IP Library Granted Patent US 8,298,097
Granted Patent B2
US 8,298,097 · App. 12/635,143 · Granted Oct 30, 2012

Multilayer core golf ball having hardness gradient within and between each core layer

Assignee: Acushnet Company
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Quick Facts
Patent No.
US 8,298,097
App. No.
12/635,143
Granted
Oct 30, 2012
Kind
B2
Abstract

A multi-layered core golf ball wherein each core layer comprises its own specific hardness gradient in addition to an overall specific hardness gradient from one core layer to the next. The inner core layer comprises a plurality of hardnesses of from about 50 Shore C to about 90 Shore C, a diameter of about 30 mm or lower, and a geometric center comprising a hardness greater than that of a first outer surface to define a negative hardness gradient of about 15 Shore C or greater. The outer core layer comprises a plurality of harnesses of from about 50 Shore C to about 95 Shore C, a thickness of about 10 mm or lower, and a second outer surface comprising a hardness greater than that of an inner surface to define a positive hardness gradient of about 20 Shore C or greater. A further outer core layer hardness, disposed in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, is greater than that of the inner and second outer surfaces. Also, the hardness of the second outer surface is similar to or less than that of the geometric center.

Claims (56)

1. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or lower and having a plurality of hardnesses of from about 50 Shore C to about 90 Shore C,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 15 Shore C or greater;

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of about 10 mm or lower and having a plurality of hardnesses of from about 50 Shore C to about 95 Shore C, wherein the inner surface comprises a third hardness and the second outer surface comprises a fourth hardness, wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 20 Shore C or greater,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is greater than the first hardness, the third hardness and the fourth hardness; and

wherein the fourth hardness is similar to or less than the first hardness.

2. The golf ball of claim 1 , wherein the third hardness is similar to the second hardness.

3. The golf ball of claim 1 , wherein the inner core layer and the outer core layer each comprises peroxide in an amount of from about 0.2 phr to about 3.0 phr and antioxidant in an amount of about 2.5 phr or less.

4. The golf ball of claim 1 , wherein the ratio of antioxidant to initiator of the inner core layer is from about 0.33 to about 4.8.

5. The golf ball of claim 1 , wherein the diameter of the inner core layer is about 26 mm or lower.

6. The golf ball of claim 1 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore C or greater.

7. The golf ball of claim 1 , wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 25 Shore C or greater.

8. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or lower and having a plurality of hardnesses of from about 50 Shore C to about 90 Shore C,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 15 Shore C or greater;

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of about 10 mm or lower and having a plurality of hardnesses of from about 50 Shore C to about 80 Shore C, wherein the inner surface comprises a third hardness and the second outer surface comprises a fourth hardness, wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 15 Shore C or lower,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is similar to or less than the first hardness and is greater than the third hardness and the fourth hardness; and

wherein the fourth hardness is less than the first hardness.

9. The golf ball of claim 8 , wherein the third hardness is similar to the second hardness.

10. The golf ball of claim 8 , wherein the inner core layer and the outer core layer each comprises peroxide in an amount of from about 0.2 phr to about 3.0 phr and antioxidant in an amount of about 2.5 phr or less.

11. The golf ball of claim 8 , wherein the ratio of antioxidant to initiator of the inner core layer is from about 0.33 to about 4.8.

12. The golf ball of claim 8 , wherein the diameter of the inner core layer is about 26 mm or lower.

13. The golf ball of claim 8 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore C or greater.

14. The golf ball of claim 8 , wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 10 Shore C or lower.

15. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or lower and having a plurality of hardnesses of from about 30 Shore D to about 68 Shore D,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore D or greater;

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of about 10 mm or lower and having a plurality of hardnesses of from about 30 Shore D to about 68 Shore D, wherein the inner surface comprises a third hardness and the second outer surface comprises a fourth hardness, wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 20 Shore D or greater,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is greater than the first hardness, the third hardness and the fourth hardness; and

wherein the fourth hardness is similar to or less than the first hardness.

16. The golf ball of claim 15 , wherein the third hardness is similar to the second hardness.

17. The golf ball of claim 15 , wherein the inner core layer and the outer core layer each comprises peroxide in an amount of from about 0.2 phr to about 3.0 phr and antioxidant in an amount of about 2.5 phr or less.

18. The golf ball of claim 15 , wherein the ratio of antioxidant to initiator of the inner core layer is from about 0.33 to about 4.8.

19. The golf ball of claim 15 , wherein the diameter of the inner core layer is about 26 mm or lower.

20. The golf ball of claim 15 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 25 Shore D or greater.

21. The golf ball of claim 15 , wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 25 Shore D or greater.

22. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or lower and having a plurality of hardnesses of from about 30 Shore D to about 68 Shore D,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore D or greater;

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of about 10 mm or lower and having a plurality of hardnesses of from about 30 Shore D to about 55 Shore D, wherein the inner surface comprises a third hardness and the second outer surface comprises a fourth hardness, wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 15 Shore D or lower,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is similar to or less than the first hardness and is greater than the third hardness and the fourth hardness; and

wherein the fourth hardness is less than the first hardness to define a negative hardness gradient of about 10D or greater.

23. The golf ball of claim 22 , wherein the third hardness is similar to the second hardness.

24. The golf ball of claim 22 , wherein the diameter of the inner core layer is about 26 mm or lower.

25. The golf ball of claim 22 , wherein the inner core layer and the outer core layer each comprises peroxide in an amount of from about 0.2 phr to about 3.0 phr and antioxidant in an amount of about 2.5 phr or less.

26. The golf ball of claim 22 , wherein the ratio of antioxidant to initiator of the inner core layer is from about 0.33 to about 4.8.

27. The golf ball of claim 22 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 25 Shore D or greater.

28. The golf ball of claim 22 , wherein the fourth hardness is greater than the third hardness to define a positive hardness gradient of about 10 Shore D or lower.

Assignments (5)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027347/0053) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0259 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 8, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027347/0053 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 10, 2009
From: SULLIVAN, MICHAEL J.; COMEAU, BRIAN; GOGUEN, DOUGLAS S.; BULPETT, DAVID A.
To: ACUSHNET COMPANY
Reel/Frame 023635/0746 →
Continuity (13)
Continuation In Part 12635025 · Dec 10, 2009
Continuation In Part 12469312 · May 20, 2009
Continuation In Part 12469258 · May 20, 2009
Continuation In Part 11829461 · Jul 27, 2007
Continuation In Part 11772903 · Jul 3, 2007
Continuation In Part 12492514 · Jun 26, 2009
Continuation In Part 12558732 · Sep 14, 2009
Continuation In Part 12558726 · Sep 14, 2009
Continuation 12186877 · Aug 6, 2008
Continuation 11832197 · Aug 1, 2007
Continuation In Part 11829461
Continuation In Part 11772903
Related Publication 20100160085A1 · Jun 24, 2010