Method for producing a marking
The present invention relates to a method for producing a marking in a coating on a substrate or on the surface of a molding, where the marking represents a negative marking within a luminescent surrounding field and is generated using a laser beam, to a marking produced with the aid of the method, and to the use thereof, in particular for the labeling of products.
1. A method for producing a marking on a surface of a moulding or a coating located on a substrate, each of which comprises luminescent particles, comprising bringing said surface or coating into contact with a laser beam, wherein the particles on area units of the surface or coating which are contacted by the laser beam are changed in such a way that their luminescence capability is destroyed, wherein the luminescent particles are included in a non-luminescent, inorganic matrix, which is in the form of pigments in the moulding or coating, and wherein the inorganic matrix comprises dielectric metal oxides and/or metal oxide hydrates.
2. The method according to claim 1 , wherein the dielectric metal oxides are Al 2 O 3 , SiO 2 , silicon dioxide hydrate, aluminium oxide hydrate or mixtures of two or more thereof.
3. The method according to claim 1 , wherein the inorganic matrix is in the form of a flake-form pigment.
4. The method according to claim 1 , wherein the pigment comprises one or more luminescent particles having a primary particle size of ≦500 nm.
5. The method according to claim 4 , wherein the pigment comprises luminescent particles which have a particle size of ≦1 μm.
6. The method according to claim 1 , wherein the luminescent particles are stimulated to luminescence in the UV wavelength region and emit visible light.
7. The method according to claim 1 , wherein the luminescent particles consist of inorganic materials.
8. The method according to claim 6 , wherein the luminescent particles consist of doped or undoped metal oxides, doped metal sulfides, metal selenides, metal oxysulfides of the lanthanides or fluorescent mixed oxides, or of mixtures of two or more thereof.
9. The method according to claim 1 , wherein the moulding consists of polymeric material.
10. The method according to claim 1 , wherein the substrate consists of a polymeric material, a cellulose-containing material, glass, ceramic or metal.
11. The method according to claim 1 , wherein the coating comprises a binder.
12. The method according to claim 1 , wherein the coating is applied to the substrate in the form of a printing ink and solidified.
13. A marking on the surface of a moulding or of a coating located on a substrate which has a non-luminescent structure within a luminescent area unit, produced by the method according to claim 1 .
14. The marking according to claim 13 , wherein the luminescent area unit is stimulated to luminescence under the action of electromagnetic radiation in the UV wavelength region and emits light in the visible wavelength region.
15. The marking according to claim 13 , wherein the non-luminescent structure is an alphanumeric symbol or a sequence of alphanumeric symbols, a logo, a symbol, a pattern, a graphical element, a picture, a line structure, a bar code or a data matrix code.
16. A labelling of a product comprising a marking on the surface of a moulding or of a coating located on a substrate according to claim 13 .
17. The labelling of a product according to claim 16 , wherein the products are consumer goods, industrial goods, electronic articles, clothing, packaging materials or security products.
18. A method for producing a marking on a surface of a moulding or a coating located on a substrate, each of which comprises luminescent particles, comprising bringing said surface or coating into contact with a laser beam, wherein the particles on area units of the surface or coating which are contacted by the laser beam are changed in such a way that their luminescence capability is destroyed, wherein the luminescent particles are included in a non-luminescent, inorganic matrix, which is in the form of pigments in the moulding or coating, and wherein at least one of the following is satisfied:
the inorganic matrix is in the form of a flake-form pigment, or
the luminescent particles consist of inorganic materials, or
the luminescent particles are stimulated to luminescence in the UV wavelength region and emit visible light, and said luminescent particles consist of doped or undoped metal oxides, doped metal sulfides, metal selenides, metal oxysulfides of the lanthanides or fluorescent mixed oxides, or of mixtures of two or more thereof, or
the coating is applied to the substrate in the form of a printing ink and solidified.
19. A marking on the surface of a moulding or of a coating located on a substrate which has a non-luminescent structure within a luminescent area unit, produced by the method according to claim 18 .
20. A labelling of a product comprising a marking on the surface of a moulding or of a coating located on a substrate according to claim 19 .