Nitride-based semiconductor substrate and method of making the same
View Patent ↗A nitride-based semiconductor substrate having a diameter of 25 mm or more, a thickness of 250 micrometers or more, and an optical absorption coefficient of less than 7 cm −1 to light with a wavelength of 380 nm or more. The nitride-based semiconductor substrate is made by the HVPE method that uses gallium chloride obtained by reacting a Ga melt with a hydrogen chloride gas. The Ga melt is contacted with the hydrogen chloride gas for one minute or more to produce the gallium chloride.
1. A nitride-based semiconductor substrate, comprising:
a diameter of 25 mm or more;
a thickness of 250 micrometers or more;
an optical absorption coefficient of less than 7 cm −1 to light with a predetermined wavelength that is equal to or greater than 380 nm, and
an electrical resistivity of 0.02 Ωcm or less.
2. The nitride-based semiconductor substrate according to claim 1 , further comprising:
a dislocation density of 1×10 7 cm −2 or less.
3. The nitride-based semiconductor substrate according to claim 1 , further comprising:
an impurity concentration of 1×10 17 cm −3 or less in relation to any of As, O, Cl, P, Na, K, Li, Ca, Sn, Ti, Fe, Cr and Ni.
4. The nitride-based semiconductor substrate according to claim 1 , wherein the electrical resistivity does not fall below 0.001 Ωcm.
5. The nitride-based semiconductor substrate according, to claim 1 , further comprising:
a carrier concentration having a range from 1×10 17 cm −3 to 1×10 19 cm −3 .
6. The nitride-based semiconductor substrate according to claim 1 , further comprising:
an oxygen impurity concentration having a range from 10 16 cm −3 to 10 18 cm −3 .
7. The nitride-based semiconductor substrate according to claim 1 , further comprising:
an iron impurity concentration having a range from 10 14 cm −3 to 10 17 cm −3 .
8. The nitride-based semiconductor substrate according to claim 1 , further comprising:
a Ga melt-hydrogen chloride gas reaction lasting for a period equal to or greater than one minute.