Toughened epoxy-anhydride no-flow underfill encapsulant
View Patent ↗A curable underfill encapsulant composition which is especially useful in the no-flow underfill encapsulation process. The composition contains an epoxy resin, a fluxing agent, a linear polyanhydride, a core shell polymer and a catalyst. In an alternative embodiment, the composition also contains a linear anhydride. Various additives, such as surfactants and coupling agents may also be added to the composition.
1. A no-flow underfill encapsulant material comprising:
a) one or more epoxy resins;
b) one or more linear polyanhydride comprising particles that are equal to or smaller than 50 microns;
c) one or more catalysts, and
d) one or more core shell polymers, and
e) a cyclic anhydride,
wherein the epoxy resin is selected from the group consisting of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, vinylcyclohexene dioxide, 3,4-epoxy-6-methyl cyclohexyl methyl-3,4 -epoxycyclohexane carboxylate, dicyclopentadiene dioxide, bisphenol A resin, 2,2-bis( 4-hydroxyphenyl) propane-epichlorohydrin copolymer, bisphenol F resin, epoxy novolac resin, poly(phenyl glycidyl ether)-co-formaldehyde, type epoxy resin, dicyclopentadiene-phenol epoxy resins, naphthalene epoxy resins, epoxy functional butadiene acrylonitrile copolymers, epoxy functional polydimethyl siloxane, and mixtures thereof and wherein the cyclic anhydride is a cycloaliphatic anhydride selected from the group consisting of methylhexa-hydro phthalic anhydride methyltetra-hydrophthalic anhydride, nadic methyl anhydride, hexa-hydro phthalic anhydride, tetra-hydro phthalic anhydride, dodecenylsuccinic anhydride, phthalic anhydride and mixtures thereof and comprises up to about 30 wt % of the encapsulant.
2. The no-flow underfill encapsulant of claim 1 , wherein the epoxy resin comprises bisphenol-F epoxy resin containing more than one 1.2 epoxy group or molecule.
3. The no-flow underfill encapsulant of claim 2 , wherein the epoxy resin comprises in the range of about 25 wt % to about 75 wt % of the encapsulant.
4. The no-flow underfill encapsulant of claim 3 , wherein the epoxy resin comprises in the range of about 35 wt % to about 65 wt % of the encapsulant.
5. The no-flow underfill encapsulant of claim 4 , wherein the epoxy resin is a mixture of bisphenol A and bisphenol F type epoxy resins.
6. The no-flow underfill encapsulant of claim 1 , wherein the linear polyanhydride comprises polysebacic polyanhydride, polyazelaic polyanhydride, polyadipic polyanhydride or mixtures thereof.
7. The underfill encapsulant of claim 6 , wherein the linear polyanhydride comprises polysebacic polyanhydride.
8. The underfill encapsulant of claim 6 , wherein the linear polyanhydride comprises in the range of about 2 wt % to about 50 wt % of the encapsulant.
9. The underfill encapsulant of claim 8 , wherein the linear polyanhydride comprises in the range of about 5 wt % to about 35 wt % of the encapsulant.
10. The underfill encapsulant of claim 1 , wherein the catalyst is an imidazole.
11. The underfill encapsulant of claim 10 , wherein the imidazole is blocked or protected for delayed reactivity.
12. The underfill encapsulant of claim 1 , wherein the catalyst is selected from the group consisting of 1-cyanoethyl-2-ethyl-4-methyl-imidazole, alkyl-substituted imidazole, triphenylphosphine, imidazolium salts, imidazole phosphates, onium borate, metal chelates, and mixtures thereof.
13. The underfill encapsulant of claim 11 , wherein the catalyst comprises in the range of about 0.05 wt % to about 1 wt % of the encapsulant.
14. The underfill encapsulant of claim 13 , wherein the catalyst comprises in the range of about 0.1 wt % to about 0.25 wt % of the encapsulant.
15. The underfill encapsulant of claim 1 , wherein the core shell polymer is selected from the group consisting of acrylonitrile-butadiene-styrene core shell polymer, methacrylate butadiene styrene core shell polymer, or mixtures thereof.
16. The underfill encapsulant of claim 15 , wherein the core shell polymer is acrylonitrile-butadiene-styrene core shell polymer.
17. The underfill encapsulant of claim 15 , wherein the core shell polymer comprises in the range of about 1 wt % to about 15 wt % of the encapsulant.
18. The underfill encapsulant of claim 17 , wherein the core shell polymer comprises in the range of about 2 wt % to about 8 wt % of the encapsulant.
19. The underfill encapsulant of claim 1 , wherein the encapsulant further comprises one or more of the group consisting of surfactants, coupling agents, reactive diluents, polymeric modifiers or mixtures thereof.
20. The underfill encapsulant of claim 19 , wherein the surfactant is selected from the group consisting of organic acrylic polymers, silicones, polyoxyethylene/polyoxypropylene block copolymers, ethylene diamine based polyoxyethylene/polyoxypropylene block copolymers, polyol-based polyoxyalkylenes, fatty alcohol-based polyoxyalkylenes, fatty alcohol polyoxyalkylene alkyl ethers and mixtures thereof.
21. The underfill encapsulant of claim 19 , wherein the reactive diluent is selected from the group consisting of p-tert-butyl-phenyl-glycidyl ether, allyl glycidyl ether, glycerol diglycidyl ether, glycidyl ether or alkyl, butanediodiglydidylether and mixtures thereof.
22. The underfill encapsulant of claim 1 , wherein the epoxy resin comprises in the range of about 25 wt % to about 75 wt % of the encapsulant.
23. The underfill encapsulant of claim 22 , wherein the epoxy resin comprises in the range of about 35 wt % to about 65 wt % of the encapsulant.
24. The no-flow underfill encapsulant of claim 1 , wherein the epoxy resin is a mixture of bisphenol A and bisphenol F type epoxy resins.