IP Library › Granted Patent US 9,839,643
Granted Patent B2
US 9,839,643 · App. 15/317,500 · Granted Dec 12, 2017

Palladium complex with high anticancer activity

Inventors: Ceyda Içsel (Bursa, TR); Engin Ulukaya (Bursa, TR); Veysel Turan Yilmaz (Bursa, TR); Konstantinos Dimas (Larissa, GR)
Assignees: ULUDAG ÜNIVERSITESI TTO; Ceyda Içsel; Engin Ulukaya; Veysel Turan Yilmaz; Konstantinos Dimas
A61K31/555
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Quick Facts
Patent No.
US 9,839,643
App. No.
15/317,500
Granted
Dec 12, 2017
Kind
B2
Abstract

A compound of the formula in which X is an anion selected front F − , CI − , Br − , I − , NO 3 − , CH 3 COO − , CN − , SCN − , NCO − and CIO 4 groups. This formula is obtained by synthezing a [Pd(bpma)Cl]X.H 2 O complex, adding barbiturate salt to the complex and obtaining crystals of the complex.

Claims (15)

1. A compound shown in formula (I):

and the letter X is an anion selected front F − , Cl − , Br − , I − , NO 3 − , CH 3 COO − , CN − , SCN − , NCO − and CIO 4 groups, in which an oxidation number of Pd is (II) and the whole complex is +1.

2. A method for obtaining the formula (I) of claim 1 comprising:

synthesizing a [Pd(bpma)Cl]X.H 2 O complex;

obtaining a solution after addition of barbiturate salt to the [Pd(bpma)Cl]X.H 2 O complex; and

obtaining [Pd(bpma)(barb)]X.H 2 O crystals.

3. The method of claim 2 , wherein before the addition of barbiturate salt to the [Pd(bpma)Cl]X.H 2 O complex the steps of:

obtaining a solution with a reflux of water soluble silver salt in water after addition to the synthesized [Pd(bpma)Cl]X.H 2 O complex;

removing AgCl (s) precipitate from the solution; and

evaporating a remaining solution after the removal AgCl (s) precipitate.

4. The method of claim 2 , wherein the method is performed up to 60° C. temperature and for 2 hours.

5. The method of claim 2 , wherein said barbiturate salt is Na(barb).

6. The method of claim 2 , wherein said water soluble silver salt is AgNO 3 .

7. A method of treating a patient suffering from colon cancer comprising administering the compound of claim 1 .

8. The method of claim 7 , wherein said compound is applied parenterally.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2021
From: IÇSEL, CEYDA; YILMAZ, VEYSEL TURAN; DIMAS, KONSTANTINOS; ULUDAG ÜNIVERSITESI TTO; ULUKAYA, ENGIN
To: BURSA ULUDAG ÜNIVERSITESI; ISTINYE ÜNIVERSITESI
Reel/Frame 056674/0159 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2017
From: IÇSEL, CEYDA; ULUKAYA, ENGIN; YILMAZ, VEYSEL TURAN; DIMAS, KONSTANTINOS
To: ULUDAG ÜNIVERSITESI TTO; IÇSEL, CEYDA; ULUKAYA, ENGIN; YILMAZ, VEYSEL TURAN; DIMAS, KONSTANTINOS
Reel/Frame 044393/0397 →
Priority Claims (1)
TR a 2014 05244 · May 9, 2014 · national
Continuity (1)
Related Publication 20170106000A1 · Apr 20, 2017