Method and apparatus for achieving maximum yield in the electrolytic preparation of group IV and V hydrides
View Patent ↗A method for generating a hydride gas of metal M 1 in an electrochemical cell comprising a cathode comprising metal M 1 , a sacrificial anode comprising metal M 2 , an initial concentration of aqueous electrolyte solution comprising a metal hydroxide, M 3 OH, wherein the sacrificial metal anode electrochemically oxidizes in the presence of the aqueous electrolyte solution comprising M 3 OH to form a metal salt, and the hydride gas of metal M 1 is formed by reducing the metal M 1 of the cathode. The method comprises the steps of determining solubility profile curves of the metal salt as the M 3 OH is consumed and the metal oxide is formed by the oxidation reaction at various concentrations of M 3 OH; determining a maximum concentration of M 3 OH that, as it is consumed, does not yield a concentration of metal salt that precipitates out of the electrolyte solution; and choosing a concentration of M 3 OH that is in the range of at and within 5% less than the maximum concentration of M 3 OH to be the initial concentration of M 3 OH.
1. A method for generating a hydride gas of metal M 1 in an electrochemical cell comprising a cathode comprising metal M 1 ; a sacrificial anode comprising metal M 2 ; an initial concentration of aqueous electrolyte solution comprising a metal hydroxide, M 3 OH; wherein the sacrificial metal anode electrochemically oxidizes in the presence of the aqueous electrolyte solution to form a metal salt, and the hydride gas of metal M 1 is formed by reducing the metal M 1 of the cathode, the method comprising the steps of:
determining solubility profile curves of the metal salt as the M 3 OH is consumed and the metal oxide is formed by the oxidation reaction at various concentrations of M 3 OH;
determining a maximum concentration of M 3 OH using the solubility profile curves; said determined maximum concentration of M 3 OH does not yield a concentration of metal salt that precipitates out of the electrolyte solution; and
choosing a concentration of M 3 OH that is in the range of at and within 5% less than the said determined maximum concentration of M 3 OH to be an initial concentration of M 3 OH.
2. The method for generating a hydride gas of metal M 1 in an electrochemical cell of claim 1 wherein M 1 is selected from the group consisting of Sb, As, Se , P, Ge, Zn, Pb, Cd and alloys thereof.
3. The method for generating a hydride gas of metal M 1 in an electrochemical cell of claim 1 wherein said sacrificial anode is selected from the group consisting of hydrogen oxidation anode, redox anode and soluble, oxidizible ionic species with an oxidation potential less than 0.4 volts versus an Hg/HgO reference electrode.
4. The method for generating a hydride gas of metal M 1 in an electrochemical cell of claim 1 wherein said sacrificial anode is a hydrogen oxidation anode and M 2 is selected from the group consisting of molybdenum, tungsten, vanadium, cadmium, lead, nickel hydroxide, chromium, antimony, arsenic and alloys thereof.
5. The method for generating a hydride gas of metal M 1 in an electrochemical cell of claim 1 wherein said sacrificial anode is a redox anode, and is selected from the group consisting of MnO 2 /MnO 3 , Fe(OH) 2 /Fe 3 O 4 , Ag 2 O/Ag 2 O 2 , and Co(OH) 3 /Co(OH) 2 .
6. The method for generating a hydride gas of metal M 1 in an electrochemical cell of claim 1 wherein M 3 in said metal hydroxide, M 3 OH, is selected from the group consisting of alkali and alkaline earth metals.
7. The method for generating a hydride gas of metal M 1 in an electrochemical cell of claim 6 wherein M 3 OH is selected from the group consisting of NaOH, KOH, LiON, CsOH, NH 4 OH and combinations thereof.