Polishing slurry, method of producing same, and method of polishing substrate
View Patent ↗Disclosed herein is a polishing slurry for chemical mechanical polishing. The polishing slurry comprises polishing particles, which have a particle size distribution including separated fine and large polishing particle peaks. The polishing slurry also comprises polishing particles, which have a median size of 50-150 nm. The present invention provides the slurry having an optimum polishing particle size, in which the polishing particle size is controlled and which is useful to produce semiconductors having fine design rules by changing the production conditions of the slurry. The present invention also provides the polishing slurry and a method of producing the same, in which a desirable CMP removal rate is assured and scratches are suppressed by controlling a polishing particle size distribution, and a method of polishing a substrate.
1. A polishing slurry comprising:
polishing particles comprising:
a plurality of grains;
a plurality of primary particles formed from agglomeration of one or more of the plurality of grains; and
a plurality of secondary particles formed from agglomeration of one or more of the plurality of primary particles,
wherein the secondary particles have a median size of 50-450 nm, the primary particles have a median size of 10-300 nm and the grains have a median size of 10-150 nm, and
wherein the polishing particles have a particle size distribution including separated first and second polishing particle peaks representing a first group of polishing particles having a first median particle size and a second group of polishing particles having a second median particle size greater than the first median particle size, respectively, a ratio of an area of the first particle peak to an area of the second particle peak is 2.85 to 25.
2. The polishing slurry as set forth in claim 1 , wherein an area ratio of the first polishing particle peak to the second polishing particle peak is 3-16.
3. The polishing slurry as set forth in claim 1 , wherein an area ratio of the first polishing particle peak to the second polishing particle peak is 3-9.
4. The polishing slurry as set forth in claim 1 , wherein the polishing particles are ceria.
5. The polishing slurry as set forth in claim 1 , further comprising deionized water and an anionic polymer compound.
6. The polishing slurry as set forth in claim 5 , wherein the anionic polymer compound is selected from the group consisting of polymethacrylic acid, ammonium polymethacrylate, polycarboxylate, sodium dodecylsulfate, alkylbenzenesulfonate, alpha-olefinsulfonate, sodium salt of monoalkyl phosphate or fatty acid, carboxyl-acryl polymer, and any combination thereof.
7. The polishing slurry as set forth in claim 5 , wherein the polishing slurry comprises 0.0001-10 wt % anionic polymer compound.
8. The polishing slurry as set forth in claim 5 , wherein the anionic polymer compound includes a polymer having a molecular weight of 2,000-50,000 g/mol.
9. The polishing slurry as set forth in claim 1 , further comprising a weak acid, organic acid, or weak base.
10. The polishing slurry as set forth in claim 1 , wherein the primary particles have a median size of 50-300 nm and the grains have a median size of 50-150 nm.
11. The polishing slurry as set forth in claim 1 , wherein the primary particles have a median size of 10-120 nm and the grains have a median size of 10-100 nm.