IP Library Granted Patent US 7,119,015
Granted Patent B2
US 7,119,015 · App. 10/879,220 · Granted Oct 10, 2006

Method for forming polysilicon plug of semiconductor device

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Quick Facts
Patent No.
US 7,119,015
App. No.
10/879,220
Granted
Oct 10, 2006
Kind
B2
Abstract

Disclosed is a method for forming a polysilicon plug of a semiconductor device. The method comprises the steps of: forming a stacked pattern of a wordline and a hard mask film on a semiconductor substrate comprising a cell region and a peripheral circuit region; forming a spacer on a sidewall of the stacked pattern; forming an interlayer insulating film on the semiconductor substrate; polishing the interlayer insulating film via a CMP process using the hard mask film as a polishing barrier film; forming a barrier film on the semiconductor substrate including the interlayer insulating film; selectively etching the barrier film and the interlayer insulating film to form a landing plug contact hole; depositing a polysilicon film filling the landing plug contact hole on the semiconductor substrate; blanket-etching the polysilicon film using the barrier film as an etching barrier film; and polishing the polysilicon film and the barrier film using the hard mask film as a polishing barrier film to form a polysilicon plug.

Claims (45)

1. A method for forming a polysilicon plug of a semiconductor device, comprising the steps of:

(a) forming a stacked pattern of a wordline and a hard mask film on a semiconductor substrate comprising a cell region and a peripheral circuit region;

(b) forming a spacer on a sidewall of the stacked pattern;

(c) forming an interlayer insulating film on the semiconductor substrate;

(d) polishing the interlayer insulating film via a CMP process until the hard mask film is exposed to planarize an entire surface of the resulting structure;

(e) forming a barrier film on the planarized entire surface of the exposed hard mask film and the interlayer insulating film;

(f) selectively etching the barrier film and the interlayer insulating film to form a landing plug contact hole;

(g) depositing a polysilicon film filling the landing plug contact hole on the semiconductor substrate;

(h) blanket-etching the polysilicon film using the barrier film as an etching barrier film; and

(i) polishing the polysilicon film and the barrier film using the hard mask film as a polishing barrier film to form a polysilicon plug.

2. The method according to claim 1 , wherein the wordline comprises a film selected from a group consisting of a polysilicon film, a doped polysilicon film, a WSi x film, a WN film, a W film and TiSi x film.

3. The method according to claim 1 , wherein the hard mask film comprises a Si 3 N 4 film formed via a LP-CVD (low pressure chemical vapor deposition) method using SiH 2 Cl 2 and NH 3 as a source or via a PE-CVD (plasma enhanced chemical vapor deposition) method using SiH 4 and NH 3 as a source.

4. The method according to claim 1 , wherein a thickness of the hard mask film ranges from 300 to 3000 Å.

5. The method according to claim 1 , wherein the spacer comprises as a stacked structure of nitride film and oxide film.

6. The method according to claim 1 , wherein the interlayer insulating film is selected from a group consisting of a BPSG (boron phosphorous silicate glass) oxide film, a PSG (phosphorous silicate glass) oxide film, an APL (advanced planarization layer) oxide film, an ALD (atomic layer deposition) oxide film and a SOD (spin on dielectric) oxide film.

7. The method according to claim 1 , wherein the interlayer insulating film ranges from 1.1 to 5 times in thickness of the stacked pattern.

8. The method according to claim 1 , wherein the step (d) is performed using a slurry for oxide film, the sluny having a pH ranging from 8 to 12 and containing an abrasive having a particle size ranging from 10 to 800 nm.

9. The method according to claim 8 , wherein the abrasive is selected from a group consisting of SiO 2 , CeO 2 , Al 2 O 3 , ZrO 2 and combinations thereof.

10. The method according to claim 1 , wherein the step (d) is performed using a slurry, the slurry having a pH ranging from 4 to 10, oxide film to nitride film polishing selectivity of 1˜500:1 and containing an abrasive having a particle size ranging from 10 to 800 nm.

11. The method according to claim 10 , wherein the abrasive is selected from a group consisting of SiO 2 , CeO 2 , Al 2 O 3 , ZrO 2 and combinations thereof.

12. The method according to claim 1 , wherein the step (d) comprises: (1) a first CMP process using a slurry for an oxide film, the slurry having a pH ranging from 8 to 12 and containing an abrasive having a particle size ranging from 10 to 800 nm to remove 0.1˜99.9% of thickness of the interlayer insulating film on the hard mask film, and (2) a second CMP process using a slurry, the sluny having a pH ranging from 4 to 10, oxide film to nitride film polishing selectivity of 1˜500:1 and containing an abrasive having a particle size ranging from 10 to 800 nm to remove the remaining portion of the interlayer insulating film.

13. The method according to claim 12 , wherein the abrasive is selected from a group consisting of SiO 2 , CeO 2 , Al 2 O 3 , ZrO 2 and combinations thereof.

14. The method according to claim 1 , wherein the step (d) is performed using a sluny having a pH ranging from 1 to 9 and containing a colloidal silica to expose the hard mask film on the cell region.

15. The method according to claim 1 , wherein the step (d) comprises performing a CMP process to polish a predetermined thickness of the interlayer insulating film, and blanket-etching a remaining portion of the interlayer insulating film to expose the hard mask film.

16. The method according to claim 1 , wherein the step (d) comprises performing a CMP process to polish a predetermined thickness of the interlayer insulating film, and blanket-etching and a wet-etching a remaining portion of the interlayer insulating film to expose the hard mask film.

17. The method according to claim 1 , wherein the barrier film is selected from a group consisting of a polysilicon film, a Si 3 N 4 film, a SiO x N y film, a tungsten film and a tungsten alloy film.

18. The method according to claim 1 , wherein the step (f) comprises:

(i) forming a photoresist film pattern on the barrier film;

(ii) selectively etching the barrier film using the photoresist film pattern as an etching mask to form a barrier film pattern;

(iii) removing the photoresist film pattern; and

(iv) performing a SAC process using the barrier film pattern as an etching mask to form the landing plug contact hole.

19. The method according to claim 18 , wherein the steps (i) through (iv) are performed in-situ in a single chamber.

20. The method according to claim 18 , wherein the steps (i) through (iii) are performed in a first chamber, and the step (iv) is performed in a second chamber.

21. The method according to claim 18 , wherein the step (iv) is performed using a gas selected from a group consisting of C 4 F 8 , C 4 F 6 and C 5 F 8 as a source.

22. The method according to claim 1 , wherein the polysilicon film is formed via an in-situ doping process or a SEG (Selective Epitaxial Growing) process.

23. The method according to claim 1 , wherein a thickness of the polysilicon film ranges from 1000 to 10000 Å.

24. The method according to claim 1 , wherein the step (i) comprises a CMP process employing a slurry for oxide film, the slurry having a pH ranging from 8 to 12 and containing an abrasive having a particle size ranging from 10 to 800 nm.

25. The method according to claim 24 , wherein the abrasive is selected from a group consisting of SiO 2 , CeO 2 , Al 2 O 3 , ZrO 2 and combinations thereof.

26. The method according to claim 1 , wherein the step (i) comprises a CMP process employing a slurry, the slurry having a pH ranging from 4 to 10, an oxide film to nitride film polishing selectivity of 1˜500:1 and containing an abrasive having a particle size ranging from 10 to 800 nm.

27. The method according to claim 26 , wherein the abrasive is selected from a group consisting of SiO 2 , CeO 2 , Al 2 O 3 , ZrO 2 and combinations thereof.

28. The method according to claim 1 , wherein the step (i) comprises (1) a first CMP process using a slurry for oxide film to remove predetermined thickness of the polysilicon film, and (2) a second CMP process performed using a slurry having an oxide film to nitride film polishing selectivity of 1˜500:1 to expose the hard mask film on the cell region.

29. The method according to claim 1 , wherein the step (i) comprises (1) a first CMP process using a slurry for polysilicon film to remove predetermined thickness of the polysilicon film, and (2) a second CMP process performed using a slurry having an oxide film to nitride film polishing selectivity of 1˜500:1 to expose the hard mask film on the cell region.

30. The method according to claim 1 , wherein the step (i) comprises (1) a first CMP process is using a slurry for oxide film to remove predetermined thickness of the polysilicon film, and (2) a second CMP process is performed using a slurry for oxide film to expose the hard mask film on the cell region.

31. The method according to claim 1 , wherein the step (i) is performed using a slurry of having a pH ranging from 1 to 9 and containing a colloidal silica to expose the hard mask film on the cell region.

32. The method according to claim 1 , further comprising, after the step (d) or (i), a post cleaning process using NH 3 , HF or SC-1(NH 4 OH+H 2 O 2 +H 2 O).

Assignments (8)
RELEASE OF U.S. PATENT AGREEMENT (FOR NON-U.S. GRANTORS) Recorded Oct 12, 2018
From: ROYAL BANK OF CANADA, AS LENDER
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U.S. PATENT SECURITY AGREEMENT (FOR NON-U.S. GRANTORS) Recorded Sep 9, 2014
From: CONVERSANT IP N.B. 868 INC.
To: CPPIB CREDIT INVESTMENTS INC., AS LENDER; ROYAL BANK OF CANADA, AS LENDER
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RELEASE OF SECURITY INTEREST Recorded Aug 7, 2014
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To: CONVERSANT INTELLECTUAL PROPERTY MANAGEMENT INC.; CONVERSANT IP N.B. 868 INC.; CONVERSANT IP N.B. 276 INC.
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CHANGE OF NAME Recorded Mar 13, 2014
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U.S. INTELLECTUAL PROPERTY SECURITY AGREEMENT (FOR NON-U.S. GRANTORS) - SHORT FORM Recorded Jan 10, 2012
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ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2011
From: HYNIX SEMICONDUCTOR INC.
To: 658868 N.B. INC.
Reel/Frame 027234/0693 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2004
From: PARK, HYUNG SOON; LEE, MIN SUK; LEE, SANG ICK; SOHN, HYUN CHUL
To: HYNIX SEMICONDUCTOR INC.
Reel/Frame 015531/0333 →