IP Library Granted Patent US 6,972,224
Granted Patent B2
US 6,972,224 · App. 10/400,896 · Granted Dec 6, 2005

Method for fabricating dual-metal gate device

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Quick Facts
Patent No.
US 6,972,224
App. No.
10/400,896
Granted
Dec 6, 2005
Kind
B2
Abstract

A method of fabricating a MOS transistor that comprises a dual-metal gate that is formed from heterotypical metals. A gate dielectric ( 34 ), such as HfO 2 , is deposited on a semiconductor substrate. A sacrificial layer ( 35 ), is next deposited over the gate dielectric. The sacrificial layer is patterned so that the gate dielectric over a first (pMOS, for example) area ( 32 ) of the substrate is exposed and gate dielectric over a second (nMOS, for example) area ( 33 ) of the substrate continues to be protected by the sacrificial layer. A first gate conductor material ( 51 ) is deposited over the remaining sacrificial area and over the exposed gate dielectric. The first gate conductor material is patterned so that first gate conductor material over the second area of the substrate is etched away. The sacrificial layer over the second area prevents damage to the underlying dielectric material as the first gate conductor material is removed.

Claims (31)

1. A method of fabricating a semiconductor device, the method comprising:

providing a semiconductor substrate having a surface and having a first area and a second area;

forming a gate dielectric on the surface over the first area and over the second area;

forming a sacrificial layer over the gate dielectric, wherein the sacrificial layer comprises silicon oxide;

patterning the sacrificial layer so that the gate dielectric over the first area is exposed and a remaining portion of the sacrificial layer protects the gate dielectric over the second area;

depositing a first metal gate conductor material over exposed gate dielectric and over the remaining portion of the sacrificial layer;

patterning the first metal gate conductor material so that the remaining portion of the sacrificial layer is exposed;

after patterning the first metal gate conductor material, removing the remaining portion of the sacrificial layer so as to expose the gate dielectric over the second area using a wet chemical etch; and

depositing a second metal gate conductor material over the patterned first metal gate conductor material and directly on the gate dielectric that was exposed over the second area as a result of removing the remaining sacrificial layer.

2. A method of fabricating a semiconductor device as defined in claim 1 , wherein the gate dielectric is a MeOx.

3. A method of fabricating a semiconductor device as defined in claim 2 , wherein the MeOx is selected from the group consisting of HfO 2 and oxides or oxynitrides of zirconium, hafnium, aluminum, lanthanum, strontium, titanium, silicon and combinations thereof.

4. A method of fabricating a semiconductor as defined in claim 1 , wherein the first metal gate conductor material is Ir.

5. A method of fabricating a semiconductor as defined in claim 1 , wherein the second metal gate conductor material is TaSiN.

6. A method of fabricating a semiconductor as defined in claim 5 , wherein the gate dielectric is a MeOx.

7. A method of fabricating a semiconductor as defined in claim 6 , wherein the gate dielectric is HfO 2 .

8. A method of fabricating a semiconductor as defined in claim 7 , wherein the first metal gate conductor material is Ir.

9. A method of fabricating a semiconductor device as defined in claim 1 , wherein:

i. the first area of the substrate accommodates the formation of a pMOS transistor;

ii. the first metal gate conductor material has a work function that approximates the valence band of silicon;

iii. the second area of the substrate accommodates the formation of an nMOS transistor; and

iv. the second metal gate conductor material has a work function that approximates the conduction band of silicon.

10. A method of fabricating a semiconductor device as defined in claim 9 , wherein the gate dielectric is HfO 2 .

11. A method of fabricating a semiconductor device, the method comprising:

providing a semiconductor substrate having a surface and having a first area and a second area;

forming a metal oxide gate dielectric on the surface over the first area and over the second area; and

protecting the metal oxide gate dielectric against a subsequent metal etch by:

imposing a first silicon oxide sacrificial layer directly on die metal oxide gate dielectric over the second area while providing an exposed portion of the metal oxide gate dielectric over the first area;

depositing a first metal directly on the exposed portion of the metal oxide gate dielectric over the first area and over the first silicon oxide sacrificial layer;

etching away the first metal over the second area using a dry etch;

etching away the first silicon oxide sacrificial layer using a wet chemical etch; and

depositing a second metal directly on the exposed portion of the metal oxide gate dielectric over the second area.

Assignments (18)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
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CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE LISTED CHANGE OF NAME SHOULD BE MERGER AND CHANGE PREVIOUSLY RECORDED AT REEL: 040652 FRAME: 0180. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Jan 12, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 041354/0148 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 040652/0180 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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