Articles and methods comprising persistent carbenes and related compositions
Articles and methods comprising persistent carbenes are provided, as well as related compositions. In some embodiments, a persistent carbene may be associated with a portion of a substrate (e.g., at least a portion of a surface on the substrate). In certain embodiments, the association of persistent carbene with the substrate may be used to affect certain properties of substrate (e.g., surface chemistry, stability). In some cases, a persistent carbene may be functionalized after association with a portion of a substrate. In some embodiments, a persistent carbene and at least one secondary compound may be associated with a portion of a substrate. Articles and methods of the present invention may be useful for applications involving electronics, sensing, microfabrication, nanotechnology, biomimetic, and drug delivery, amongst others.
1. A method, comprising:
associating a persistent carbene with a portion of a substrate,
wherein the persistent carbene is a cyclicaminocarbene or a diaminocarbene or other persistent carbene,
wherein the substrate comprises a silicon surface comprising a plurality of Si—H bonds, and wherein the association comprises insertion of the carbene into an Si—H bond.
2. The method of claim 1 , wherein the persistent carbene comprises the structure:
wherein R 5 is optionally substituted alkyl, optionally substituted heteroalkyl, optionally substituted aryl, or optionally substituted heteroalkyl; and each R 6 , R 7 , and R 8 is independently hydrogen, optionally substituted alkyl or optionally substituted heteroaryl, or optionally, two R 6 , two R 7 or two R 8 are joined together to form optionally substituted cycloalkylene or optionally substituted cycloheteroalkylene.
3. The method of claim 2 , wherein R 5 is optionally substituted aryl.
4. The method of claim 2 , wherein each R 6 is optionally substituted alkyl.
5. The method of claim 2 , wherein each R 7 is hydrogen.
6. The method of claim 2 , wherein the two R 8 are joined together to form an optionally substituted cycloalkylene.
7. The method of claim 1 , wherein the persistent carbene comprises the structure:
wherein each R 9 is the same or different and is optionally substituted alkyl, optionally substituted heteroalkyl, optionally substituted aryl, or optionally substituted heteroaryl.
8. The method of claim 7 , wherein each R 9 is optionally substituted alkyl.
9. The method of claim 1 , wherein the persistent carbene comprises the structure:
10. The method of claim 1 , wherein the substrate comprises a silicon wafer.
11. The method of claim 1 , wherein the substrate comprises a plurality of silicon nanoparticles.
12. An article formed using the method of claim 1 .
13. The article of claim 12 , wherein the article is a solar cell or a microelectronic device.