Method of reducing delamination
A method of reducing freeze-thaw delamination of electrode layers from the electrolyte membranes in a fuel cell is disclosed. The method comprises reducing the water content of the MEA to or below 80 percent of saturation prior to exposing the MEA to freezing conditions. Most preferably the water content of the MEA is reduced to or below about 40 percent of saturation.
1 . A method of reducing freeze-thaw delamination of electrode layers from the electrolyte membranes in a fuel cell comprising reducing the water content of the MEA to or less than about 80 percent of saturation prior to exposing the MEA to freezing conditions.
2 . A method as set forth in claim 1 wherein the water content of the MEA is reduced to or less than about 70 percent of saturation.
3 . A method as set forth in claim 1 wherein the water content of the MEA is reduced to or less than about 50 percent of saturation.
4 . A method as set forth in claim 1 wherein the water content of the MEA is reduced to or less than about 40 percent of saturation.
5 . A method as set forth in claim 1 wherein the water content of the MEA is reduced by operating the fuel cell at low inlet gas humidification prior to shutdown of the fuel cell.
6 . A method as set forth in claim 1 wherein the water content of the MEA is reduced by purging the MEA with dry gas after shutdown of the fuel cell.
7 . A method as set forth in claim 6 wherein the gas is selected from the group comprising air, hydrogen and mixtures thereof.
8 . A method as set forth in claim 1 further comprising measuring the water content of the MEA.
9 . A method as set forth in claim 8 wherein the water content of the MEA is determined by quantifying the membrane ionic conductance.
10 . A method as set forth in claim 1 wherein the water content of the MEA is reduced to or less than about 80 percent of saturation when the temperature is to be reduced to not below −10° C.
11 . A method as set forth in claim 2 wherein the water content of the MEA is reduced to or less than about 70 percent of saturation when the temperature is to be reduced to not below about −20° C.
12 . A method as set forth in claim 3 wherein the water content of the MEA is reduced to or less than about 50 percent of saturation when the temperature is to be reduced to not below about −30° C.
13 . A method as set forth in claim 3 wherein the water content of the water of the MEA is reduced to or less than about 40 percent of saturation when the temperature is reduced to below about −30° C.