Method for the production of a metal-ceramic substrate
View Patent ↗Disclosed is a method for producing a metal-ceramic substrate. According to said method, a metal layer is applied to at least one face of a ceramic substrate or a ceramic layer by means of a direct bonding process, and the metal-ceramic substrate or partial substrate is aftertreated in a subsequent step at a gas pressure (aftertreatment pressure) ranging approximately between 400 and 2000 bar and an aftertreatment temperature ranging approximately.
1. A method for manufacturing a metal-ceramic substrate, the method comprising the steps of:
applying a metal layer to at least one side of a ceramic substrate or a ceramic layer using a direct bonding process at a direct copper bonding temperature between 1025° C. and 1083° C. to form the metal-ceramic substrate, and
post-treating the metal-ceramic substrate subsequent to applying the metal layer in a processing step at a gas pressure between approximately 400 and 2000 bar and at a post-treatment temperature between approximately 450 and 1060° C.
2. the method according to claim 1 , wherein a gas atmosphere of the post-treatment, based on the post-treatment temperature, has an oxygen content or an oxygen partial pressure that is greater than a partial pressure at which a breakdown of a bond border surface between copper and ceramic occurs, but which is limited upward so that no appreciable oxidation of the copper takes place.
3. The method according to claim 2 , wherein the oxygen partial pressure at a post-treatment temperature between 900° C. and 1060° C. is between 2×10 −7 and 1×10 −3 bar and at a post-treatment temperature between 450° C. and 900° C. is between 3×10 −16 and 1×10 −2 bar.
4. The method according to claim 1 , wherein a pressure gas for post treatment is an inert gas, argon or nitrogen.
5. The method according to claim 1 , wherein a thickness of the at least one ceramic layer is between approximately 0.2 and 4 mm.
6. The method according to claim 1 , wherein a thickness of the at least one metal layer is between approximately 0.07 and 1.0 mm.
7. The method according to claim 1 , wherein at least one hole is made in at least one ceramic layer for producing at least one through-hole contact, and that metal layers provided on two surface sides of the ceramic layer in the proximity of the hole are formed into the hole and connected with each other during the post-treatment.
8. The method according to claim 1 , wherein at least one hole is made in at least one ceramic layer for producing at least one through-hole contact, that an element made of an electrically conductive material, or copper, is inserted into the at least one hole and that during the post-treatment the metal layers provided in the proximity of the at least one hole on two surface sides of the ceramic layer are pressed by means of permanent deformation against the metal element and connected with the latter.
9. The method according to claim 8 , wherein a diameter of the metal element is equal to or approximately equal to the diameter of the hole.
10. The method according to claim 8 wherein the metal element has a length perpendicular to the surface sides of the ceramic layer that is equal to or less than the thickness of the ceramic layer.
11. The method according to claim 1 , for manufacturing a metal-ceramic substrate in a sandwich construction, wherein at least two ceramic layers are bonded to each other through the direct copper bonding process via at least one metal layer located in between.
12. The method according to claim 1 , wherein at least one metal layer is applied to the outside of each ceramic layer using the direct copper bonding process.
13. The method according to claim 1 that for manufacturing a metal-ceramic substrate in a sandwich construction, wherein one first sub-substrate with at least one first ceramic layer and with two metallizations on the two surface sides and one second sub-substrate with at least one ceramic layer and at least one metallization on one surface side of the ceramic layer are manufactured using the direct copper bonding process, that the two sub-substrates are bonded to each other via at least one metal layer in a further direct copper bonding process, and that the post-treatment is carried out in a further process step at the post-treatment pressure and the post-treatment temperature.
14. The method according to claim 13 wherein the at least one metallization is structured after the post-treatment.
15. The method according to claim 14 , wherein the metal-ceramic substrate, after structuring of the at least one metallization, is separated into individual substrates, by breaking along break-off lines.
16. The method according to claim 1 , wherein the post-treatment temperature is approximately 560° C. and the gas pressure is 1900 bar.
17. The method according to claim 1 , wherein the post-treatment temperature is approximately 950° C. and the gas pressure is approximately 900 bar.
18. The method according to claim 1 , wherein the post-treatment temperature is approximately 1030° C. and the gas pressure is approximately 850 bar.
19. The method according to claim 1 , wherein the post-treatment temperature is approximately 1030° C. and the gas pressure is approximately 750 bar.
20. A method for manufacturing a metal-ceramic substrate, the method comprising the steps of:
(i) applying a metal layer to at least one side of a ceramic substrate or a ceramic layer using a direct bonding process at a direct copper bonding temperature between 1025° C. and 1083° C. to form the metal-ceramic substrate, and
(ii) post-treating the metal-ceramic substrate subsequent to applying the metal layer in a processing step at a gas pressure between approximately 400 and 2000 bar and the post-treating is carried out at a post-treatment temperature of at least 50% of the direct copper bonding temperature, that is between 1025° C. and 1083° C.