Reduction of carrot defects in silicon carbide epitaxy
View Patent ↗Single crystal silicon carbide epitaxial layer on an off-axis substrate are manufactured by placing the substrate in an epitaxial growth reactor, growing a first layer of epitaxial silicon carbide on the substrate, interrupting the growth of the first layer of epitaxial silicon carbide, etching the first layer of epitaxial silicon carbide to reduce the thickness of the first layer, and regrowing a second layer of epitaxial silicon carbide on the first layer of epitaxial silicon carbide. Carrot defects may be terminated by the process of interrupting the epitaxial growth process, etching the grown layer and regrowing a second layer of epitaxial silicon carbide. The growth interruption/etching/regrowth may be repeated multiple times. A silicon carbide epitaxial layer has at least one carrot defect that is terminated within the epitaxial layer. A semiconductor stricture includes an epitaxial layer of silicon carbide on an off-axis silicon carbide substrate, and a carrot defect having a nucleation point in the vicinity of an interface between the substrate and the epitaxial layer and is terminated within the epitaxial layer.
1. A method of manufacturing a single crystal silicon carbide epitaxial layer on an off-axis silicon carbide substrate comprising:
flowing a source gas and a carrier gas into a reaction chamber for growing a first layer of epitaxial silicon carbide on the substrate wherein the source gas is flowed at a first flow rate;
reducing, but not halting, the flow of the source gas from the first flow rate to a reduced flow rate while maintaining a flow of the carrier gas;
etching the first layer of epitaxial silicon carbide with at least the carrier gas and at least partially due to the reduction in flow of the source gas from the first flow rate to the reduced flow rate without halting the flow of the source gas to reduce the thickness of the first layer and maintaining a reduced flow of the source gases into the reaction chamber while etching the first layer of epitaxial silicon carbide with at least the carrier; and
growing a second layer of epitaxial silicon carbide on the etched first layer of epitaxial silicon carbide.
2. A method according to claim 1 , further comprising interrupting the growth of the first layer of epitaxial silicon carbide prior to etching the first layer of epitaxial silicon carbide.
3. A method according to claim 2 , wherein growing a first layer of epitaxial silicon carbide comprises flowing silicon and carbon containing source gases over the substrate and interrupting the growth of the first layer of epitaxial silicon carbide comprises reducing the flow of the source gases.
4. A method according to claim 1 , wherein the carrier gas comprises H 2 , HCl, Cl 2 and/or propane.
5. A method according to claim 1 , wherein the first layer of epitaxial silicon carbide is doped with a dopant at a concentration of 1E18 cm −3 or greater.
6. A method according to claim 1 , wherein the first layer of epitaxial silicon carbide has a thickness of less than 4 microns.
7. A method according to claim 1 , wherein the first layer of epitaxial silicon carbide has a thickness of greater than 2 microns.
8. A method according to claim 1 , wherein the first layer of epitaxial silicon carbide has a thickness of about 4 microns.
9. A method according to claim 1 , wherein etching the first layer of epitaxial silicon carbide comprises etching the first layer of epitaxial silicon carbide by about 1 micron or more.
10. A method according to claim 1 , wherein etching the first layer of epitaxial silicon carbide comprises etching the first layer of epitaxial silicon carbide by about 1 micron or less.
11. A method according to claim 1 , wherein the second layer of epitaxial silicon carbide is grown to a thickness of about 2 microns.
12. A method according to claim 1 , further comprising etching the second epitaxial layer, and growing a third epitaxial layer on the etched second epitaxial layer.
13. A method according to claim 12 , further comprising interrupting the growth of the second epitaxial layer prior to etching the second epitaxial layer.
14. A method according to claim 1 , wherein the substrate comprises silicon carbide having a polytype selected from the group consisting of 2H, 4H, and 6H.
15. A method according to claim 1 , wherein etching the first layer of epitaxial silicon carbide comprises etching the first layer of epitaxial silicon carbide within the epitaxial growth reactor.
16. A method according to claim 1 , wherein the first epitaxial layer and the second epitaxial layer provide a buffer layer on the substrate.
17. A method according to claim 1 , wherein growing a first layer of epitaxial silicon carbide on the substrate comprises growing a first layer of epitaxial silicon carbide on an epitaxial layer on the substrate.
18. The method of claim 1 , further comprising growing a third epitaxial layer of silicon carbide on the second epitaxial layer of silicon carbide, wherein the first layer of epitaxial silicon carbide has a first doping concentration and the third layer of epitaxial silicon carbide has a second doping concentration that is less than the first doping concentration.
19. A method of manufacturing a single crystal silicon carbide epitaxial layer on an off-axis silicon carbide substrate comprising:
flowing a source gas into a reaction chamber for growing a first layer of epitaxial silicon carbide on the substrate;
flowing a carrier gas together with the source gas as a combined process gas at a first flow rate and wherein at least the carrier gas etches silicon carbide;
reducing a total flow rate of the combined process gas from the first flow rate to a reduced flow rate without halting the flow of the combined process gas;
etching the first layer of epitaxial silicon carbide at least partially due to the reduction in the flow rate of the combined process gas from the first flow rate to the reduced flow rate without halting the flow of the combined process gas to reduce the thickness of the first layer and maintaining a reduced, but not halted, flow of the source gases into the reaction chamber while etching the first layer of epitaxial silicon carbide; and
growing a second layer of epitaxial silicon carbide on the etched first layer of epitaxial silicon carbide.
20. The method of claim 19 , wherein the carrier gas comprises H 2 , HCl, Cl 2 and/or propane.