IP Library Granted Patent US 7,235,471
Granted Patent B2
US 7,235,471 · App. 10/854,389 · Granted Jun 26, 2007

Method for forming a semiconductor device having a silicide layer

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,235,471
App. No.
10/854,389
Granted
Jun 26, 2007
Kind
B2
Abstract

A method for forming a semiconductor device includes providing a semiconductor substrate, forming an insulating layer over the semiconductor substrate, forming a conductive layer over the insulating layer, forming a first metal silicide layer over the conductive layer, patterning the conductive layer to form a patterned first layer, wherein the patterned first layer is a part of a control electrode, patterning the first metal silicide layer to form a patterned first metal silicide layer over the control electrode so that the patterned first metal silicide layer remains over the control electrode, and forming a second metal silicide over the patterned metal silicide layer, wherein the second metal silicide layer has a thickness greater than the thickness of first metal silicide layer.

Claims (45)

1. A method for forming a semiconductor device, the method comprising;

providing a semiconductor substrate;

forming an insulating layer over the semiconductor substrate;

forming a conductive layer over the insulating layer;

forming a first metal silicide layer over the conductive layer by performing an anneal and implanting nitrogen into the first metal silicide layer, wherein the first metal silicide has a first thickness;

patterning the conductive layer to form a patterned first layer, wherein the patterned first layer is at least a part of a control electrode;

patterning the first metal silicide layer to form a patterned first metal silicide layer over the control electrode so that the patterned first metal silicide layer remains over the control electrode; and

forming a second metal silicide over the patterned metal silicide layer, wherein the second metal silicide layer comprises the first metal silicide layer, the second metal silicide layer has a second thickness, and the second thickness of the second metal silicide layer is greater than the first thickness of first metal silicide layer.

2. The method of claim 1 , wherein the first thickness is less than approximately 25 nanometers and the second thickness is less than approximately 40 nanometers.

3. The method of claim 1 , wherein forming a first metal silicide layer comprises forming a first metal silicide layer selected from the group consisting of nickel silicide, cobalt silicide and titanium silicide.

4. The method of claim 3 , wherein the second metal silicide consists of the same material.

5. The method of claim 3 , wherein the second metal silicide consists of different materials.

6. The method of claim 1 , wherein forming the second metal silicide layer further comprises depositing a third metal silicide layer over the first metal silicide layer using a process selected from the group consisting of chemical vapor deposition (CVD) and atomic layer deposition (ALD).

7. The method of claim 1 , wherein forming the second metal silicide layer further comprises:

sputtering a metal layer on the first layer;

performing a first anneal at a first temperature; and

performing a second anneal at a second temperature, wherein the second temperature is greater than the first temperature.

8. A method for forming a semiconductor device, the method comprising:

providing a semiconductor substrate;

forming an insulating layer over the semiconductor substrate;

forming a polysilicon layer over the insulating layer;

forming a first metal silicide layer over the polysilicon layer by performing an anneal and implanting nitrogen into the first metal silicide layer, wherein the first metal silicide layer comprises silicon and one of cobalt and nickel;

patterning the first metal silicide layer and the polysilicon layer;

forming a second metal silicide over the patterned metal silicide layer, wherein the second metal silicide and the first metal silicide form a combined metal silicide region.

9. The method of claim 8 , wherein the second metal silicide is a different material than the first metal silicide.

10. The method of claim 8 , wherein the second metal silicide is a same material as the first metal silicide.

11. The method of claim 8 , wherein forming the first metal silicide layer over the first layer further comprises depositing the first metal silicide layer using a process selected from the group consisting of chemical vapor deposition (CVD) and atomic layer deposition (ALD).

12. The method of claim 8 , wherein forming the first metal silicide layer over the first layer further comprises:

sputtering a metal layer on the first layer;

performing a first anneal at a first temperature; and

performing a second anneal at a second temperature, wherein the second temperature is greater than the first temperature.

13. The method of claim 12 , wherein forming the second metal silicide layer further comprises implanting nitrogen into the second metal silicide layer.

14. The method of claim 8 , wherein the first metal silicide layer has a first thickness and the combined metal silicide region has a second thickness, wherein the first thickness is less than the second thickness.

15. The method of claim 14 , wherein the first thickness is less than approximately 25 nanometers and the second thickness is less than approximately 40 nanometers.

16. A method of forming a semiconductor device, the method comprising:

providing a semiconductor substrate;

forming a gate electrode stack over the semiconductor substrate, wherein the gate electrode stack comprises a top layer comprising silicon;

forming a first metal silicide layer over the top layer by performing an anneal and implanting nitrogen into the first metal silicide layer, wherein the first metal silicide layer comprises one of nickel and cobalt;

patterning the gate electrode stack to form a gate electrode, wherein patterning the gate electrode stack comprises patterning the metal layer to form at least a part of the gate electrode;

patterning the first metal silicide layer over the gate electrode stack to form a patterned first metal silicide layer;

doping the semiconductor substrate laterally adjacent the gate electrode to form active regions; and

forming a second metal silicide layer over on the first metal silicide layer and the active regions.

17. The method of claim 16 , wherein the gate electrode stack consists of the top layer.

18. The method of claim 17 , wherein the gate electrode stack further comprises a bottom layer, wherein the bottom layer comprises a metal.

19. The method of claim 1 , wherein forming the first metal silicide layer over the conductive layer further comprises depositing the first metal silicide layer using a process selected from the group consisting of chemical vapor deposition (CVD) and atomic layer deposition (ALD).

Assignments (23)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE LISTED CHANGE OF NAME SHOULD BE MERGER AND CHANGE PREVIOUSLY RECORDED AT REEL: 040652 FRAME: 0180. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Jan 12, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 041354/0148 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 040652/0180 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0655 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded May 13, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024397/0001 →
SECURITY AGREEMENT Recorded Nov 1, 2007
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 020045/0448 →
SECURITY AGREEMENT Recorded Feb 2, 2007
From: FREESCALE SEMICONDUCTOR, INC.; FREESCALE ACQUISITION CORPORATION; FREESCALE ACQUISITION HOLDINGS CORP.; FREESCALE HOLDINGS (BERMUDA) III, LTD.
To: CITIBANK, N.A. AS COLLATERAL AGENT
Reel/Frame 018855/0129 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 26, 2004
From: JAWARANI, DHARMESH; STEPHENS, TAB A.
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 015396/0442 →