Positive active material for rechargeable lithium battery and rechargeable lithium battery including same
The positive active material for a rechargeable lithium battery includes a composite material of a microporous carbon-based material and a lithium composite compound and a carbon layer on the surface of the composite material.
1. A positive active material for a rechargeable lithium battery, comprising:
a composite material comprised of a microporous carbon-based material and a lithium composite compound formed by agglomerating the microporous carbon-based material and the lithium composite compound wherein the composite material comprises secondary particles comprising smaller primary particles of the microporous carbon-based material and the lithium composite compound agglomerated together, and the primary particles have an average particle size (D50) of 1 micrometer or less; and
a carbon layer disposed partially or entirely on the surface of the secondary particles of the composite material, wherein
the microporous carbon-based material comprises one of activated carbon, carbide derived carbon (CDC), expanded carbon, expanded graphite and a combination thereof, has an average particle size (D50) ranging from 100 nm or more and less than 1 μm, and has a specific surface area ranging from 50 m 2 /g to 3000 m 2 /g;
the lithium composite compound comprising Li a A 1-b X b D 2 (0.90≦a≦1.8, 0≦b≦0.5); Li a A 1-b X b O 2-c D c (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05); Li a E 1-b X b O 2-c D c (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05); Li a E 2-b X b O 4-c D c (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05); Li a Ni 1-b-c Co b X c D α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.5, 0<α≦2); Li a Ni 1-b-c Co b X c O 2-α T α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni 1-b-c Co b X c O 2-α T 2 (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni 1-b-c Mn b X c D α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α≦2); Li a Ni 1-b-c Mn b X c O 2-α T α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni 1-b-c Mn b X c O 2-α T 2 (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni b E c G d O 2 (0.90≦a≦1.8, 0≦b≦0.9, 0≦c≦0.5, 0.001≦d≦0.1); Li a Ni b Co b Mn d G e O 2 (0.90≦a≦1.8, 0≦b≦0.9, 0≦c≦0.5, 0≦d≦0.5, 0.001≦e≦0.1); Li a NiG b O 2 (0.90≦a≦1.8, 0.001≦b≦0.1) Li a CoG b O 2 (0.90≦a≦1.8, 0.001≦b≦0.1); Li a MnG b O 2 (0.90≦a≦1.8, 0.001≦b≦0.1); Li a Mn 2 G b O 4 (0.90≦a≦1.8, 0.001≦b≦0.1); Li a Mn 1-g G g PO 4 (0.90≦a≦1.8, 0<g≦0.5); wherein A in the above formulae being selected from the group consisting of Ni, Co, Mn, and a combination thereof; X in the above formulae being selected from the group consisting of Al, Ni, Mn, Cr, Fe, Mg, Sr, V, a rare earth element, and a combination thereof; D in the above formulae being selected from the group consisting of O, F, S, P, and a combination thereof; E in the above formulae being selected from the group consisting of Co, Mn, and a combination thereof; T in the above formulae being selected from the group consisting of F, S, P, and a combination thereof; G in the above formulae being selected from the group consisting of Al, Cr, Mn, Fe, Mg, La, Ce, Sr, V, and a combination thereof;
the lithium composite compound and the microporous carbon-based material is mixed in a ratio ranging from 99:1 wt % to 70:30 wt %; and
the carbon layer is about 1 nm to about 500 nm thick.
2. The positive active material of claim 1 , the lithium composite compound having an average particle size (D50) ranging from 100 nm to 1 μm.
3. The positive active material of claim 1 , the positive active material further comprising a conductive material.
4. The positive active material of claim 3 , the conductive material being one of carbon black, carbon nanotubes, carbon nanofiber, vapor-grown carbon fiber (VGCF), carbon powder, graphite powder and a combination thereof.
5. The positive active material of claim 3 , the conductive material being in an amount of 1 to 5 parts by weight based on 100 parts by weight of the composite material.
6. A rechargeable lithium battery comprising:
a negative electrode comprising a negative active material;
a positive electrode comprising a positive active material comprising a composite material comprised of a microporous carbon-based material and a lithium composite compound formed by agglomerating the microporous carbon-based material and the lithium composite compound wherein the composite material comprises secondary particles comprising smaller primary particles of the microporous carbon-based material and the lithium composite compound agglomerated together, and the primary particles have an average particle size (D50) of 1 micrometer or less; and a carbon layer partially or entirely disposed partially or entirely on the surface of the secondary particles of the composite material; and
a non-aqueous electrolyte, wherein
the microporous carbon-based material comprises one of activated carbon, carbide derived carbon (CDC), expanded carbon, expanded graphite and a combination thereof, has an average particle size (D50) ranging from 100 nm or more and less than 1 μm, and has a specific surface area ranging from 50 m 2 /g to 3000 m 2 /g;
the lithium composite compound comprising Li a A 1-b X b D 2 (0.90≦a≦1.8, 0≦b≦0.5); Li a A 1-b X b O 2-c D c (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05); Li a E 1-b X b O 2-c D c (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05); Li a E 2-b X b O 4-c D c (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05); Li a Ni 1-b-c Co b X c D α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.5, 0<α≦2); Li a Ni 1-b-c Co b X c O 2-α T α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni 1-b-c Co b X c O 2-α T 2 (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni 1-b-c Mn b X c D α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α≦2); Li a Ni 1-b-c Mn b X c O 2-α T α (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni 1-b-c Mn b X c O 2-α T 2 (0.90≦a≦1.8, 0≦b≦0.5, 0≦c≦0.05, 0<α<2); Li a Ni b E c G d O 2 (0.90≦a≦1.8, 0≦b≦0.9, 0≦c≦0.5, 0.001≦d≦0.1); Li a Ni b Co b Mn d G e O 2 (0.90≦a≦1.8, 0≦b≦0.9, 0≦c≦0.5, 0≦d≦0.5, 0.001≦e≦0.1); Li a NiG b O 2 (0.90≦a≦1.8, 0.001≦b≦0.1) Li a CoG b O 2 (0.90≦a≦1.8, 0.001≦b≦0.1); Li a MnG b O 2 (0.90≦a≦1.8, 0.001≦b≦0.1); Li a Mn 2 G b O 4 (0.90≦a≦1.8, 0.001≦b≦0.1); Li a Mn 1-g G g PO 4 (0.90≦a≦1.8, 0<g≦0.5); wherein A in the above formulae being selected from the group consisting of Ni, Co, Mn, and a combination thereof; X in the above formulae being selected from the group consisting of Al, Ni, Mn, Cr, Fe, Mg, Sr, V, a rare earth element, and a combination thereof; D in the above formulae being selected from the group consisting of O, F, S, P, and a combination thereof; E in the above formulae being selected from the group consisting of Co, Mn, and a combination thereof; T in the above formulae being selected from the group consisting of F, S, P, and a combination thereof; G in the above formulae being selected from the group consisting of Al, Cr, Mn, Fe, Mg, La, Ce, Sr, V, and a combination thereof;
the lithium composite compound and the microporous carbon-based material being mixed in a ratio ranging from 51:49 wt % to 99:1 wt %; and
the carbon layer is about 1 nm to about 500 nm thick.
7. The rechargeable lithium battery of claim 6 , the lithium composite compound having an average particle size (D50) ranging from 100 nm to 1 μm.
8. The rechargeable lithium battery of claim 6 , the positive active material further comprising a conductive material.
9. The rechargeable lithium battery of claim 8 , the conductive material being one of carbon black, carbon nanotubes, carbon nanofiber, vapor grown carbon fiber (VGCF), carbon powder, graphite powder and a combination thereof.
10. The rechargeable lithium battery of claim 8 , the conductive material being comprised in an amount of 1 to 5 parts by weight based on 100 parts by weight of the composite material.