Composition for adhering materials together
View Patent ↗The present invention is directed to a composition of adhering together first and second materials. The composition features a multi-functional reactive compound that includes a backbone group and first and second functional groups; a cross-linker, and a catalyst. The first functional group is responsive to a first actinic energy to form cross-linked molecules and to adhere a subset of the cross-linked molecules to the first material. The second functional group is responsive to a second actinic energy, differing from the first actinic energy to adhere to the second material.
1. An adhesive composition for adhering a polymerizable material to a solid substrate during polymerization of the polymerizable material, said composition comprising:
a multi-functional reactive compound having a backbone group and first and second functional groups, wherein said first functional group is selected from a set of functional groups consisting of a carboxylic group and an epoxy group;
a catalyst; and
a cross-linker,
wherein the adhesive composition differs chemically from the polymerizable material,
with said first functional group being responsive to a first actinic energy to form cross-linked molecules and adhere a subset of said cross-linked molecules to the solid substrate through the first functional group, and said second functional group being responsive to a second actinic energy, differing from said first actinic energy to react with the polymerizable material during polymerization of the polymerizable material.
2. The composition as recited in claim 1 wherein said first actinic energy includes thermal energy.
3. The composition as recited in claim 1 wherein said second actinic energy includes broad band ultraviolet energy.
4. The composition as recited in claim 1 wherein said multi-functional reactive compound has the following structure:
where x and y are integer numbers.
5. The composition as recited in claim 1 wherein said multi-functional reactive compound has the following structure:
wherein R′, R″ and R′″ are linking groups, X and X′ are functional groups, and x, y, z are averaged repeating numbers.
6. The composition as recited in claim 5 wherein said linking groups R′, R″ and R′″ are randomly distributed throughout said multi-functional reactive compound.
7. The composition as recited in claim 1 wherein said first functional group adheres to the solid substrate through an adhering mechanism selected from a set of mechanisms consisting of covalent bonds, ionic bonds, and Van der Waals forces.
8. The composition as recited in claim 1 wherein said cross-linker includes a linking functional group and said first functional group adheres to the solid substrate through said linking functional group of said cross-linker.
9. The composition as recited in claim 1 wherein said second functional group adheres to the polymerizable material by forming covalent bonds therewith during polymerization of the polymerizable material.
10. The composition as recited in claim 1 wherein said second functional group is selected from a set of functional groups consisting of acrylic and vinyl ether.
11. A composition for adhering a polymerizable material to a solid substrate during polymerization of the polymerizable material, said composition comprising:
a multi-functional reactive compound having a backbone group and first and second functional groups, wherein said first functional group is selected from a set of functional groups consisting of a carboxylic group and an epoxy group;
a cross-linker; and
a catalyst,
with said first functional group being responsive to a first actinic energy to form cross-linked molecules and adhere a subset of said cross-linked molecules to said solid substrate through the first functional group, and said second functional group being responsive to a second actinic energy, differing from said first actinic energy to adhere to said polymerizable material during polymerization of the polymerizable material, wherein the composition differs chemically from the solid substrate and the polymerizable material; and
wherein said cross-linker includes a linking functional group and said first functional group adheres to said solid substrate through said linking functional group of the cross-linker.
12. The composition as recited in claim 11 further including a solvent.
13. The composition as recited in claim 11 wherein said second functional group is selected from a set of functional groups consisting of acrylic and vinyl ether.
14. The composition as recited in claim 11 wherein said first functional group adheres to said solid substrate through an adhering mechanism selected from a set of mechanisms consisting of covalent bonds, ionic bonds, and Van der Waals forces.
15. The composition as recited in claim 11 wherein said second functional group adheres to said polymerizable material by forming covalent bonds therewith.
16. A composition for adhering a polymerizable material to a solid substrate during polymerization of the polymerizable material, said composition comprising:
a multi-functional reactive compound having a backbone group and first and second functional groups, with said first functional group providing carboxylic functionality and said second functional group providing acrylic functionality;
a cross-linker;
a catalyst; and
a solvent, with said first functional group being responsive to a first actinic energy to form cross-linked molecules and adhere a subset of said cross-linked molecules to said solid substrate through the first functional group, and said second functional group being responsive to a second actinic energy, differing from said first actinic energy to adhere to said polymerizable material during polymerization of the polymerizable material; and
wherein the composition differs chemically from the solid substrate and the polymerizable material.
17. The composition as recited in claim 16 wherein said cross-linker includes a linking functional group and said first functional group adheres to said solid substrate through said linking functional group of the cross-linker.
18. The composition as recited in claim 17 wherein said first functional group adheres to said solid substrate through an adhering mechanism selected from a set of mechanisms consisting of covalent bonds, ionic bonds, and Van der Waals forces.
19. An adhesive composition for adhering a polymerizable material to a solid substrate during polymerization of the polymerizable material, said composition comprising:
a multi-functional reactive compound having a backbone group and first and second functional groups, the multi-functional reactive compound having the following structure:
where x and y are integer numbers;
a catalyst; and
a cross-linker,
with said first functional group being responsive to a first actinic energy to form cross-linked molecules and adhere a subset of said cross-linked molecules to the solid substrate and said second functional group being responsive to a second actinic energy, differing from said first actinic energy to react with the polmerizable material during polymerization of the polymerizable material.
20. An adhesive composition for adhering a polymerizable material to a solid substrate during polymerization of the polymerizable material, said composition comprising:
a multi-functional reactive compound having a backbone group and first and second functional groups X and X′, the multi-functional reactive compound having the following structure:
wherein R′, R″ and R′″ are linking groups and x, y, z are averaged repeating numbers;
a catalyst; and
a cross-linker,
with said first functional group being responsive to a first actinic energy to form cross-linked molecules and adhere a subset of said cross-linked molecules to the solid substrate and said second functional group being responsive to a second actinic energy, differing from said first actinic energy to react with the polymerizable material during polymerization of the polymerizable material.
21. The composition as recited in claim 20 , wherein said linking groups R′, R″ and R′″ are randomly distributed throughout said multi-functional reactive compound.