Alternative additives to enhance slurry dewatering
The invention provides methods and compositions for improving dewatering of mineral slurry. The method comprises adding an R-Succinic Compound (such as octadecenyl succinic acid, hexadecenyl succinic acid, and/or dodecenyl succinic acid) to the slurry. The R-Succinic Compound removes water that would otherwise be trapped within the filtered slurry cake.
1. A method of enhancing dewatering of a mineral bearing slurry in a dewatering step of a mineral processing application, the method comprising:
adding a wash fluid to the mineral bearing slurry; and
adding to the mineral bearing slurry or to the wash fluid a composition comprising at least one R-succinic compound having a structure selected from formula (I) or formula (II), a conjugate acid-base of the R-succinic compound having the structure selected from formula (I) or formula (II), an anhydride of the R-succinic compound having the structure selected from formula (I) or formula (II), or any combination thereof, wherein formula (I) is
and
wherein R and R′ are independent, distinct, and represent alkyl, alkenyl, or aromatic hydrocarbon groups containing 1-30 carbon atoms.
2. The method of claim 1 in which the R-succinic compound is selected from the list consisting of: octadecenyl succinic acid, hexadecenyl succinic acid, dodecenyl succinic acid, and any combination thereof.
3. The method of claim 1 in which the composition further comprises a base.
4. The method of claim 1 in which the composition is used within a filtration process.
5. The method of claim 1 in which the R-succinic compound forms in situ within the mineral bearing slurry or the wash fluid.
6. The method of claim 1 in which the R-succinic compound is in one form selected from the group consisting of: an anhydride form, an acid form, a salt form, and any combination thereof.
7. The method of claim 1 in which the mineral bearing slurry contains one or more minerals selected from the group consisting of: metals, non-metals, zinc, tin, aluminum, coal, iron, copper, gold, silver, rare earth metals, diamonds, sulfur, noble metals, ferrous minerals, cobalt, nickel, lithium, metal sulfides, metal oxides, lead, molybdenum, cadmium, cobalt, sulfides, oxides, pyrites, hydrates, chromium, manganese, lime, calcium, carbonates, solids, and any combination thereof.
8. The method of claim 1 in which the dewatering step includes:
using dewatering screens, sedimentation, filtering, thermal drying, suction drying, vacuum drying, or any combination thereof.
9. The method of claim 1 in which the dewatering step is upstream from one stage of the mineral processing application selected from the group consisting of:
adsorption, centrifugation, cyclonic separation, density based separation, chromatography, crystallization, decantation, distillation, drying, electrophoresis, elutriation, evaporation, extraction,leaching extraction, liquid-liquid extraction, solid phase extraction, flotation, dissolved air flotation, froth flotation, flocculation, filtration, mesh filtration, membrane filtration, microfiltration, ultrafiltration, nanofiltration, reverse osmosis, fractional distillation, fractional freezing, magnetic separation, precipitation, recrystallization, sedimentation, gravity separation, sieving, stripping, sublimation, vapor-liquid separation, winnowing, zone refining, and any combination thereof.
10. The method of claim 1 in which the dewatering step is downstream from one stage of the mineral processing application selected from the group consisting of:
adsorption, centrifugation, cyclonic separation, density based separation, chromatography, crystallization, decantation, distillation, drying, electrophoresis, elutriation, evaporation, extraction, leaching extraction, liquid-liquid extraction, solid phase extraction, flotation, dissolved air flotation, froth flotation, flocculation, filtration, mesh filtration, membrane filtration, microfiltration, ultrafiltration, nanofiltration, reverse osmosis, fractional distillation, fractional freezing, magnetic separation, precipitation, recrystallization, sedimentation, gravity separation, sieving, stripping, sublimation, vapor-liquid separation, winnowing, zone refining, and any combination thereof.
11. The method of claim 1 , wherein the wash fluid comprises water.
12. The method of claim 1 , wherein the wash fluid consists essentially of water.
13. The method of claim 1 , wherein the composition is added to the mineral bearing slurry alongside the wash fluid, before the wash fluid, after the wash fluid, or any combination thereof.
14. The method of claim 1 , wherein the composition is added to the wash fluid.
15. The method of claim 3 , wherein the base is selected from potassium hydroxide, sodium hydroxide, sodium bicarbonate, sodium carbonate, ammonia, ammonium hydroxide, organic bases, or any combination thereof.
16. The method of claim 1 , wherein the R-succinic compound is formed by opening the ring of an R-succinic anhydride compound.