Optical compensation film, method of manufacturing the same, and liquid crystal display provided with the same
Disclosed is an optical compensation film including a supporter, and an optical compensation layer disposed on at least one surface of the supporter and including a polymer of cholesteric liquid crystal molecules having a structure in which a plurality of parallel-arranged liquid crystal molecules are helically arranged, wherein the cholesteric liquid crystal layer has a helical axis that is bent and tilted to the supporter at an angle represented by the following Equation 1; a method of manufacturing the same; and a liquid crystal device (LCD) including the optical compensation film. H =(θ T −θ B )*( d′/d ) γ +θ B [Equation 1] In Equation 1, H is a tilt angle of the helical axis of a layer of the cholesteric liquid crystal molecules; θ B is a tilt angle of liquid crystal molecule contact with the supporter; θ T is a tilt angle of a liquid crystal molecule disposed at a part of the layer furthest from the supporter; d is a thickness of the layer; d′ is a distance from the supporter along a vertical direction; γ is a degree of variation in tilt angle of helical axis; and γ≧0.01.
1. An optical compensation film comprising:
a supporter; and
an optical compensation layer disposed on at least one surface of the supporter and comprising a polymer of cholesteric liquid crystal molecules having a helical structure, wherein a helical axis of the cholesteric liquid crystal molecules is bent and tilted with respect to the supporter at an angle represented by the following Equation 1:
H =(θ T−θB )*( d′/d )γ+θ B [Equation 1]
and wherein a plurality of cholesteric liquid crystalline molecules are arranged in a helical shape to form a segment; wherein each segment comprises the plurality of cholesteric liquid crystalline molecules that undergo one helical rotation; and wherein the cholesteric liquid crystalline molecules have different segments that have different orientations with respect to the supporter; wherein, in Equation 1, H is a tilt angle of the helical axis of a layer of the cholesteric liquid crystal molecules; θB is a tilt angle of a cholesteric liquid crystal molecule in contact with the supporter; θT is a tilt angle of a cholesteric liquid crystal molecule disposed at a part of the layer furthest from the supporter; wherein θB and θT are not equal to each other and wherein θB and θT are both greater than zero; d is a thickness of the layer; d′ is a distance from the supporter to a part of the layer along a vertical direction; γ is a degree of variation in tilt angle of the helical axis; and γ≧0.01.
2. The optical compensation film of claim 1 , wherein γ is in the range of about 0.01≦γ≦about 100.
3. The optical compensation film of claim 2 , wherein θT is about 80 degrees or less.
4. The optical compensation film of claim 2 , wherein θB is about 120 degrees or less.
5. The optical compensation film of claim 1 , further comprising an alignment layer disposed between the supporter and the optical compensation layer.
6. A liquid crystal display comprising:
a liquid crystal display panel comprising:
a first display panel;
a second display panel; and
a liquid crystal layer interposed between the first display panel and the second display panel; and
an optical compensation film mounted on at least one surface of the liquid crystal display panel,
wherein the optical compensation film comprises:
a supporter, and
an optical compensation layer disposed on at least one surface of the supporter and comprising a polymer of cholesteric liquid crystal molecules having a helical structure,
wherein a helical axis of the cholesteric liquid crystal molecules is bent and tilted with respect to the supporter at an angle represented by the following Equation 1:
H =(θ T−θB )*( d′/d )γ+θ B [Equation 1]
and wherein a plurality of cholesteric liquid crystalline molecules having the helical structure form a segment; wherein each segment comprises the plurality of cholesteric liquid crystalline molecules that undergo one helical rotation; and wherein the cholesteric liquid crystalline molecules have different segments that have different orientations with respect to the supporter; wherein, in Equation 1, H is a tilt angle of the helical axis of a layer of the cholesteric liquid crystal molecules; θB is a tilt angle of a liquid crystal molecule in contact with the supporter; θT is a tilt angle of a liquid crystal molecules disposed at a part of the layer furthest from the supporter; wherein θB and θT are not equal to each other and wherein θB and θT are both greater than zero; d is a thickness of the layer; d′ is a distance from the supporter to a part of the layer along a vertical direction; γ is a degree of variation in tilt angle of the helical axis; and γ≧0.01.
7. The liquid crystal display of claim 6 , wherein the γ is in the range of about 0.01≦γ≦about 100.
8. The liquid crystal display of claim 7 , wherein θT is about 80 degrees or less.
9. The liquid crystal display of claim 7 , wherein θB is about 120 degrees or less.
10. The liquid crystal display of claim 6 , wherein the liquid crystal display panel is a TN mode liquid crystal display panel.