IP Library Granted Patent US 6,933,227
Granted Patent B2
US 6,933,227 · App. 10/691,984 · Granted Aug 23, 2005

Semiconductor device and method of forming the same

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Quick Facts
Patent No.
US 6,933,227
App. No.
10/691,984
Granted
Aug 23, 2005
Kind
B2
Abstract

A process for forming a semiconductor structure includes forming a gate dielectric overlying a substrate, a conductive gate electrode overlying the gate dielectric, a barrier layer overlying and in physical contact with the conductive gate electrode, and an organic anti-reflective coating (ARC) layer overlying and in physical contact with the barrier layer.

Claims (23)

1. A process for forming a semiconductor structure comprising: forming a gate dielectric overlying a substrate, a conductive gate electrode overlying the gate dielectric, a barrier layer overlying and in physical contact with the conductive gate electrode, and an organic anti-reflective coating (ARC) layer overlying and in physical contact with the barrier layer, wherein forming comprises forming a masking layer overlying the organic ARC layer, further comprising removing the masking layer and the organic ARC layer, wherein forming further comprises forming an oxygen-containing layer between the organic ARC layer and the masking layer, and wherein removing further comprises removing the masking layer, the oxygen-containing layer, and the organic ARC layer.

2. The process of claim 1 , further comprising removing the barrier layer.

3. The process of claim 1 , wherein the conductive gate electrode comprises a metal.

4. The process of claim 1 , wherein the conductive gate electrode comprises polysilicon.

5. The process of claim 1 , wherein the barrier layer has a thickness in a range of approximately 20 Angstroms to 500 Angstroms.

6. The process of claim 1 , wherein the organic ARC layer comprises carbon.

7. The process of claim 3 , wherein the barrier layer is further characterized as an oxygen resistant barrier layer.

8. The process of claim 3 , wherein the barrier layer comprises at least one of silicon and nitrogen.

9. The process of claim 3 , wherein the barrier layer comprises a metal whose oxides are conductive.

10. The process of claim 3 , wherein the barrier layer comprises amorphous silicon.

11. The process of claim 8 , wherein the barrier layer comprises silicon and nitrogen.

12. A process for forming a semiconductor structure comprising: forming a gate dielectric overlying a substrate, a conductive gate electrode overlying the gate dielectric, a barrier layer overlying and in physical contact with the conductive gate electrode, and an organic anti-reflective coating (ARC) layer overlying and in physical contact with the barrier layer, wherein the conductive gate electrode comprises a metal and wherein the barrier layer comprises a metal selected from a group consisting of iridium, ruthenium, and platinum.

13. A process for forming a semiconductor structure, comprising: forming a gate dielectric layer overlying a substrate; forming a metal gate electrode layer overlying the gate dielectric layer; forming a barrier layer overlying the metal gate electrode layer; forming a carbon-containing ARC layer overlying the barrier layer; forming a patterned masking layer overlying the carbon-containing ARC layer; removing portions of the gate dielectric layer, the metal gate electrode layer, the barrier layer, and the carbon-containing ARC layer using the patterned masking layer to form an intermediate gate stack; and removing the masking layer and the carbon-containing ARC layer from the intermediate gate stack to form a gate stack, wherein removing the masking layer and the carbon-containing ARC layer is performed in an oxygen and plasma environment.

14. The process of claim 13 , wherein during removal of the masking layer and the carbon-containing ARC layer in the oxygen and plasma environment, the barrier layer retards oxygen from diffusing into the metal gate electrode layer of the intermediate gate stack.

15. The process of claim 13 , further comprising: forming spacers adjacent to each sidewall of the gate stack; and forming source and drain regions in the substrate, underlying at least a potion of the spacers and the gate stack.

16. The process of claim 15 , further comprising: removing the barrier layer from the gate stack; and saliciding the source and drain regions.

17. The process of claim 16 , wherein removing the barrier layer is performed after saliciding the source and drain regions.

18. The process of claim 13 , wherein the barrier layer is characterized as one of an oxygen resistant and an oxygen absorbing layer.

19. The process of claim 13 , wherein the barrier layer comprises at least one of silicon and nitrogen.

20. The process of claim 13 , wherein the barrier layer comprises at least one selected from the group consisting of a non-conductive oxygen resistant layer, a conductive oxygen resistant layer, and a conductive oxygen-absorbing layer.

21. The process of claim 13 , wherein the barrier layer is in direct physical contact with the metal gate electrode layer, and the carbon-containing ARC layer is in direct physical contact with the barrier layer.

22. The process of claim 21 , wherein the barrier layer has a thickness in a range of approximately 20 Angstroms to 500 Angstroms.

23. The processing of claim 13 , further comprising forming an oxygen-containing layer overlying the carbon-containing ARC layer, wherein the pattern masking layer is formed overlying the oxygen-containing layer, and wherein removing further comprises removing portions of the oxygen-containing layer to form the intermediate gate stack.

Assignments (17)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE LISTED CHANGE OF NAME SHOULD BE MERGER AND CHANGE PREVIOUSLY RECORDED AT REEL: 040652 FRAME: 0180. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Jan 12, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 041354/0148 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 040652/0180 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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