Epoxy resin compositions, processes utilizing same and articles made therefrom

1. A process for preparing a resin coated article, the process comprising contacting a substrate with an accelerated resin composition comprising a brominated epoxy resin, a curing agent, and a cure accelerator compound;

wherein the cure accelerator compound is an alkali metal containing cure accelerator compound selected from the group consisting of an alkali metal containing hydroxide, an alkali metal containing alkoxide, an alkali metal containing phenoxide, an alkali metal containing carboxylate, an alkali metal containing halide salt, an alkali metal containing borate, an alkali metal containing bicarbonate, an alkali metal containing carbonate, an alkali metal containing chlorate, an alkali metal containing nitrate, an alkali metal containing phosphate, an alkali metal containing sulfate, an alkali metal containing sulfide, an alkali metal containing sulfite, an alkali metal containing polysulfide, an alkali metal containing thiocyanate, an alkali metal containing silicate, an alkali metal containing aluminate, an alkali metal containing phosphonate, an alkali metal containing sulfonate, an alkali metal containing cyanate, an alkali metal containing thiolate, an alkali metal containing thiophenoxide, an alkali metal containing thiocarboxylate, an alkali metal containing thiophosphate, an alkali metal containing imide salt, an alkali metal ion complexed with coordinating compounds, and combinations thereof;

wherein the curing agent consists essentially of dicyandiamide or a melamine;

wherein the brominated epoxy resin is derived from the reaction of an epihalohydrin and a phenol or a phenol type compound; and

wherein the contacting occurs by a contacting method.

2. The process of claim 1 wherein the accelerated resin composition further comprises one or more solvent(s).

3. The process of claim 1 wherein the accelerated resin composition is in powder, hot melt, solution or dispersion form.

4. The process of claim 1 wherein the contacting method is selected from the group consisting of powder coating, spray coating, die coating, roll coating, resin infusion and contacting the substrate with a bath comprising the accelerated resin composition.

5. The process of claim 1 wherein the substrate comprises a material selected from the group consisting of glass, fiberglass, quartz, paper, thermoplastic resin, an unwoven aramid reinforcement, carbon, graphite, ceramic, metal and combinations thereof.

6. The process of claim 1 wherein the article is a prepreg, wherein the substrate comprises a material selected from the group consisting of glass, fiberglass, quartz, paper, thermoplastic resin, an unwoven aramid reinforcement, carbon, graphite and combinations thereof, and wherein the contacting occurs in a bath comprising the accelerated resin composition and optionally one or more solvent(s).

7. The process of claim 6 wherein the substrate is glass or fiberglass in the form of a woven cloth or a mat.

8. The process of claim 1 wherein the alkali metal containing cure accelerator compound is selected from the group consisting of an alkali metal containing hydroxide, an alkali metal containing alkoxide, an alkali metal containing phenoxide, an alkali metal containing carboxylate, an alkali metal containing halide salt, an alkali metal containing carbonate and combinations thereof.

9. The process of claim 1 wherein the cure accelerator consists essentially of an alkali metal containing compound represented by the formula MOR or (MO) n —R wherein M is a metal selected from Group 1 of the Periodic Table of the Elements, O is oxygen, and R is hydrogen or a substituted or unsubstituted hydrocarbyl group.

10. The process of claim 9 wherein M is lithium, sodium or potassium, and R is hydrogen or a C1 to C40 hydrocarbyl group.

11. The process of claim 9 wherein OR represents a hydroxy, a methoxy, an ethoxy, an n-propoxy, an isopropoxy, an n-butoxy, an iso-butoxy, a sec-butoxy, a tert-butoxy, or a phenoxy group.

12. The process of claim 9 wherein the alkali metal containing compound is selected from the group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, sodium methoxide, potassium methoxide, lithium methoxide and combinations thereof.

13. The process of claim 1 wherein the alkali metal containing cure accelerator compound is utilized in an amount greater than 0.00001 molar equivalents per 100 grams of epoxy resin solids.

14. The process of claim 1 wherein the phenol or a phenol type compound is selected from the group consisting of bisphenols, halogenated bisphenols, hydrogenated bisphenols, novolac resins, polyalkylene glycols and combinations thereof.

15. A resin coated article prepared by the process of claim 1 .

16. A prepreg prepared by the process of claim 1 .

17. The process of claim 1 wherein the accelerated resin composition is free of imidazole cure accelerator.

18. A process for preparing a resin coated article, the process comprising contacting a substrate with an accelerated resin composition comprising a brominated epoxy resin, a curing agent, and a cure accelerator compound;

wherein the cure accelerator compound is an alkali metal containing cure accelerator compound selected from the group consisting of an alkali metal containing hydroxide, an alkali metal containing alkoxide, an alkali metal containing phenoxide, an alkali metal containing carboxylate, an alkali metal containing halide salt, an alkali metal containing borate, an alkali metal containing bicarbonate, an alkali metal containing carbonate, an alkali metal containing chlorate, an alkali metal containing nitrate, an alkali metal containing phosphate, an alkali metal containing sulfate, an alkali metal containing sulfide, an alkali metal containing sulfite, an alkali metal containing polysulfide, an alkali metal containing thiocyanate, an alkali metal containing silicate, an alkali metal containing aluminate, an alkali metal containing phosphonate, an alkali metal containing sulfonate, an alkali metal containing cyanate, an alkali metal containing thiolate, an alkali metal containing thiophenoxide, an alkali metal containing thiocarboxylate, an alkali metal containing thiophosphate, an alkali metal containing imide salt, an alkali metal ion complexed with coordinating compounds, and combinations thereof;

wherein the curing agent consists essentially of dicyandiamide;

wherein the brominated epoxy resin is derived from the reaction of an epihalohydrin and a phenol or a phenol type compound; and

wherein the phenol or phenol type compound is selected from the group consisting of dihydroxy phenols, biphenols, bisphenols, halogenated biphenols, halogenated bisphenols, hydrogenated bisphenols, alkylated biphenols, alkylated bisphenols, trisphenols, phenol-aldehyde resins, novolac resins, halogenated phenol-aldehyde novolac resins, substituted phenol-aldehyde novolac resins, phenol-hydrocarbon resins, substituted phenol-hydrocarbon resins, phenol hydroxybenzaldehyde resins, alkylated phenol-hydroxybenzaldehyde resins, hydrocarbon-phenol resins, hydrocarbon-halogenated phenol resins, hydrocarbon-alkylated phenol resins, and combinations thereof.

19. A process for preparing a resin coated article, the process comprising contacting a substrate with an accelerated resin composition consisting essentially of a brominated epoxy resin, a curing agent, and a cure accelerator compound;

wherein the cure accelerator compound is an alkali metal containing cure accelerator compound selected from the group consisting of an alkali metal containing hydroxide, an alkali metal containing alkoxide, an alkali metal containing phenoxide, an alkali metal containing carboxylate, an alkali metal containing halide salt, an alkali metal containing borate, an alkali metal containing bicarbonate, an alkali metal containing carbonate, an alkali metal containing chlorate, an alkali metal containing nitrate, an alkali metal containing phosphate, an alkali metal containing sulfate, an alkali metal containing sulfide, an alkali metal containing sulfite, an alkali metal containing polysulfide, an alkali metal containing thiocyanate, an alkali metal containing silicate, an alkali metal containing aluminate, an alkali metal containing phosphonate, an alkali metal containing sulfonate, an alkali metal containing cyanate, an alkali metal containing thiolate, an alkali metal containing thiophenoxide, an alkali metal containing thiocarboxylate, an alkali metal containing thiophosphate, an alkali metal containing imide salt, an alkali metal ion complexed with coordinating compounds, and combinations thereof;

wherein the curing agent is dicyandiamide or a melamine;

wherein the brominated epoxy resin is derived from the reaction of an epihalohydrin and a phenol or a phenol type compound; and

wherein the phenol or phenol type compound is selected from the group consisting of bisphenols, halogenated bisphenols, hydrogenated bisphenols, novolac resins, and combinations thereof.

20. A process for preparing a resin coated article, the process comprising contacting a substrate with an accelerated resin composition consisting essentially of a brominated epoxy resin, a curing agent, and a cure accelerator compound;

wherein the cure accelerator compound is an alkali metal hydroxide;

wherein the curing agent is dicyandiamide;

wherein the brominated epoxy resin is derived from the reaction of an epihalohydrin and a phenol or a phenol type compound; and

wherein the phenol or phenol type compound is selected from the group consisting of resorcinol, catechol, hydroquinone, biphenol, bisphenol A, bisphenol AP, bisphenol F, bisphenol K, tetrabromobisphenol A, phenol-formaldehyde novolac resins, alkyl substituted phenol-formaldehyde resins, phenol-hydroxybenzaldehyde resins, cresol-hydroxybenzaldehyde resins, dicyclopentadiene-phenol resins, dicyclopentadiene-substituted phenol resins, tetramethylbiphenol, tetramethyl-tetrabromobiphenol, tetramethyltribromobiphenol, tetrachlorobisphenol A and combinations thereof.