IP Library Granted Patent US 10,695,616
Granted Patent B1
US 10,695,616 · App. 16/535,917 · Granted Jun 30, 2020

Graphene core for a golf ball with a soft cover

Inventors: Petra Petrich (Escondido, CA); David Bartels (Carlsbad, CA); Hong G. Jeon (Carlsbad, CA); Carl Brown (Temecula, CA)
Assignee: Callaway Golf Company
A63B37/0051A63B37/0031A63B37/0033A63B37/0043A63B37/0045A63B37/0065A63B37/0069A63B37/0074A63B37/0075A63B37/0076A63B37/0092C01B32/182C08F36/06C08K3/042
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Quick Facts
Patent No.
US 10,695,616
App. No.
16/535,917
Granted
Jun 30, 2020
Kind
B1
Abstract

A golf ball with a core comprising polybutadiene and graphene, and a soft cover is disclosed herein. The golf ball has a dual core with an outer core comprising polybutadiene and graphene. The soft cover is preferably composed of a highly neutralized polymer, a first ionomer, a second ionomer, and a paraloid impact modifier.

Claims (20)

1. A golf ball comprising:

an inner core comprising a polybutadiene material, wherein the inner core has a deflection of at least 0.23 under a load of 220 pounds;

an outer core comprising polybutadiene material; and

a cover layer disposed over the outer core, the cover layer consisting essentially of 10 to 30 wt % of a highly neutralized polymer, 10 to 90 wt % of a first ionomer, 0 to 30 wt % of a second ionomer, 0 to 30 wt % of a third ionomer, 15 to 25 wt % of a masterbatch comprising from 15 to 30 wt % of an impact modifier, and 1 to 10 wt % of a color masterbatch, wherein the impact modifier is at least one of methyl methacrylate-butadiene-styrene polymer (MBS) impact-property modifiers for poly(vinyl chloride) or acrylic/methacrylic core-shell modifiers for polycarbonate;

wherein the golf ball has a diameter of at least 1.68 inches, a mass lower than 45.93 grams, and a COR of at least 0.790.

2. The golf ball according to claim 1 wherein the cover layer has a Shore D hardness ranging from 35 to 60.

3. The golf ball according to claim 1 wherein the outer core has a tensile modulus ranging from 8 MPa to 10 MPa.

4. A golf ball comprising:

an inner core comprising a polybutadiene, wherein the inner core has a deflection of at least 0.23 under a load of 220 pounds;

an outer core comprising a polybutadiene; and

a cover layer disposed over the outer core, the cover layer consisting essentially of 10 to 30 wt % of a highly neutralized polymer, 10 to 30 wt % of a first ionomer, 10 to 30 wt % of a second ionomer, 10 to 30 wt % of a third ionomer, 15 to 25 wt % of a masterbatch comprising from 15 to 30 wt % of an impact modifier, and 1 to 10 wt % of a color masterbatch, wherein the impact modifier is at least one of methyl methacrylate-butadiene-styrene polymer (MBS) impact-property modifiers for poly(vinyl chloride), and acrylic/methacrylic core-shell modifiers for polycarbonate;

wherein the golf ball has a diameter of at least 1.68 inches, a mass lower than 45.93 grams, and a COR of at least 0.790.

5. The golf ball according to claim 4 wherein the outer core has a tensile modulus ranging from 8 MPa to 10 MPa.

6. A golf ball comprising:

an inner core comprising a polybutadiene, wherein the inner core has a deflection of at least 0.23 under a load of 220 pounds;

an outer core comprising a polybutadiene;

a mantle layer; and

a cover layer disposed over the outer core, the cover layer consisting essentially of 10 to 30 wt % of a highly neutralized polymer, 10 to 30 wt % of a first ionomer, 10 to 30 wt % of a second ionomer, 10 to 30 wt % of a third ionomer, 15 to 25 wt % of a masterbatch comprising from 15 to 30 wt % of an impact modifier, and 1 to 10 wt % of a color masterbatch; wherein the cover layer has a thickness ranging from 0.025 inch to 0.055 inch, wherein the impact modifier is at least one of methyl methacrylate-butadiene-styrene polymer (MBS) impact-property modifiers for poly(vinyl chloride), and acrylic/methacrylic core-shell modifiers for polycarbonate;

wherein the cover layer has a Shore D hardness ranging from 35 to 60;

wherein the golf ball has a diameter of at least 1.68 inches, a mass lower than 45.93 grams, and a COR of at least 0.790.

Assignments (4)
SECURITY INTEREST Recorded May 17, 2023
From: TOPGOLF CALLAWAY BRANDS CORP.; OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 063692/0009 →
SECURITY AGREEMENT Recorded May 16, 2023
From: TOPGOLF CALLAWAY BRANDS CORP. (FORMERLY CALLAWAY GOLF COMPANY); OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A, AS COLLATERAL AGENT
Reel/Frame 063665/0176 →
CHANGE OF NAME Recorded Jan 25, 2023
From: CALLLAWAY GOLF COMPANY
To: TOPGOLF CALLAWAY BRANDS CORP.
Reel/Frame 062512/0585 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 8, 2019
From: PETRICH, PETRA; BARTELS, DAVID; JEON, HONG G.; BROWN, CARL
To: CALLAWAY GOLF COMPANY
Reel/Frame 050004/0729 →
Continuity (8)
Continuation 16290711 · Mar 1, 2019
Continuation In Part 16164661 · Oct 18, 2018
Continuation In Part 16054703 · Aug 3, 2018
Continuation 15705011 · Sep 14, 2017
Continuation In Part 15436169 · Feb 17, 2017
Provisional Application 62401034 · Sep 28, 2016
Provisional Application 62693220 · Jul 2, 2018
Provisional Application 62695645 · Jul 9, 2018