Polymer compound, material for organic electroluminescence element using same, and organic electroluminescence element

1. A polymer compound comprising repeating units represented by formula (1-1) or (1-2) and repeating units represented by formula (3):

wherein:

each of R 1 to R 6 independently represents a linear or branched alkyl group having 1 to 20 carbon atoms, a linear or branched alkoxy group having 1 to 20 carbon atoms, a linear or branched alkylthio group having 1 to 20 carbon atoms, a linear or branched alkenyl group having 2 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 30 ring carbon atoms, or a heteroaryl group having 5 to 30 ring atoms;

each of a and b represents an integer of 0 to 4;

each of c and d represents an integer of 0 to 3; and

each of Ar 1 , Ar 2 , Ar 3 , and Ar 4 independently represents a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heteroaryl group having 5 to 30 ring atoms,

wherein:

each of R 7 , R 8 , R 9 , and R 10 independently represents a linear or branched alkyl group having 1 to 20 carbon atoms, a linear or branched alkenyl group having 2 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 30 ring carbon atoms, or a heteroaryl group having 5 to 30 ring atoms;

R 9 and R 10 may be bonded to each other to form a hydrocarbon ring;

each of e and f represents an integer of 0 to 3, and when e or f is 2, adjacent groups R 9 or adjacent groups R 10 may be bonded to each other to form a hydrocarbon ring; and

at least one selected from the group consisting of R 7 , R 8 , R 9 , and R 10 has a substituent comprising a polymerizable functional group.

2. The polymer compound according to claim 1 , wherein each of R 1 to R 6 represents a linear or branched alkyl group having 1 to 20 carbon atoms, a linear or branched alkenyl group having 2 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 30 ring carbon atoms, or a heteroaryl group having 5 to 30 ring atoms.

3. The polymer compound according to claim 1 , wherein each of R 1 to R 6 represents a linear or branched alkyl group having 1 to 20 carbon atoms, a linear or branched alkoxy group having 1 to 20 carbon atoms, a linear or branched alkylthio group having 1 to 20 carbon atoms, a linear or branched alkenyl group having 2 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 24 ring carbon atoms, or a heteroaryl group having 5 to 24 ring atoms.

4. The polymer compound according to claim 1 , wherein each of R 1 to R 6 represents a linear or branched alkyl group having 1 to 20 carbon atoms, a linear or branched alkenyl group having 2 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 24 ring carbon atoms, or a heteroaryl group having 5 to 24 ring atoms.

5. The polymer compound according to claim 1 , wherein each of Ar 1 , Ar 2 , Ar 3 , and Ar 4 independently represents a substituted or unsubstituted aryl group having 6 to 24 ring carbon atoms or a substituted or unsubstituted heteroaryl group having 5 to 24 ring atoms.

6. The polymer compound according to claim 1 , wherein the polymer compound further comprises repeating units represented by formula (2):

Ar 5   (2)

wherein Ar 5 represents an arylene group having 6 to 24 ring carbon atoms or a heteroarylene group having 5 to 24 ring atoms.

7. The polymer compound according to claim 1 , wherein the group comprising a polymerizable functional group is:

a group represented by formula (i):

 wherein:

each of R 11 , R 12 , and R 13 independently represents a hydrogen atom, a fluorine atom, a linear or branched alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms;

L 11 represents a divalent linking group; and

n represents 0 or 1, provided that when n is 0, L 11 is a single bond;

a group represented by formula (ii):

wherein L 12 represents a divalent linking group and n represents 0 or 1,

provided that when n is 0, L 12 is a single bond;

a group represented by formula (iii):

wherein L 13 represents a divalent linking group and n represents 0 or 1,

provided that when n is 0, L 13 is a single bond;

a group represented by formula (iv):

wherein L 14 represents a divalent linking group and n represents 0 or 1,

provided that when n is 0, L 14 is a single bond;

a group represented by formula (v):

 wherein:

R 14 represents a hydrogen atom, a substituted or unsubstituted linear or branched alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms;

L 15 represents a divalent linking group; and

n represents 0 or 1, provided that when n is 0, L 15 is a single bond; or

a group other than the group represented by any of formulae (i) to (v), which comprises a ring-forming or ring-opening polymerizable functional group selected from the group consisting of a group comprising a substituted or unsubstituted norbornene skeleton, a group comprising a substituted or unsubstituted epoxy group or oxetane group, a group comprising a lactone structure or a lactam structure, a cyclooctatetraene group, a 1,5-cyclooctadiene group, a 1,ω-diene group, an o-divinylbenzene group, and a 1,ω-diyne group.

8. A material for organic electroluminescence devices comprising the polymer compound according to claim 1 .

9. An organic electroluminescence device which comprises at least one layer between a pair of electrodes and the at least one layer comprises at least one polymer compound according to claim 1 .

10. The organic electroluminescence device according to claim 9 , wherein the layer comprising the polymer compound is a charge injection transport layer.

11. The organic electroluminescence device according to claim 10 , wherein the charge injection transport layer is a hole injection transport layer.

12. The organic electroluminescence device according to claim 9 , wherein the organic electroluminescence device comprises a light emitting layer between the pair of electrodes, and the light emitting layer comprises a light emitting compound other than the polymer compound.

13. The organic electroluminescence device according to claim 9 , wherein the organic electroluminescence device comprises an electron injection transport layer between the pair of electrodes, and the electron injection transport layer comprises an electron injecting compound other than the polymer compound.