Chemically compatible, lightweight heat pipe
View Patent ↗The present invention provides an apparatus including a magnesium alloy vessel that is substantially free of aluminum and zinc, but including magnesium in combination with a gettering metal and a method for making such apparatus. The magnesium alloy vessel has a hollow interior cavity containing a working fluid, with a stable, protective layer formed on the inside wall of the vessel so as to establish non-corrosive compatibility with the working fluid.
1. A method for manufacturing a heat transfer device comprising the steps of:
(A) alloying a magnesium base metal that is substantially free of aluminum and zinc to a getter metal so as to form a magnesium getter alloy;
(B) fabricating said magnesium getter alloy into a vessel having an interior wall defining a hollow interior cavity;
(C) forming a stable protective layer upon said interior wall, wherein said stable protective layer is in thermally-compatible contact with said interior wall;
(D) filling at least a portion of said hollow interior cavity with a capillary wick structure;
(E) evacuating said hollow interior cavity; and
(F) charging a portion of said hollow interior cavity with a working fluid, wherein said working fluid is in chemically non-reactive contact with said stable protective layer.
2. The method according to claim 1 wherein said getter metal is selected from the group consisting of zirconium, titanium, hafnium and yttrium.
3. The method according to claim 1 wherein zirconium is alloyed to said magnesium base metal in a weight percentage of about 0.1-5.0%.
4. The method according to claim 1 wherein zirconium is alloyed to said magnesium base metal in a weight percentage of about 0.6%.
5. The method according to claim 1 wherein a nitride derivative of said magnesium getter alloy is formed on said interior wall of said vessel as the stable protective layer.
6. The method according to claim 5 wherein ammonia is charged into said hollow interior cavity as said working fluid.
7. The method according to claim 1 wherein an oxide derivative of said magnesium getter alloy is formed on said interior wall of said vessel as the stable protective layer.
8. The method according to claim 7 wherein water is charged into said hollow interior cavity as said working fluid.
9. A method for preventing base metal corrosion in a heat transfer device, comprising the steps of:
(A) alloying a magnesium metal that is substantially free of aluminum and zinc to a getter metal so as to form a magnesium getter alloy wherein said magnesium getter alloy functions as a base metal for said heat transfer device;
(B) fabricating said base metal into a vessel having an interior wall defining a hollow interior cavity;
(C) filling at least a portion of said hollow interior cavity with a capillary wick structure;
(D) evacuating said hollow interior cavity;
(E) charging a portion of said hollow interior cavity with a working fluid; and,
(F) oxidizing said interior wall of said vessel so as to form a stable protective layer, wherein said stable protective layer comprises an oxidation product of said base metal and said working fluid, and further wherein said protective layer inhibits contact between said interior wall and said working fluid so as to prevent corrosive interaction by said working fluid upon said interior wall.
10. The method according to claim 9 wherein said getter metal is selected from the group consisting of zirconium, titanium, hafnium and yttrium.
11. The method according to claim 9 wherein zirconium is alloyed to said magnesium metal in a weight percentage of about 0.1-5.0%.
12. The method according to claim 9 wherein zirconium is alloyed to said magnesium metal in a weight percentage of about 0.6%.
13. The method according to claim 9 wherein ammonia is charged into said hollow interior cavity as said working fluid.
14. The method according to claim 9 wherein water is charged into said hollow interior cavity as said working fluid.
15. A method for preventing hydrogen gas generation in a heat transfer device, comprising the steps of:
(A) alloying a magnesium metal, substantially free of aluminum and zinc, to a getter metal so as to form a magnesium getter alloy;
(B) fabricating said magnesium getter alloy into a vessel having an interior wall defining a hollow interior cavity;
(C) forming a stable protective layer upon said interior wall, wherein said stable protective layer comprises substantially a combination of an oxide of said getter metal and an oxide of said magnesium metal, and further wherein said getter metal oxide reacts to absorb hydrogen gas produced within said hollow interior cavity;
(D) filling at least a portion of said hollow interior cavity with a capillary wick structure;
(E) evacuating said hollow interior cavity; and
(F) charging a portion of said hollow interior cavity with a working fluid, said working fluid being liquid water.
16. The method according to claim 15 wherein said getter metal is selected from the group consisting of zirconium, titanium, hafnium and yttrium.
17. The method according to claim 15 wherein zirconium is alloyed to said magnesium metal in a weight percentage of about 0.1-5.0%.
18. The method according to claim 15 wherein zirconium is alloyed to said magnesium metal in a weight percentage of about 0.6%.