Continuous reactor
View Patent ↗Reactors and methods for reducing the carbon monoxide concentration in a reactant stream are provided. The reactors are generally configured such that a reactant from a second reactant stream may be continuously introduced along at least a portion of the length of a first reactant stream. A membrane may separate a first reactant stream and a second reactant stream.
1. A method for removing carbon monoxide from a reactant stream, the method comprising:
configuring a reactor to comprise:
a first flow path defining a length and a preferential oxidation catalyst disposed therealong, said first flow path configured to convey carbon monoxide and hydrogen contained in said reactant stream;
a second flow path configured to convey an oxygen-containing fluid stream; and
an oxygen-porous membrane disposed between said first and second flow paths;
flowing said reactant stream along said first flow path such that at least said carbon monoxide contained therein contacts said preferential oxidation catalyst; and
variably flowing oxygen to said first flow path in order to promote a preferential oxidation reaction between said oxygen and said carbon monoxide that is in contact with said preferential oxidation catalyst, said variably flowing of said oxygen comprising:
continuously flowing oxygen contained in said second flow path along at least a portion of said length of said first flow path such that said continuously flowing oxygen passes across said membrane and to said carbon monoxide that is in contact with said preferential oxidation catalyst; and
discretely flowing oxygen into an upstream portion of said first flow path in such quantity that catalytic reaction with said carbon monoxide that is in contact with said preferential oxidation catalyst occurs while inhibiting in said first flow path both the consumption of hydrogen in said reactant stream and the formation of a reverse water gas shift reaction in said reactant stream, a combination of said continuously flowing and said discretely flowing configured to avoid an even distribution of oxygen throughout said first flow path.
2. The method as claimed in claim 1 wherein said continuously flowing oxygen is first introduced downstream from a beginning of said first flow path.
3. The method as claimed in claim 1 wherein said preferential oxidation catalyst is selected to preferentially oxidize carbon monoxide over hydrogen.
4. The method as claimed in claim 1 wherein said oxygen-porous membrane separates said first and second flow paths from a beginning of said length to said end of said length.
5. The method as claimed in claim 1 wherein said first and second flow paths are fluidly separated from one another along said length of said first reactant flow path at least up to where said oxygen-porous membrane is present.
6. The method as claimed in claim 1 wherein said first flow path defines an elongate channel that comprises at least a first sidewall and a second sidewall such that said first sidewall comprises said membrane.
7. The method as claimed in claim 6 wherein said second sidewall comprises a heat exchanger wall.
8. The method as claimed in claim 6 wherein said preferential oxidation catalyst is disposed on said first sidewall.
9. The method as claimed in claim 6 wherein said preferential oxidation catalyst is disposed on said second sidewall.
10. The method as claimed in claim 1 wherein said membrane comprises yttria stabilized bismuth oxide.
11. The method as claimed in claim 1 wherein said membrane comprises silver.
12. The method as claimed in claim 1 wherein said membrane comprises ETS-4 zeolite material.
13. The method as claimed in claim 1 wherein said membrane comprises SOFC electrolyte material.
14. The method as claimed in claim 13 wherein said SOFC electrolyte material is selected from CeO 2 doped with Mg 2+ , Ca 2+ , Sr 2+ , Yb 3+ , Y 3+ , Gd 3+ , La 3+ , Ti 4+ , Zr 4+ , Nb 5+ , Sc 3+ , Sm 3+ ; Zr doped with Ca, Y, yttria-stabalized zirconia (YSZ); perovskite-type La 1−x A x Co 1−y B y O 3−d where A=Sr, Ba, Ca, B═Fe, Cu, Ni, and d is the non-stoichiometery factor; La 0.85 Sr 0.15 MnO 3 ; and perovskite-type ABO 3 where A=La, Sr, Ca, B═Co, Fe; and combinations thereof.
15. The method as claimed in claim 1 wherein said membrane comprises a TiO 2 /polyimide composite.
16. The method as claimed in claim 1 wherein said second flow path is configured such that oxygen from said second flow path is continuously introduced only to a portion of said first flow path proximate to an end of said length.