IP Library Granted Patent US 9,941,534
Granted Patent B2
US 9,941,534 · App. 14/207,687 · Granted Apr 10, 2018

Integrated power generation and carbon capture using fuel cells

Inventors: Paul J. Berlowitz (Glen Gardner, NJ); Timothy Andrew Barckholtz (Whitehouse Station, NJ); Frank Hershkowitz (Basking Ridge, NJ)
Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
H01M8/06C01B3/16C01B3/34C01B3/48C01B3/50C04B7/367C07C1/0485C07C29/152C07C29/1518C10G2/32C10G2/332C10G2/34C10K3/04C21B15/00C25B3/02F02C3/22F02C6/18H01M8/04H01M8/04097H01M8/04111H01M8/04156H01M8/04761H01M8/04805H01M8/0612H01M8/0618H01M8/0625H01M8/0631H01M8/0637H01M8/0662H01M8/0668H01M8/0687H01M8/14H01M8/141H01M8/145C01B2203/00C01B2203/02C01B2203/0205C01B2203/0227C01B2203/0233C01B2203/0283C01B2203/04C01B2203/0405C01B2203/046C01B2203/0415C01B2203/0475C01B2203/0495C01B2203/061C01B2203/062C01B2203/066C01B2203/067C01B2203/1205C01B2203/1241C01B2203/148C01B2203/84C01B2203/86C04B2290/20C21B2300/02H01M2008/147H01M2250/10H01M2250/407H01M2300/0051Y02B90/14Y02E20/14Y02E20/16Y02E20/185Y02E50/18Y02E60/50Y02E60/526Y02E60/563Y02E60/566Y02P10/132Y02P20/129Y02P20/13Y02P30/30Y02P70/56Y02T10/16
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Quick Facts
Patent No.
US 9,941,534
App. No.
14/207,687
Granted
Apr 10, 2018
Kind
B2
Abstract

Systems and methods are provided for capturing CO 2 from a combustion source using molten carbonate fuel cells (MCFCs). At least a portion of the anode exhaust can be recycled for use as a fuel for the combustion source. Optionally, a second portion of the anode exhaust can be recycled for use as part of an anode input stream. This can allow for a reduction in the amount of fuel cell area required for separating CO 2 from the combustion source exhaust and/or modifications in how the fuel cells can be operated.

Claims (9)

1. A system for power generation, comprising:

a combustion turbine including a compressor, the compressor receiving an oxidant input and being in fluid communication with a combustion zone, the combustion zone further receiving at least one combustion fuel input, the combustion zone being in fluid communication with an expander having an exhaust output;

an exhaust gas recirculation system providing fluid communication between a first portion of the expander exhaust output and the combustion zone;

a molten carbonate fuel cell array comprising one or more fuel cell anodes and one or more fuel cell cathodes, the molten carbonate fuel cell array having at least one cathode input, at least one cathode output, at least one anode input, and at least one anode output, a second portion of the expander exhaust output being in fluid communication with the at least one cathode input; and

an anode recycle loop comprising one or more carbon dioxide separation stages for separating an anode exhaust stream to form an anode recycle loop output, a first portion of an anode recycle loop output being provided to the combustion zone as a combustion fuel input.

2. The system of claim 1 , wherein a second portion of the anode recycle loop output is provided to the at least one anode input.

3. The system of claim 1 , wherein the anode recycle loop further comprises a water gas shift reaction stage, the anode exhaust stream passing through the water gas shift reaction stage prior to at least one stage of the one or more carbon dioxide separation stages.

4. The system of claim 1 , wherein the exhaust gas recirculation system further comprises a heat recovery steam generation system.

5. The system of claim 1 , wherein the exhaust gas recirculation system provides fluid communication between a first portion of the expander exhaust output and the combustion zone by passing the first portion of the expander exhaust output into the compressor.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2015
From: BERLOWITZ, PAUL J.; HERSHKOWITZ, FRANK; BARCKHOLTZ, TIMOTHY A.
To: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Reel/Frame 036256/0549 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2014
From: BERLOWITZ, PAUL J.; BARCKHOLTZ, TIMOTHY A.; HERSHKOWITZ, FRANK H.
To: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Reel/Frame 032722/0713 →
Continuity (12)
Provisional Application 61788628 · Mar 15, 2013
Provisional Application 61787587 · Mar 15, 2013
Provisional Application 61787697 · Mar 15, 2013
Provisional Application 61787879 · Mar 15, 2013
Provisional Application 61884376 · Sep 30, 2013
Provisional Application 61884545 · Sep 30, 2013
Provisional Application 61884565 · Sep 30, 2013
Provisional Application 61884586 · Sep 30, 2013
Provisional Application 61884605 · Sep 30, 2013
Provisional Application 61884635 · Sep 30, 2013
Provisional Application 61889757 · Oct 11, 2013
Related Publication 20140272617A1 · Sep 18, 2014