Hybrid nanosilver/liquid metal ink composition and uses thereof
The present disclosure is directed to a hybrid conductive ink including: silver nanoparticles and eutectic low melting point alloy particles, wherein a weight ratio of the eutectic low melting point alloy particles and the silver nanoparticles ranges from 1:20 to 1:5. Also provided herein are methods of forming an interconnect including a) depositing a hybrid conductive ink on a conductive element positioned on a substrate, wherein the hybrid conductive ink comprises silver nanoparticles and eutectic low melting point alloy particles, the eutectic low melting point alloy particles and the silver nanoparticles being in a weight ratio from about 1:20 to about 1:5; b) placing an electronic component onto the hybrid conductive ink; c) heating the substrate, conductive element, hybrid conductive ink and electronic component to a temperature sufficient i) to anneal the silver nanoparticles in the hybrid conductive ink and ii) to melt the low melting point eutectic alloy particles, wherein the melted low melting point eutectic alloy flows to occupy spaces between the annealed silver nanoparticles, d) allowing the melted low melting point eutectic alloy of the hybrid conductive ink to harden and fuse to the electronic component and the conductive element, thereby forming an interconnect. Electrical circuits including conductive traces and, optionally, interconnects formed with the hybrid conductive ink are also provided.
1. An interconnect comprising a hybrid conductive ink comprising a eutectic low melting point alloy and annealed silver nanoparticles, wherein the eutectic low melting point alloy occupies spaces between the annealed silver nanoparticles, and wherein the eutectic low melting point alloy comprises In 51.0 Bi 32.5 Sn 16.5 .
2. The interconnect of claim 1 , wherein a weight ratio of the eutectic low melting point alloy and the annealed silver nanoparticles ranges from 1:20 to 1:5.
3. The interconnect of claim 1 , wherein a weight ratio of the eutectic low melting point alloy and the annealed silver nanoparticles is 1:5.
4. The interconnect of claim 1 , wherein the interconnect is self-healing.
5. The interconnect of claim 1 , wherein the interconnect is positioned on a plastic substrate.
6. The interconnect of claim 5 , wherein the plastic substrate is selected from the group consisting of polyester, polycarbonate, polyimide, polyethylene terephthalate and polyethylene naphthalate (PEN).
7. The interconnect of claim 1 , wherein the annealed silver nanoparticles comprise a plurality of silver nanoparticles, wherein the plurality of silver nanoparticles has an average particle size ranging from about 0.5 to about 100.0 nanometers.
8. The interconnect of claim 1 , wherein a resin is not present in the hybrid conductive ink.
9. The interconnect of claim 1 , wherein the interconnect is formed according to a method comprising:
a) depositing a hybrid ink comprising a plurality of silver nanoparticles on a conductive element positioned on a substrate;
b) placing an electronic component onto the hybrid ink;
c) heating the substrate, the conductive element, the hybrid ink and the electronic component to a temperature sufficient i) to anneal the plurality of silver nanoparticles in the conductive ink to thereby form the annealed silver nanoparticles of the hybrid conductive ink and ii) to melt a plurality of In 51.0 Bi 32.5 Sn 16.5 particles to form a melted low melting point eutectic alloy, wherein the melted low melting point eutectic alloy flows to occupy spaces between the annealed plurality of silver nanoparticles, and
d) allowing the melted low melting point eutectic alloy of the hybrid conductive ink to harden and fuse to the electronic component and the conductive element, thereby forming the interconnect.
10. The interconnect of claim 9 , wherein a weight ratio of the plurality of the In 51.0 Bi 32.5 Sn 16.5 particles and the plurality of silver nanoparticles is 1:5.
11. The interconnect of claim 9 , wherein the sufficient temperature is about 130° ° C.
12. The interconnect of claim 9 , wherein the substrate is a plastic substrate.
13. The interconnect of claim 12 , wherein the plastic substrate is selected from the group consisting of polyester, polycarbonate, polyimide, polyethylene terephthalate and polyethylene naphthalate (PEN).
14. The interconnect of claim 9 , wherein the hybrid conductive ink is deposited via aerosol ink jet printing.