Crosslinking reactions
View Patent ↗The present invention relates to a process of making a starch crosslinked with sodium trimetaphosphate or with a combination of sodium trimetaphosphate and sodium tripolyphosphate. The reaction has increased efficiency over the standard crosslinking process and/or reduced phosphorus effluent.
1. A process of preparing a granular corn or wheat starch comprising crosslinking the corn or wheat starch using sodium trimetaphosphate or a combination of sodium trimetaphosphate and sodium tripolyphosphate:
a. wherein the pH is adjusted to between 11.5 and 12.0 prior to the crosslinking reaction using an at least 25% alkali solution and is maintained at 11.5 to 12.0 throughout the crosslinking reaction;
b. wherein no more than 2% water by weight of the starch (dry basis) is added to the starch during the pH adjustment prior to the crosslinking reaction;
c. wherein the sodium trimetaphosphate is used in an amount of from about 5-16% by weight of the starch;
d. wherein the reaction is conducted at a solids level of at least 36% by weight; and
e. wherein the reaction is conducted for a period of from about 10 minutes to 30 hours.
2. The process of claim 1 , wherein the pH is maintained at 11.5.
3. The process of claim 1 , wherein the reaction is conducted at a solids level of from 36% to 44% by weight.
4. The process of claim 1 , wherein the reaction is conducted at a temperature from about 25° C. to 70° C.
5. The process of claim 4 , wherein the reaction is conducted at a temperature from about 30° C. to 50° C.
6. The process of claim 1 , wherein the reaction is conducted for a period of from about 3 hours to 24 hours.
7. The process of claim 6 , wherein the reaction is conducted for a period of from about 16 to 24 hours.
8. The process of claim 1 , wherein from about 0.1-20% sodium sulfate and/or sodium chloride by weight of the starch is added to the reaction mixture.
9. The process of claim 1 , wherein from about 0.01 to 0.2% sodium tripolyphosphate by weight of the starch is used.
10. The process of claim 1 , wherein from about 0.05-0.16% sodium tripolyphosphate by weight of the starch is used.
11. The process of claim 1 , wherein the combination of the STMP/STPP is at a level of from about 1 to 20% by weight of the starch.
12. The process of claim 11 , wherein the combination of the STMP/STPP is at a level of from about 5 to 16% by weight of the starch.
13. The process of claim 1 , wherein the reaction mixture is made basic using sodium hydroxide.
14. The process of claim 13 , wherein the sodium hydroxide is used at a level of at least 0.4 to 0.8% on starch weight.
15. The process of claim 14 , wherein the sodium hydroxide is used at a level of from 0.55 to 0.65% on starch weight.