Method for producing a high-aspect ratio conductive pattern on a substrate
View Patent ↗Conductive patterns and methods of using and printing such conductive patterns are disclosed. In certain examples, the conductive patterns may be produced by disposing a conductive material between supports on a substrate. The supports may be removed to provide conductive patterns having a desired length and/or geometry.
1. A method for producing a high-aspect ratio conductive pattern on a substrate, comprising:
applying a first support layer on the substrate to form a solid support defining a spacing having an effective height;
printing a first conductive ink material layer to fill the defined spacing of the solid support;
applying a second support layer to the first support layer to increase the effective height of the spacing defined by the solid support;
printing a second conductive ink material layer on the first conductive ink material layer to reach the increased effective height of the spacing defined by the solid support;
further alternately applying additional support layers, to further define the solid support, and printing additional conductive ink material layers to achieve a third effective height associated with a high-aspect ratio with reference to the defined spacing; and
removing the solid support to provide the high-aspect ratio conductive pattern with the third effective height on the substrate.
2. The method of claim 1 in which the conductive ink material layers comprise capped metal particles.
3. The method of claim 1 further comprising curing the substrate prior to removing the solid support.
4. The method of claim 1 further comprising curing the substrate after removing the solid support.
5. The method of claim 1 in which the removing step comprises stripping the solid support.
6. The method of claim 1 in which the removing step comprises heating the substrate.
7. The method of claim 1 , wherein the substrate is a prepreg.
8. A method of printing a conductive pattern of a desired thickness on a substrate using a printer, the method comprising:
disposing a solid support material in a first reservoir of the printer;
disposing an ink in a second reservoir of the printer;
printing support lines with the solid support material from the first reservoir on the substrate;
printing a conductive pattern between the support lines with the ink from the second reservoir on the substrate;
alternating printing of the solid support material, to further define the solid support, and the ink on the substrate to consecutively increase an effective height of the support lines and an effective height of the conductive pattern until a desired thickness of the conductive pattern on the substrate is achieved; and
removing the support lines to provide a high-aspect ratio conductive pattern with the effective height on the substrate.
9. The method of claim 1 , further comprising sintering the high ratio conductive pattern before removing the solid support.
10. The method of claim 1 , wherein the conductive ink material layers comprise capped metal nanoparticles dispersed in a solvent system.
11. The method of claim 10 , wherein the capped metal nanoparticles comprise one or more members selected from the group consisting of silver, gold, copper, nickel, platinum, palladium, and iron.
12. The method of claim 1 , wherein the solid support defining the spacing comprises a system of support lines.
13. The method of claim 8 , further comprising sintering the high ratio conductive pattern.
14. The method of claim 8 , wherein the ink comprises capped metal nanoparticles dispersed in a solvent system.
15. The method of claim 14 , wherein the capped metal nanoparticles comprise one or more members selected from the group consisting of silver, gold, copper, nickel, platinum, palladium, and iron.
16. The method of claim 1 , wherein the high-aspect ratio conductive pattern provided has a height that is at least five times greater than a width.
17. The method of claim 7 further comprising thermally treating the prepreg with the at least one disposed high-aspect ratio conductive pattern.
18. The method of claim 2 , wherein the capped metal particles provide a conductivity of at least about 30*10 4 S/cm.
19. The method of claim 2 , wherein the capped metal particles comprise hexadecylamine.