substrate,
wherein the coating layer comprises:
a filler (A) having an average particle diameter of about 0.3 μm to about 2 μm; and
a binder (B) comprising: an organic polymer having a glass transition temperature (T g ) of about −50° C. to about 60° C.; and an inorganic particle having an average particle diameter of about 5 nm to about 200 nm, an organic particle having an average particle diameter of about 5 nm to about 200 nm, or a combination thereof,
wherein, in the binder (B), the inorganic particle, the organic particle or the combination thereof is included in an amount of about 10 parts by weight to about 100 parts by weight based on 100 parts by weight of the organic polymer.
2. The separator of claim 1 , wherein the separator further comprises an adhesion layer on the coating layer.
3. The separator of claim 2 , wherein the adhesion layer comprises: the binder (B); an acrylate-based binder; a rubber-based binder; a diene-based binder; a styrene-based binder; or a combination thereof.
4. The separator of claim 1 , wherein the organic polymer comprises a diene-based polymer, an acrylate-based polymer, a styrene-based polymer, a urethane-based polymer, a polyolefin-based polymer, or a combination thereof.
5. The separator of claim 1 , wherein the binder (B) comprises the organic particle comprising a cross-linked polymer.
6. The separator of claim 5 , wherein the organic particle comprises cross-linked polymethyl methacrylate (PMMA).
7. The separator of claim 1 , wherein the binder (B) comprises the organic particle having a glass transition temperature of greater than or equal to about 60 ° C.
8. The separator of claim 7 , wherein the organic particle comprises polyurethane.
9. The separator of claim 1 , wherein the binder (B) comprises the inorganic particle comprising Al 2 0 3 , SiO 2 , TiO 2 , SnO 2 , CeO 2 , NiO, CaO, ZnO, MgO, ZrO 2 , Y 2 O 3 , SrTiO 3 , BaTiO 3 , Mg F 2 , Mg(OH) 2 , or a combination thereof.
10. The separator of claim 1 , wherein the binder (B) comprises an inorganic particle and an organic polymer, and
the binder (B) further comprises a binding agent to bind the inorganic particle and the organic polymer.
11. The separator of claim 10 , wherein the binding agent is included in an amount of about 0.03 parts by weight to about 10 parts by weight based on 100 parts by weight of the organic polymer.
12. The separator of claim 1 , wherein the binder (B) has a storage modulus at 40° C. of about 50 MPa to about 200 MPa, and a storage modulus at 100° C. of about 30 MPa to about 150 MPa.
13. The separator of claim 1 , wherein the filler (A) is included in an amount of about 70 wt % to about 99 wt % based on a total amount of the coating layer.
14. The separator of claim 1 , wherein the filler (A) is an inorganic compound, an organic compound, or a combination thereof.
15. A separator comprising:
a porous substrate;
a coating layer on one side or both sides of the porous substrate; and
an adhesion layer on the coating layer,
wherein the coating layer comprises:
a filler (A) having an average particle diameter of about 0.3 μm to about 2 μm; and
a binder resin, and
a binder (B) comprising: an organic polymer having a glass transition temperature (T g ) of about −50° C. to about 60° C; and an inorganic particle having an average particle diameter of about 5 nm to about 200 nm, an organic particle having an average particle diameter of about 5 nm to about 200 nm, or a combination thereof,
wherein, in the binder (B), the inorganic particle, the organic particle or the combination thereof is included in an amount of about 10 parts by weight to about 100 parts by weight based on 100 parts by weight of the organic polymer.
16. A rechargeable lithium battery comprising the separator of claim 1 .