(Meth)acrylate-based resin composition having excellent impact resistance and transparency
Disclosed is a (meth)acrylate-based resin composition comprising a poly(alkyl(meth)acrylate-phenyl(meth)acrylate) copolymer comprising phenyl(meth)acrylate having excellent surface hardness and a high refractive index, as a base resin and a (conjugated diene (meth)acrylate) graft copolymer having excellent impact absorption efficiency, the (meth)acrylate-based resin composition providing excellent transparency by exhibiting excellent impact resistance even using a small amount of impact modifier. The (meth)acrylate-based resin composition having excellent impact resistance and transparency comprises 1 to 29 wt % of the (conjugated diene-(meth)acrylate) graft copolymer and 71 to 99 wt % of the poly(alkyl(meth)acrylate-phenyl(meth)acrylate) copolymer.
1. A (meth)acrylate-based resin composition, comprising:
90 to 95 wt % of a poly(alkyl(meth)acrylate-phenyl(meth)acrylate) copolymer; and
5 to 10 wt % of a conjugated diene based polymer.
2. The (meth)acrylate-based resin composition according to claim 1 , wherein the conjugated diene based polymer is selected from the group consisting of conjugated diene based graft copolymer, styrene-butadiene-styrene block copolymer, and a mixture thereof.
3. The (meth)acrylate-based resin composition according to claim 1 , wherein an alkyl group of alkyl(meth)acrylate of the poly(alkyl(meth)acrylate-phenyl(meth)acrylate) copolymer is a C1 to C5 alkyl group.
4. The (meth)acrylate-based resin composition according to claim 1 , wherein alkyl(meth)acrylate of the poly(alkyl(meth)acrylate-phenyl(meth)acrylate) copolymer is selected from the group consisting of methylacrylate, ethylacrylate, methylmethacrylate, ethylmethacrylate, methylethacrylate, ethylethacrylate, propylacrylate, isopropylacrylate, butylacrylate, propylmethacrylate, isopropylmethacrylate, butylmethacrylate, isobutylmethacrylate, and a mixture of two or more thereof.
5. The (meth)acrylate-based resin composition according to claim 1 , wherein a weight ratio of alkyl(meth)acrylate:phenyl(meth)acrylate in the poly(alkyl(meth)acrylate-phenyl(meth)acrylate) copolymer is 10 to 90:90 to 10.
6. The (meth)acrylate-based resin composition according to claim 2 , wherein the conjugated diene based polymer has a refractive index of 1.5150 to 1.5160.
7. The (meth)acrylate-based resin composition according to claim 2 , wherein the conjugated diene based graft copolymer is an ABS based graft copolymer comprising rubber latex as a core.
8. The (meth)acrylate-based resin composition according to claim 7 , wherein the conjugated diene based rubber latex as a core is obtained by emulsion polymerizing a conjugated diene based monomer, or a mixture of a conjugated diene based monomer and vinyl aromatic monomer, in the presence of an emulsifier.
9. The (meth)acrylate-based resin composition according to claim 8 , wherein the conjugated diene based monomer is selected from the group consisting of 1,3-butadiene, isoprene, chloroprene, or a mixture of two or more thereof.
10. The (meth)acrylate-based resin composition according to claim 8 , wherein the vinyl aromatic monomer is selected from the group consisting of styrene, α-methylstyrene, vinyl toluene, α-chlorostyrene, o-methyl styrene, dichlorostyrene, vinylnaphthalene, and a mixture of two or more thereof.
11. The (meth)acrylate-based resin composition according to claim 8 , wherein, in the mixture of the conjugated diene based monomer and vinyl aromatic monomer, a mix ratio of the conjugated diene based monomer:vinyl aromatic monomer is 70 to 95:5 to 30 in parts by weight.
12. The (meth)acrylate-based resin composition according to claim 1 , wherein the conjugated diene based polymer includes a styrene-butadiene-styrene copolymer.