Magnetic nanomaterials and synthesis method
View Patent ↗A magnetic nanoparticle ( 22 ), a magnetic nanomaterial ( 30 ), assembly ( 30 ), and a method for synthsising a magnetic nanoparticle, relating to thermodynamically stable and air stable ferromagnetic nanoparticles of adjustable aspect ratio made upon decomposition of organometallic precursors in solution in the presence of a reaction gas and a mixture of organic ligands. The magnetic nanomaterial comprises magnetic nanoparticles of homogeneous size, shape, and magnetic orientation that comprises a magnetic core ( 24, 34 ) ferromagnetic at room temperature and/or operating temperatures, and a non-magnetic matrix ( 26, 36 ) encapsulating the magnetic core. This magnetic nanomaterial could be used in high frequency integrated circuit applications, such as used in wireless portable electronic devices, to enchance magnetic field confinement and improve passive component performance at MHz and GHz frequency in a variety of passive and active devices, such as transformers, on-chip signal isolation, inductors, and the like.
1. A method for synthesising a magnetic nanomaterial comprising an assembly of magnetic nanoparticles comprising the steps of:
providing a first solution comprising a solvent with a carboxylic acid and an amine;
adding the first solution to a metal-organic precursor to form a second solution;
heating the second solution under pressure for a predetermined period to produce an assembly of thermodynamically stable magnetic nanoparticles each comprising a magnetic core that is ferromagnetic at a room temperature and/or an operating temperature between room temperature and 105°C., and a non-magnetic constituent encapsulating the magnetic core to make the magnetic nanoparticles protected against atmosphere contaminants and electrically isolated, the process conditions being adjusted so that the magnetic nanoparticles have a selected aspect ratio, and the nanomaterial having a permeability and ferromagnetic resonance suitable for use in MHz-GHz range frequencies.
2. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein the solvent in said first solution step comprises an ether.
3. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein the solvent in said first solution step comprises an aromatic solvent selected from the group consisting of toluene and anisole.
4. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein the carboxylic acid in said first solution step comprises an oleic acid.
5. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein the amine in said first solution step comprises an oleylamine.
6. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein the metal-organic precursor in said first solution step comprises a hydrocarbon metal complex.
7. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein said heating step comprises heating at temperatures between 100 and 250° C. for times between 3 and 60 hours under pressures between 1 and 10 Bars of H 2 or H 2 -containing gas mixtures.
8. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein said magnetic cores comprise a ferromagnetic element selected from the group consisting of Fe, Go, and Ni, and the metal-organic precursor in said first solution step comprises a precursor of the selected ferromagnetic element.
9. A method for synthesising a magnetic nanomaterial as claimed in claim 1 wherein said magnetic cores comprise a binary or tertiary alloy of ferromagnetic elements selected from the group consisting of Fe, Co, and Ni, and the metal-organic precursor in said first solution step comprises a precursor of the selected ferromagnetic elements.