Photothermal spectroscopy with hollow-core optical fiber
The present invention provides a gas measuring method based on photothermal effect in hollow-core optical fiber comprising: filling a target gas into the core of a hollow-core optical fiber; coupling a probe light and a periodically modulated pump light into the hollow-core optical fiber; absorbing the pump light by the target gas resulting in the periodic modulation of the phase of the probe light; demodulating the phase modulation information of the probe light to obtain the concentration of the target gas, wherein the pump laser is wavelength and/or amplitude modulated. In the present invention, two lasers including a pump laser and a probe laser are used for the measurement, this approach is simple and practical. Also, the use of the hollow-core optical fiber with extremely-small core area greatly increases the optical power density, thus enhances the strength of the detected photothermal signal; this method allows ppb level gas measurement with high selectivity, and is universally suitable for the detection of gases with absorption in near-infrared.
1. A gas measuring method based on photothermal effect in hollow-core optical fiber, comprising the following steps:
filling a target gas into the core of a hollow-core optical fiber;
coupling a probe light and a periodically modulated pump light into the hollow-core optical fiber;
absorbing the modulated pump light by the target gas to generate a photothermal excitation effect resulting in the periodic modulation of the phase of the probe light;
demodulating the phase modulation information of the probe light to obtain the concentration of the target gas;
wherein the periodic modulation of the pump laser is wavelength and/or amplitude modulation,
wherein the probe light is a pulsed light,
wherein the obtained concentration of the target gas is a distributed gas concentration along the length of the hollow-core optical fiber, and
wherein demodulating the phase modulation information of the probe light comprises demodulating the phase modulation information of the back scattered pulsed probe light in the hollow-core optical fiber.
2. The gas measuring method based on photothermal effect in hollow-core optical fiber of claim 1 , wherein demodulating the phase modulation information of a back scattered pulsed probe light in the hollow-core optical fiber comprises the steps of:
combining the phase-modulated back scattered probe light with the unmodulated probe light to obtain an interference light, and
obtaining phase changes of the back scattered light distributed along the length of the hollow-core optical fiber by demodulating the signal generated by a beat frequency of the interference light, to obtain the distributed concentration information of the target gas along the length of the optical fiber.
3. The gas measuring method based on photothermal effect in hollow-core optical fiber of claim 2 , wherein the probe light comprises a first part and a second part;
wherein the first part is a frequency-shifted pulsed light generated by an acousto-optic modulator, and
wherein the second part serves as an unmodulated probe light which interferes with the phase-modulated back scattered probe light.