IP Library Granted Patent US 7,112,304
Granted Patent B2
US 7,112,304 · App. 10/412,602 · Granted Sep 26, 2006

Robust chemiresistor sensor

Assignee: Therm-O-Disc, Incorporated
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Quick Facts
Patent No.
US 7,112,304
App. No.
10/412,602
Granted
Sep 26, 2006
Kind
B2
Abstract

A chemiresistor sensor probe for detecting target analytes. The probe includes a body having a first control surface and a second control surface recessed within the first. A sensor film comprises numerous conductive particles disposed upon the second surface. The film swells upon absorbing one or more analytes for which it has an affinity, thus causing the conductive particles to become more dispersed and increasing the resistance between the particles. The thickness of the film is equal to the distance between the first surface and the second surface, thus permitting the thickness to be controlled by varying the distance between the control surfaces. The robustness of the sensor probe is enhanced by placing a porous or mesh electrode along with, or in place of, a chemical binding agent between the film and the terminals. The robustness is also improved by placing a diode in series with the sensor circuit.

Claims (62)

1. A chemiresistor sensor probe for detecting the presence of one or more target analytes in the atmosphere of an ambient environment, the probe comprising:

a body comprising a sensing portion and a terminal portion;

a sensor film located on said sensing portion; and

first and second terminals disposed within said body, each of said first and second terminals extending from said sensing portion to the terminal portion and protruding from said body; and

conductive interlocking portions, one each disposed between each of said first and second terminals and said sensor film, each said interlocking portion in direct contact with said sensor film and a respective one of said first and second terminals.

2. The chemiresistor sensor probe of claim 1 , further comprising a cap attached to said body and covering said sensor film, said cap comprising at least one aperture that permits the atmosphere of the ambient environment to pass through the cap.

3. The chemiresistor sensor probe of claim 1 , wherein at least one of said conductive interlocking portions comprise a conductive plate.

4. The chemiresistor sensor probe of claim 3 , wherein said conductive plate comprises a mesh surface.

5. The chemiresistor sensor probe of claim 1 , further comprising a chemical bond between at least one of said first and second terminals and said sensor film.

6. The chemiresistor sensor probe of claim 1 , further comprising at least one aperture within each of said first and second terminals for receipt of a positioning rod for positioning said terminals within said body during manufacturing.

7. The chemiresistor sensor probe of claim 1 , wherein said probe body comprises of a molded polymer.

8. The chemiresistor sensor probe of claim 1 , wherein said sensor film comprises a crosslinked, polymeric matrix.

9. The chemiresistor sensor probe of claim 1 , further comprising a sensor circuit having a diode to prevent bypass leakage from negatively affecting the performance of said sensor probe.

10. The chemiresistor sensor probe of claim 1 , further comprising:

a plurality of conductive materials disposed within said sensor film, said conductive materials becoming more dispersed within said film as said film swells upon absorbing said analytes, thus increasing a resistance of said film.

11. The chemiresistor sensor probe of claim 1 , wherein said sensor film is first applied to a second control surface of said sensing portion that is recessed beneath a first control surface in excess with a portion of said film extending beyond said first control surface being subsequently removed such that said film has a thickness equal to a distance that said second control surface is recessed beneath said first control surface.

12. The chemiresistor sensor probe of claim 1 , further comprising:

a sensor circuit coupled with said sensor probe, said sensor circuit to prevent bypass leakage from negatively affecting performance of said sensor probe.

13. The chemiresistor sensor probe of claim 1 , further comprising a control unit in communication with each of said first terminal and said second terminal to monitor electrical properties of said sensor film, said control unit is operable to generate a first signal representing the presence or absence of the analytes.

14. The chemiresistor sensor probe of claim 13 , further comprising a user interface in communication with said control unit, said user interface operable to receive said first signal and generate a second signal representing the presence or absence of the analytes.

15. A chemiresistor sensor probe for detecting the presence of one or more target analytes in the atmosphere of an ambient environment, the probe comprising:

a molded body comprising a sensing region and a bottom surface opposite of said sensing region;

a sensor film comprising a cross-linked polymeric matrix located in said sensing region;

first and second terminals disposed within said body, each of said first and second terminals extending from said sensing region through said bottom surface so as to protrude from said body, each of said first and second terminals comprising an interlocking member disposed between and in direct contact with said sensor film and a respective one of said first and second terminals; and

a molded cap attached to said body and covering said sensor film, said cap comprising at least one aperture which permits the atmosphere of the ambient environment to pass through the cap.

16. The chemiresistor sensor probe of claim 15 , wherein at least one of said conductive interlocking members comprise a conductive plate.

17. The chemiresistor sensor probe of claim 16 , wherein said conductive plate comprises a mesh surface.

18. The chemiresistor sensor probe of claim 15 , further comprising a chemical bond between at least one of said first and second terminals and said sensor film.

19. The chemiresistor sensor probe of claim 15 , wherein said sensor film is first applied to a second control surface of said sensing region that is recessed beneath a first control surface in excess with a portion of said film extending beyond said first control surface being subsequently removed such that said film has a thickness equal to a distance that said second control surface is recessed beneath said first control surface.

20. The chemiresistor sensor probe of claim 15 , further comprising:

a sensor circuit coupled with said sensor probe, said sensor circuit to prevent bypass leakage from negatively affecting performance of said sensor probe.

21. The chemiresistor sensor probe of claim 15 , further comprising a control unit in communication with each of said first terminal and said second terminal to monitor electrical properties of said sensor film, said control unit is operable to generate a first signal representing the presence or absence of the analytes.

22. The chemiresistor sensor probe of claim 21 , further comprising a user interface in communication with said control unit, said user interface operable to receive said first signal and generate a second signal representing the presence or absence of the analytes.

23. A chemiresistor sensor probe for detecting the presence of one or more target analytes comprising:

a probe body;

a sensor film that absorbs the target analytes when the analytes are present mounted at an exterior surface of said probe body; and

a first and a second terminal each having an interlocking device in direct contact with said sensor film.

24. The chemiresistor sensor probe of claim 23 , further comprising a cap attached to said body and covering said sensor film, said cap comprising at least one aperture that permits the atmosphere of the ambient environment to pass through the cap.

25. The chemiresistor sensor probe of claim 23 , wherein said interlocking device comprises a conductive plate.

26. The chemiresistor sensor probe of claim 25 , wherein said conductive plate comprises a mesh surface.

27. The chemiresistor sensor probe of claim 23 , further comprising a chemical bond between at least one of said first and second terminals and said sensor film.

28. The chemiresistor sensor probe of claim 23 , wherein said probe body comprises a molded polymer.

29. The chemiresistor sensor probe of claim 23 , wherein said sensor film comprises a crosslinked, polymeric matrix.

30. The chemiresistor sensor probe of claim 23 , wherein said sensor film is first applied to a second control surface of said probe body that is recessed beneath a first control surface in excess with a portion of said film extending beyond said first control surface being subsequently removed such that said film has a thickness equal to a distance that said second control surface is recessed beneath said first control surface.

31. The chemiresistor sensor probe of claim 23 , further comprising a control unit in communication with each of said first terminal and said second terminal to monitor electrical properties of said sensor film, said control unit is operable to generate a first signal representing the presence or absence of the analytes.

32. The chemiresistor sensor probe of claim 31 , further comprising a user interface in communication with said control unit, said user interface operable to receive said first signal and generate a second signal representing the presence or absence of the analytes.

33. A chemiresistor sensor system for detecting the presence of one or more analytes comprising:

a probe including a first electrode and a second electrode each having a conductive interlocking device in direct contact with a sensor film, said probe operable to generate a first output indicative of the absence or presence of the analytes in the environment;

a control unit in electrical communication with said first and second electrodes, said control unit operable to receive said first output from said probe and generate a signal corresponding to said first output; and

a user interface in communication with said control unit, said user interface operable to receive said signal from said control unit and generate a second output corresponding to the absence or presence of analytes in the environment.

34. A chemiresistor sensor probe for detecting the presence of one or more target analytes comprising:

a probe body;

a sensor film including a crosslinked polymeric matrix mounted at an exterior surface of said probe body; and

a first and a second terminal each having a conductive interlocking device in direct contact with said sensor film, said first and second terminals extending from said sensor film through said probe body and protruding from said probe body.

35. The chemiresistor sensor probe of claim 34 , further comprising a control unit in communication with each of said first terminal and said second terminal to monitor electrical properties of said sensor film, said control unit is operable to generate a first signal representing the presence or absence of the analytes.

36. The chemiresistor sensor probe of claim 35 , further comprising a user interface in communication with said control unit, said user interface operable to receive said first signal and generate a second signal representing the presence or absence of the analytes.

37. A chemiresistor sensor probe for detecting the presence of one or more analytes comprising:

a probe body;

a sensor film including a crosslinked polymeric matrix mounted at an exterior surface of said probe body; and

a first terminal having a first conductive mesh plate mounted directly to said first terminal and a second terminal having a second conductive mesh plate mounted directly to said second terminal, said first and said second mesh plates each in direct contact with said sensor film.

38. The chemiresistor sensor probe of claim 37 , further comprising a control unit in communication with each of said first terminal and said second terminal to monitor electrical properties of said sensor film, said control unit is operable to generate a first signal representing the presence or absence of the analytes.

39. The chemiresistor sensor probe of claim 38 , further comprising a user interface in communication with said control unit, said user interface operable to receive said first signal and generate a second signal representing the presence or absence of the analytes.

Assignments (10)
RELEASE OF SECURITY INTEREST Recorded Jun 9, 2026
From: MORGAN STANLEY SENIOR FUNDING, INC. AS COLLATERAL AGENT
To: THERM-O-DISC, INCORPORATED
Reel/Frame 075844/0075 →
RELEASE OF SECURITY INTEREST Recorded Jun 9, 2026
From: MORGAN STANLEY SENIOR FUNDING, INC. AS COLLATERAL AGENT
To: THERM-O-DISC, INCORPORATED
Reel/Frame 075844/0512 →
RELEASE OF SECURITY INTEREST Recorded Jun 5, 2026
From: ARGENT INSTITUTIONAL TRUST COMPANY
To: THERM-O-DISC, INCORPORATED
Reel/Frame 075697/0530 →
OMNIBUS ASSIGNMENT OF INTELLECTUAL PROPERTY SECURITY AGREEMENTS Recorded Nov 13, 2024
From: TOKEN FINANCE HOLDINGS, LLC, AS EXISTING AGENT
To: ARGENT INSTITUTIONAL TRUST COMPANY, AS SUCCESSOR AGENT
Reel/Frame 069351/0180 →
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Jan 31, 2024
From: THERM-O-DISC, INCORPORATED
To: TOKEN FINANCE HOLDINGS, LLC, AS COLLATERAL AGENT
Reel/Frame 066382/0576 →
SECURITY INTEREST Recorded May 31, 2022
From: THERM-O-DISC, INCORPORATED
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 060243/0871 →
SECURITY INTEREST Recorded May 31, 2022
From: THERM-O-DISC, INCORPORATED
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 061521/0328 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2003
From: STARLING, JARED; KHADKIKAR, PRASAD S.; STERKEN, ROBERT; VOLZ, CHARLES L.; BLOK, EDWARD J.
To: THERM-O-DISC, INCORPORATED
Reel/Frame 014316/0251 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2003
From: EMERSON ELECTRIC CO.
To: THERM-O-DISC, INCORPORATED
Reel/Frame 014316/0248 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2003
From: DONNELLY, DONALD E.
To: EMERSON ELECTRIC CO.
Reel/Frame 014316/0429 →
Continuity (1)
Related Publication 20040200722A1 · Oct 14, 2004