Low dielectric materials and methods for making same
View Patent ↗Low dielectric materials and films comprising same have been identified for improved performance when used as interlevel dielectrics in integrated circuits as well as methods for making same. These materials are characterized as having a dielectric constant (κ) a dielectric constant of about 3.7 or less; a normalized wall elastic modulus (E 0 ′), derived in part from the dielectric constant of the material, of about 15 GPa or greater; and a metal impurity level of about 500 ppm or less. Low dielectric materials are also disclosed having a dielectric constant of less than about 1.95 and a normalized wall elastic modulus (E 0 ′), derived in part from the dielectric constant of the material, of greater than about 26 GPa.
1. A process for forming a low dielectric film having a dielectric constant of about 3.7 or less and a normalized wall elastic modulus (E 0 ′), derived in part from the dielectric constant of the material, of about 15 GPa or greater, the process comprising:
providing a mixture comprising a product from the hydrolysis and condensation of at least one silica source and at least one porogen wherein the mixture has a metal impurity content of about 500 ppm or less;
dispensing the mixture onto a substrate to form a coated substrate; and
curing the coated substrate to one or more temperatures and for a time sufficient to form the dielectric film.
2. The process of claim 1 wherein the porogen is selected from the group consisting of labile organic groups, solvents, thermally decomposable polymers, surfactants, dendrimers, hyper branched polymers, polyoxyalkylene compounds, small molecules, or combinations thereof.
3. The process of claim 2 wherein the porogen is selected from the group of polyoxyalkylene compounds consisting of polyoxyalkylene non-ionic surfactants, polyoxyalkylene polymers, polyoxyalkylene copolymers, polyoxyalkylene oligomers or combinations thereof.
4. The process of claim 1 wherein the at least one silica source is selected from the group of compounds represented by the following formulas:
i. R a Si(OR 1 ) 4-a , wherein R represents a hydrogen atom, a fluorine atom, or a monovalent organic group; R 1 represents a monovalent organic group; and a is an integer of 1 or 2;
ii. Si(OR 2 ) 4 , where R 2 represents a monovalent organic group;
iii. R 3 b (R 4 O) 3-b Si—(R 7 ) d —Si(OR 5 ) 3-c R 6 c , wherein R 3 to R 6 may be the same or different and each represents a monovalent organic group; b and c may be the same or different and each is a number of 0 to 2; R 7 represents an oxygen atom, a phenylene group, or a group represented by —(CH 2 ) n —, wherein n is an integer of 1 to 6; and d is 0 or 1; or combinations thereof.
5. The process of claim 1 wherein the mixture further comprises a catalyst.
6. The process of claim 1 wherein the mixture further comprises a surfactant.
7. The process of claim 1 wherein the mixture further comprises a solvent.
8. The process of claim 1 wherein the curing step is conducted at a temperature no greater than 450° C.
9. The process of claim 8 wherein the curing step is conducted at a temperature no greater than 400° C.
10. The process of claim 1 wherein the curing step is conducted for a time no greater than about 30 minutes.
11. The process of claim 10 wherein the curing step is conducted for a time of no greater than 15 minutes.
12. The process of claim 11 wherein the curing step is conducted for a time of no greater than 6 minutes.
13. The process of claim 1 wherein the dispensing step involves non-contact induced spreading forces.
14. The process of claim 13 wherein the dispensing step involves spin coating.
15. The process of claim 1 wherein the dispensing step involves one or more processes selected from the group consisting of oscillating non-contact induced spreading forces, gravity-induced spreading forces, wetting-induced spreading forces, or combinations thereof.
16. The process of claim 1 wherein the mixture has a metal impurity content of about 100 ppb or less.
17. The process of claim 16 wherein the mixture has a metal impurity content of about 10 ppb or less.
18. The process of claim 1 wherein the mixture further comprises an ionic additive.
19. The film formed by the process of claim 1 .
20. The film of claim 19 wherein the film has a metal impurity content of about 500 ppm or less.
21. A process for forming a film with a low dielectric constant, the process comprising:
providing a first film made from a mixture comprising at least one porogen and a product from the hydrolysis and condensation of at least one silica source;
measuring the elastic modulus value and the dielectric constant value of the first film;
calculating a void fraction value of the first film from the dielectric constant using a Maxwell equation;
determining the normalized wall elastic modulus of the first film from the elastic modulus and the calculated void fraction values; and
adjusting the void fraction for a second film to increase or decrease the elastic modulus of the second film wherein the increased or decreased elastic modulus results is accompanied by an increase or a decrease in the dielectric constant of the second film, the second film having substantially the same normalized elastic modulus as the first film.
22. The process of claim 21 wherein the mixture further comprises a surfactant.
23. The process of claim 22 wherein the adjusting comprises varying the amount of the surfactant in the mixture.
24. The process of claim 21 wherein the mixture further comprises a solvent.
25. The process of claim 24 wherein the adjusting comprises varying the amount of the solvent in the mixture.
26. A process for forming a low dielectric film having a dielectric constant of about 3.7 or less and a normalized wall elastic modulus (E 0 ′), derived in part from the dielectric constant of the material, of about 15 GPa or greater, the process comprising:
providing a mixture comprising a product from the hydrolysis and condensation of at least one silica source and at least one porogen;
dispensing the mixture onto a substrate to form a coated substrate; and
curing the coated substrate to one or more temperatures no greater than 450° C. and for a time sufficient to form the dielectric film.
27. A process for forming a low dielectric film having a dielectric constant of about 2.0 or less and a normalized wall elastic modulus (E 0 ′), derived in part from the dielectric constant of the material, that ranges between about 5 GPa and about 15 GPa, the process comprising:
providing a mixture comprising a product from the hydrolysis and condensation of at least one silica source and at least one porogen;
dispensing the mixture onto a substrate to form a coated substrate; and
curing the coated substrate to one or more temperatures and for a time sufficient to form the dielectric film.