Multilayer ceramic capacitor and manufacturing method therefor
A multilayer ceramic capacitor having a multilayer ceramic element with internal electrodes opposed to each other and dielectric ceramic layers interposed therebetween, and external electrodes on a surface of the multilayer ceramic element and electrically connected to the internal electrodes. The external electrodes contain a first non-precious metal as a first conductive component, and glass containing BaO and/or SrO, where a total content of the BaO and/or the SrO is 34 mol % or more. The internal electrodes have a second non-precious metal different from the first non-precious metal included in the external electrodes. A glass layer is formed at interfacial parts between the ceramic layers and the external electrodes, and a diffusion length thereof is within a range of 1 μm to 5 μm from joint interfaces between the external electrodes and the internal electrodes at the joints.
1. A multilayer ceramic capacitor comprising:
a multilayer ceramic element having internal electrodes opposed to each other with dielectric ceramic layers interposed therebetween; and
external electrodes on a surface of the multilayer ceramic element and electrically connected to the internal electrodes, wherein:
(a) the external electrodes contain a first non-precious metal as a first conductive component; and the external electrodes contain a glass containing BaO and/or SrO, a total content of the BaO and/or the SrO is 34 mol % or more with respect to a total amount of the glass included in the external electrodes, the glass included in the external electrodes contains SiO 2 in a range of 42 mol % to 47 mol % with respect to the total amount of the glass in the external electrodes, and the glass included in the external electrodes forms a glass layer at interfaces between the dielectric ceramic layers and the external electrodes;
(b) the internal electrodes contain, as a second conductive component, a second non-precious metal different from the non-precious metal in the external electrodes; and
(c) the first non-precious metal is diffused into the internal electrodes at joints between the external electrodes and the internal electrodes, and a diffusion length thereof is within a range of 1 μm to 5 μm from joint interfaces between the external electrodes and the internal electrodes at the joints.
2. The multilayer ceramic capacitor according to claim 1 , wherein the first non-precious metal is a Cu-based material.
3. The multilayer ceramic capacitor according to claim 2 , wherein the first non-precious metal has an average particle size of 1.0 μm to 3.8 μm.
4. The multilayer ceramic capacitor according to claim 1 , wherein the first non-precious metal has an average particle size of 1.0 μm to 3.8 μm.
5. The multilayer ceramic capacitor according to claim 2 , wherein the second non-precious metal is a Ni-based material.
6. The multilayer ceramic capacitor according to claim 1 , wherein the second non-precious metal is a Ni-based material.
7. A method for manufacturing a multilayer ceramic capacitor, the method comprising:
forming external electrodes on a multilayer ceramic element having internal electrodes opposed to each other with dielectric ceramic layers interposed therebetween by applying to the multilayer ceramic element a conductive paste containing:
(a) a first non-precious metal powder of 1.0 μm to 3.8 μm in average particle size; and
(b) a glass powder containing BaO and/or SrO, where a total content of the BaO and/or the SrO is 34 mol % or more with respect to a total amount of the glass powder, and wherein the glass powder contains SiO 2 in a range of 42 mol % to 47 mol % with respect to the total amount of the glass powder; and
firing the multilayer ceramic element having the conductive paste applied thereto at 700° C. to 850° C.
8. The method for manufacturing a multilayer ceramic capacitor according to claim 7 , wherein the first non-precious metal is a Cu-based material.
9. The method for manufacturing a multilayer ceramic capacitor according to claim 8 , wherein the first non-precious metal has an average particle size of 1.0 μm to 3.8 μm.
10. The method for manufacturing a multilayer ceramic capacitor according to claim 7 , wherein the first non-precious metal has an average particle size of 1.0 μm to 3.8 μm.
11. The method for manufacturing a multilayer ceramic capacitor according to claim 8 , wherein the internal electrodes contain a second non-precious metal that is a Ni-based material.
12. The method for manufacturing a multilayer ceramic capacitor according to claim 7 , wherein the internal electrodes contain a second non-precious metal that is a Ni-based material.