Method of preparing a coating solution and a corresponding use of the coating solution for coating a substrate
View Patent ↗A method of preparing a coating solution, comprising the steps of providing a first solution comprising a lower alcohol; a polyethylene glycol; a complexing agent; and water; providing a second solution comprising a higher alcohol; and at least one metal alkoxide, wherein the metal in said at least one metal alkoxide is selected from the group consisting of zirconium, aluminium, titanium, tantalum and yttrium; forming a sol-gel solution by mixing said first and second solutions and thereby hydrolyzing said at least one metal alkoxide to a metal oxide and an alcohol; forming a concentrated solution by removing said lower alcohol and the alcohol resulting from the hydrolysis of said at least one metal alkoxide; and forming a coating solution by adding a medium alcohol to said concentrated solution.
1. A method for coating a substrate, comprising the steps of:
providing a substrate, and a coating solution prepared by the following steps:
providing a first solution comprising:
a lower alcohol having a chain length of four carbon atoms or less (C 1 -C 4 );
a polyethylene glycol;
a complexing agent; and
water;
providing a second solution comprising:
a higher alcohol having a chain length from eight to twenty carbon atoms (C 8 -C 20 ); and
at least one metal alkoxide, wherein the metal in said at least one metal alkoxide is selected from the group consisting of zirconium, aluminium, titanium, tantalum and yttrium;
forming a sol-gel solution by mixing said first and second solutions and thereby hydrolyzing said at least one metal alkoxide to a metal oxide and an alcohol;
forming a concentrated solution by removing said lower alcohol and the alcohol resulting from the hydrolysis of said at least one metal alkoxide; and
forming a coating solution by adding a medium alcohol having a chain length from 5 to 10 carbon atoms (C 5 -C 10 ) to said concentrated solution;
spin-coating said coating solution onto said substrate to form a coated substrate;
forming a dry coating on said substrate by subjecting said coated substrate to a drying step.
2. The method according to claim 1 , wherein said substrate is a 12 inch wafer or a 12 inch silicon wafer.
3. The method according to claim 1 , comprising heating said coated substrate to a temperature in the range of from 100° C. to 200° C. as said drying step.
4. The method according to claim 1 , comprising heating said coated substrate over a period of time in the range of from 1 minute to 30 minutes as said drying.
5. The method according to claim 1 , wherein said spin-coating is performed at a rotational speed in the range of from 1500 rpm to 2600 rpm.
6. The method according to claim 1 , wherein said dry coating on said substrate has a thickness of at least 400 nm.
7. The method according to claim 1 , wherein after the drying step an additional annealing is performed in order to form a coating on said substrate by said dry coating.
8. The method according to claim 7 , wherein said annealing comprises heating said dry coating to a temperature in the range of from 600° C. to 800° C.
9. The method according to claim 7 , wherein said annealing comprises heating said dry coating at a heating rate of at least 2000 K/min.
10. The method according to claim 7 , wherein said annealing comprises heating said dry coating over a period of time in the range of from 10 seconds to 10 minutes.
11. The method according to claim 7 , wherein said coating on said substrate has a refractive index of at least 2.
12. The method according to claim 7 , wherein said coating on said substrate has a variation of the thickness of said coating of less than 13%.
13. The method according to claim 7 , wherein said coating on said substrate has a stress of less than 150 MPa.