Pre-applied fluxing underfill composition having pressure sensitive adhesive properties
View Patent ↗The present invention relates to a pressure sensitive fluxing underfill composition that may be pre-applied to electronic components, such as CSP's, in order to increase the reliability of the component against mechanical stresses such as impact and bending. The composition contains an epoxy resin, a solid anhydride curing agent, and catalyst. Other materials, such as air release agents and fillers, may also be added as desired. The composition may be applied selectively to parts of the CSP, for example to the solder bumps. The composition provides sufficient tack in order to hold the electronic assembly together during the assembly process.
1. A pressure sensitive fluxable underfill encapsulant material comprising
a) at least one epoxy resin;
b) a solid anhydride curing agent, and
c) at least one catalyst,
wherein the catalyst is an imidazole-anhydride adduct comprising an adduct of imidazole and anhydride selected from the group comprising pyromellitic dianhydride, methylhexa-hydro phthalic anhydride. hexa-hydro phthalic anhydride, tetra-hydro phthalic anhydride, phthalic anhydride, bisphenyl dianhydride, benzophenone tetracarboxylic dianhydride, 1-cyanoethyl-2-ethyl-4-methyl-imidazole, alkyl-substituted imidazole, triphenylphosphine, onium borate, non-N-substituted imidazoles, 2-phenyl-4-methyl imidazole, 2-phenyl imidazole, imidazole, N-substituted imidazole and mixtures thereof and wherein the imidazole-anhydride adduct comprises in the range of about 0.01 wt % to about 10 wt % of the encapsulant.
2. The underfill encapsulant of claim 1 , wherein the underfill encapsulant is a tacky solid at room temperature.
3. The underfill encapsulant of claim 1 , wherein the at least one epoxy resin is selected from the group comprising monofunctional and multifunctional glycidyl ethers of Bisphenol-A, monofunctional and multifunctional glycidyl ethers of Bisphenol-F, aliphatic epoxies, aromatic epoxies, saturated epoxies, unsaturated epoxies, and cycloaliphatic epoxy resins.
4. The underfill encapsulant of claim 3 , wherein at least one epoxy resin is selected from the group consisting of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, vinylcyclohexene dioxide, 3,4-epoxy-6-methyl cyclohexyl methyl-3,4-epoxycyclohexane carboxylate, dicyclopentadiene dioxide, epoxy novolac resin, poly(phenyl glycidyl ether)-co-formaldehyde, biphenyl type epoxy resin, dicyclopentadiene-phenol epoxy resins, naphthalene epoxy resins, epoxy functional butadiene acrylonitrile copolymers, epoxy functional polydimethyl siloxane, and mixtures thereof.
5. The underfill encapsulant of claim 1 , wherein the at least one epoxy resin comprises in the range of about 30 wt % to about 98 wt % of the encapsulant.
6. The underfill encapsulant of claim 5 , wherein the epoxy resin comprises in the range of about 40 wt % to about 60 wt % of the encapsulant.
7. The underfill encapsulant of claim 1 , wherein the imidazole-anhydride adduct comprises an adduct of 2-phenyl-4-methyl imidazole and pyromelittic dianhydride.
8. The underfill encapsulant of claim 1 , wherein the imidazole or imidazole-anhydride adduct comprises in the range of about 0.1 wt % to about 5 wt % of the encapsulant.
9. The underfill encapsulant of claim 1 , wherein the catalyst is 2-phenylimidazole phosphate.
10. The underfill encapsulant of claim 9 , wherein the 2-phenylimidazole phosphate comprises in the range of about 0.01 wt % to about 10 wt % of the encapsulant.
11. The underfill encapsulant of claim 10 , wherein the 2-phenylimidazole phosphate comprises in the range of about 0.1 wt % to about 5 wt % of the encapsulant.
12. The underfill encapsulant of claim 1 , wherein the encapsulant further comprises one or more of group consisting of surfactants, coupling agents, reactive diluents, air release agents, flow additives, adhesion promoters and mixtures thereof.