Oligomer additive and lithium battery
An oligomer additive is provided. The oligomer additive is obtained by a reaction of a maleimide, a barbituric acid and a dibenzyl trithiocarbonate. A lithium battery including an anode, a cathode, a separator, an electrolyte solution and a package structure is also provided, wherein the cathode includes the oligomer additive.
1. An oligomer additive is obtained by a reaction of a maleimide, a barbituric acid and a dibenzyl trithiocarbonate.
2. The oligomer additive according to claim 1 , wherein a molar ratio of the maleimide to the barbituric acid is between 1:1 and 4:1.
3. The oligomer additive according to claim 1 , wherein a usage amount of the maleimide is 70.8 parts by weight to 90.6 parts by weight, a usage amount of the barbituric acid is 29.2 parts by weight to 9.4 parts by weight, and a usage amount of the dibenzyl trithiocarbonate is 1 part by weight to 10 parts by weight, based on 100 parts by weight of a total weight of the maleimide and the barbituric acid.
4. The oligomer additive according to claim 1 , wherein the maleimide comprises a mono-maleimide or a bismaleimide, wherein the mono-maleimide is selected from the group consisting of N-phenylmaleimide, N-(o-methylphenyl)-maleimide, N-(m-methylphenyl)-maleimide, N-(p-methylphenyl)-maleimide, N-cyclohexylmaleimide, maleimidophenol, maleimidobenzocyclobutene, phosphorus-containing maleimide, phosphonate-containing maleimide, siloxane-containing maleimide, N-(4-tetrahydropyranyl-oxyphenyl)maleimide, and 2,6-xylylmaleimide, and the bismaleimide has a structure represented by formula 1:
wherein R 1 comprises:
5. The oligomer additive according to claim 1 , wherein the barbituric acid has a structure represented by formula 2:
wherein R 2 and R 3 are each independently selected from the group consisting of —H, —CH 3 , —C 2 H 5 , —C 6 H 5 , —CH(CH 3 ) 2 , —CH 2 CH(CH 3 ) 2 , —CH 2 CH 2 CH(CH 3 ) 2 , and
6. A lithium battery, comprising:
an anode;
a cathode configured separately from the anode, wherein the cathode comprises the oligomer additive according to claim 1 ;
a separator disposed between the anode and the cathode, wherein the separator, the anode, and the cathode define a housing region;
an electrolyte solution disposed in the housing region; and
a package structure packaging the anode, the cathode, and the electrolyte solution.
7. The lithium battery according to claim 6 , wherein the electrolyte solution comprises an organic solvent, a lithium salt, and an additive.
8. The lithium battery according to claim 7 , wherein the additive comprises mono-maleimide, polymaleimide, bismaleimide, polybismaleimide, a copolymer of bismaleimide and mono-maleimide, vinylene carbonate, or a mixture thereof.