Bituminous composition in the form of granules and method for preparing same
Disclosed is a bituminous composition in the form of granules, each granule including a core and a coating and having a mass for approximately one hundred particles of from 0.5 g to 2 g, the core including from 40 wt. % to 60 wt. % of a binder matrix; from 30 wt. % to 40 wt. % of a polymer; from 4 wt. % to 6 wt. % of a compatibilizing agent; and from 2 wt. % to 15 wt. % of an anti-adhesive filler; and the coating including an anti-sticking agent. The invention relates also to a method for preparing the composition, and to the use thereof in bitumen plants.
1. A method for preparing granules comprising a binder matrix composition, comprising the following steps:
a. providing from 40 wt. % to 60 wt. % of a binder matrix, from 30 wt. % to 40 wt. % of a polymer, from 4 wt. % to 6 wt. % of a compatibilizing agent, and from 3 wt. % to 15 wt. % of an anti-adhesive filler;
b. micronizing the polymer in the presence of the compatibilizing agent to form a preparation comprising micronized polymer having polymer particles with a diameter of from 250 μm to 1000 μm;
c. adding the binder matrix to said preparation comprising micronized polymer obtained in step b. to form a mixture comprising binder matrix;
d. adding the anti-adhesive filler to said mixture comprising binder matrix obtained in step c. to form a core;
e. formulating the core obtained in step d. to a pre-granulated product;
f. drying the pre-granulated product;
g. coating the pre-granulated product with an anti-sticking agent;
wherein step b. is carried out at a temperature of less than or equal to 60° C., and steps c. and d. are carried out at a temperature of from 130° C. to 200° C.
2. The method according to claim 1 , wherein step e. includes pressurization of from 2000 kPa to 7000 kPa.
3. The method according to claim 1 , wherein the polymer is a styrene-butadiene-styrene (SBS) copolymer.
4. The method according to claim 1 , wherein step d. further includes the addition of from 1 wt. % to 5 wt. % of a crosslinking agent.
5. The method according to claim 1 , wherein the compatibilizing agent is chosen from the group composed of a wax based on a mixture of fatty acid derivatives, a paraffin wax, a wax of vegetable origin, a wax of animal origin, or a mixture thereof.
6. The method according to claim 1 , wherein the binder matrix is chosen from the group composed of bitumen of grade 35/50, bitumen of grade 50/70, bitumen of grade 70/100, bitumen of grade 160/220, tall-oil pitch or derivatives thereof, a mixture of fatty acids or derivatives thereof, an oil of vegetable origin, an oil of animal origin, a colophony derivative, a methyl ester of a vegetable oil, or a mixture thereof.
7. The method according to claim 1 , wherein the anti-adhesive filler is chosen from the group composed of talc, zinc stearate, calcium stearate, magnesium stearate, polyethylene powder, polyethylene wax, ground silica, carbon black, or a mixture thereof.
8. The method according to claim 1 , wherein step e. includes shearing of said core in order to obtain a pre-granulated product formed by particles, said particles having a mass for approximately one hundred particles of from 0.6 g to 0.8 g.
9. The method according to claim 1 , wherein the polymer provided in step a. is in the form of grains having a size of from 1 mm to 10 mm.
10. A binder matrix composition in the form of granules, each granule comprising a core and a coating and having a mass for approximately one hundred particles of from 0.5 g to 2 g, the core comprising:
from 40 wt. % to 60 wt. % of a binder matrix;
from 30 wt. % to 40 wt. % of a polymer;
from 4 wt. % to 6 wt. % of a compatibilizing agent; and
from 2 wt. % to 15 wt. % of an anti-adhesive filler;
and the coating comprising an anti-sticking agent.
11. The composition according to claim 10 , wherein the core further comprises from 1% to 5% of a crosslinking agent.
12. A coating unit that is constructed and arranged to utilize the composition according to claim 10 .
13. A binder plant constructed and arranged to use the composition according to claim 11 .
14. The method of claim 1 , wherein step b is performed to form a preparation comprising micronized polymer having polymer particles with a diameter of from 400 μm to 600 μm.
15. The method according to claim 2 , wherein the polymer is a styrene-butadiene-styrene (SBS) copolymer.
16. The method according to claim 2 , wherein step d. further includes the addition of from 1 wt. % to 5 wt. % of a crosslinking agent.
17. The method according to claim 3 , wherein step d. further includes the addition of from 1 wt. % to 5 wt. % of a crosslinking agent.
18. The method according to claim 2 , wherein the compatibilizing agent is chosen from the group composed of a wax based on a mixture of fatty acid derivatives, a paraffin wax, a wax of vegetable origin, a wax of animal origin, or a mixture thereof.
19. The method according to claim 3 , wherein the compatibilizing agent is chosen from the group composed of a wax based on a mixture of fatty acid derivatives, a paraffin wax, a wax of vegetable origin, a wax of animal origin, or a mixture thereof.
20. The method according to claim 4 , wherein the compatibilizing agent is chosen from the group composed of a wax based on a mixture of fatty acid derivatives, a paraffin wax, a wax of vegetable origin, a wax of animal origin, or a mixture thereof.