Transparent rare-earth oxide sintered body and manufacturing method thereof
View Patent ↗The invention intends to obtain a transparent yttrium oxide sintered body of which in-line transmittance in a visible wavelength region of 400 to 800 nm at a thickness of 1 mm is 60% or more, without using aluminum that readily segregates in grain boundaries of yttrium oxide, without using special raw materials in which a silicon content is particularly reduced and without finely pulverizing raw materials. A transparent yttrium oxide sintered body that contains, with yttrium oxide as a main component, at least either one of tantalum or niobium or both thereof and has the in-line transmittance of 60% or more at a thickness of 1 mm in a visible wavelength region in the range of 400 to 800 nm.
1. A transparent yttrium oxide sintered body, comprising:
yttrium oxide as a main component; and
niobium in solid solution with the yttrium oxide;
wherein in-line transmittance when a thickness thereof is 1 mm in a visible wavelength region in a range of 400 to 800 nm is 60% or more.
2. The transparent yttrium oxide sintered body according to claim 1 , wherein the body further comprises tantalum in solid solution with the yttrium oxide.
3. The transparent yttrium oxide sintered body according to claim 2 , wherein the body comprises tantalum in a range of 0.1 to 1.3 wt % in terms of metal.
4. A manufacturing method of a transparent yttrium oxide sintered body, comprising:
adding at least one of niobium and a niobium compound to a yttrium oxide powder to blend therewith;
forming the blended material to a yttrium oxide molded body containing the niobium; and
sintering the yttrium oxide molded body at 1700° C. or more and 2000° C. or less under a vacuum, hydrogen or rare gas atmosphere to form a transparent yttrium oxide sintered body comprising yttrium oxide as a main component and niobium in solid solution with the yttrium oxide, wherein in-line transmittance when a thickness of the yttrium oxide sintered body is 1 mm in a visible wavelength region in a range of 400 to 800 nm is 60% or more.
5. The manufacturing method of the transparent yttrium oxide sintered body according to claim 4 , wherein in the adding step tantalum or tantalum compound is further added in a range of 0.2 to 1.5 wt % to yttrium oxide in terms of metal to form a transparent yttrium oxide sintered body further containing tantalum in solid solution with the yttrium oxide.
6. The manufacturing method of a transparent yttrium oxide sintered body according to claim 4 , wherein the niobium or the niobium compound is added in a range of 0.1 to 1.0 wt % to yttrium oxide in terms of metal.
7. The manufacturing method of the transparent yttrium oxide sintered body according to claim 4 , wherein a specific surface area of yttrium oxide powder is 5 m 2 /g or more and 50 m 2 /g or less and
wherein in the adding step at least one of tantalum and a tantalum compound is further added in a range of 0.2 to 1.5 wt % in terms of metal to form a transparent yttrium oxide sintered body further containing tantalum in solid solution with the yttrium oxide.
8. The manufacturing method of a transparent yttrium oxide sintered body according to claim 4 , wherein a specific surface area of yttrium oxide powder is 5 m 2 /g or more and 50 m 2 /g or less and
at least one of niobium and a niobium compound is added in a range of 0.1 to 1.0 wt % in terms of metal.
9. The transparent yttrium oxide sintered body according to claim 3 , wherein the tantalum is contained in a range of 0.1 to 0.3 wt % in terms of metal, and no striae is contained.
10. A transparent yttrium oxide sintered body, comprising:
yttrium oxide as a main component; and
niobium;
wherein the niobium is contained in a range of 0.05 to 0.2 wt % in terms of metal,
wherein the in-line transmittance at a thickness of 1 mm in a visible wavelength region in a range of 400 to 800 nm is 60% or more and no striae is contained.
11. The transparent yttrium oxide sintered body according to claim 1 , wherein the body comprises niobium in a range of 0.05 to 0.5 wt % in terms of metal.
12. The transparent yttrium oxide sintered body according to claim 11 , wherein the body comprises niobium in a range of 0.05 to 0.2 wt % in terms of metal and the sintered body does not contain striae.