Method of manufacturing dual gate oxide film
View Patent ↗The present invention is provided to manufacture a dual gate oxide film. According to the present invention, it is possible to obtain a high-quality NO gate oxide film for high voltage and a high-quality NO gate oxide film for low voltage where nitrogen is distributed uniformly in the entire oxide films by carrying out a rapid annealing process in an inert atmosphere after carrying out an NO annealing process in order to prevent a phenomenon that nitrogen is not distributed uniformly and segregated in a gate oxide film for high voltage due to application of the NO annealing process after forming a gate oxide film for low voltage.
1. A method of manufacturing a dual gate oxide film, comprising the steps of:
forming a first gate oxide film having a first thickness on a semiconductor substrate in which a high-voltage driving element region and a low-voltage driving element region are defined;
leaving the first gate oxide film only on the semiconductor substrate of the high-voltage driving element region;
forming a second gate oxide film having a thickness less than the first thickness on the semiconductor substrate of the low-voltage driving element region including the first gate oxide film;
carrying out an NO annealing process to diffuse nitrogen into the first and the second gate oxide films; and
carrying out a rapid annealing process to distribute the nitrogen uniformly in the first and the second gate oxide films, thereby forming an NO gate oxide film for a high voltage and an NO gate oxide film for a low voltage.
2. The method of manufacturing a dual gate oxide film according to claim 1 , wherein the first gate oxide film is formed using a pure oxide at an oxidation temperature of 750° C. to 850° C. to have a thickness of 300 Å to 500 Å.
3. The method of manufacturing a dual gate oxide film according to claim 1 , wherein the first gate oxide film is formed using an H 2 /O 2 /N 2 gas at an oxidation temperature of 750° C. to 850° C. to have a thickness of 300 Å to 500 Å, and then an N 2 annealing process is carried out thereto.
4. The method of manufacturing a dual gate oxide film according to claim 1 , wherein the second gate oxide film is formed using a pure oxide at an oxidation temperature of 750° C. to 850° C. to have a thickness of 60 Å to 100 Å.
5. The method of manufacturing a dual gate oxide film according to claim 1 , further comprising a step of carrying out an oxidation pre-cleaning process before the step of forming the second gate oxide film.
6. The method of manufacturing a dual gate oxide film according to claim 5 , wherein the oxidation pre-cleaning process is performed for 30 to 100 seconds, and a recipe thereof is composed of 50:1 to 100:1 (HF:H 2 O) HF+N(NH 4 OH:H 2 O 2 :H 2 O=1:4:20,25° C.).
7. The method of manufacturing a dual gate oxide film according to claim 5 , wherein the oxidation pre-cleaning process is carried out using a 100:1 to 300:1 BOE cleaning method.
8. The method of manufacturing a dual gate oxide film according to claim 1 , wherein the NO annealing process is carried out in-situ after the step of forming the second gate oxide film.
9. The method of manufacturing a dual gate oxide film according to claim 1 , wherein the rapid annealing process is carried out at a temperature of 500 ° C. to 700°C. for 15 to 50 seconds, in an inert atmosphere of argon.