Surface modified nanoparticles
Surface-modified nanoparticles are produced by associating ligand interactive agents with the surface of a nanoparticle. The ligand interactive agents are bound to surface modifying ligands that are tailored to impart particular solubility and/or compatibility properties. The ligand interactive agents are crosslinked via a linking/crosslinking agent, such as hexamethoxymethylmelamine or a derivative thereof. The linking/crosslinking agent may provide a binding site for binding the surface modifying ligands to the ligand interactive agents.
1. A method of functionalizing an InP/ZnS nanoparticle, comprising:
associating, in a solvent, a ligand interactive agent comprising a C 8 -C 20 fatty acid with the nanoparticle to form a mixture comprising a ligand interactive agent-nanoparticle association complex;
adding a linking/crosslinking agent comprising a melamine and a surface modifying ligand to the mixture; and
reacting the ligand interactive agent-nanoparticle association complex, the linking/crosslinking agent and the surface modifying ligand to form a functionalized nanoparticle having an outer surface comprising the surface modifying ligand.
2. The method of claim 1 , further comprising providing capping ligands on the nanoparticle and wherein associating the ligand interactive agent with the nanoparticle comprises intercalating the ligand interactive agent with the capping ligands.
3. The method of claim 1 , wherein the linking/crosslinking agent provides a binding site for binding the surface modifying ligand to the ligand interactive agent.
4. The method of claim 1 , wherein the surface modifying ligand is water soluble.
5. The method of claim 1 , wherein the surface modifying ligand comprises a polyether.
6. The method of claim 1 , wherein the surface modifying ligand is a monomethoxy polyethylene glycol.
7. The method of claim 1 , wherein the surface modifying ligand comprises a silicone.
8. The method of claim 1 , further comprising adding a catalyst to the mixture.
9. A composition comprising an InP/ZnS nanoparticle and a melamine compound.
10. The composition of claim 9 , wherein the nanoparticle further comprises:
a ligand interactive agent comprising a C 8 -C 20 fatty acid and having a first portion associated with the surface nanoparticle and a second portion bound to the melamine compound; and
at least one surface modifying ligand bound to the melamine compound.
11. The composition of claim 10 , further comprising a polar solvent.
12. The composition of claim 11 , wherein the nanoparticle has a quantum yield of greater than about 35%.
13. The composition of claim 12 , wherein the nanoparticle does not comprise cadmium.
14. The composition of claim 13 , wherein the composition is an ink.
15. The composition of claim 10 , further comprising capping ligands on the surface of the nanoparticle, wherein the first portion of the ligand interactive agent is intercalated with the capping ligands.
16. The method of claim 8 , wherein the catalyst is salicylic acid.
17. The method of claim 8 , wherein the catalyst is p-toluene sulfonic acid.