IP Library Granted Patent US 7,700,499
Granted Patent B2
US 7,700,499 · App. 12/008,607 · Granted Apr 20, 2010

Multilayer silicon nitride deposition for a semiconductor device

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Quick Facts
Patent No.
US 7,700,499
App. No.
12/008,607
Granted
Apr 20, 2010
Kind
B2
Abstract

A method for making a semiconductor device is provided which comprises (a) providing a semiconductor structure equipped with a gate ( 209 ) and a channel region, said channel region being associated with the gate; (b) depositing a first sub-layer ( 231 ) of a first stressor material over the semiconductor structure, said first stressor material containing silicon-nitrogen bonds and imparting tensile stress to the semiconductor structure; (c) curing the first stressor material through exposure to a radiation source; (d) depositing a second sub-layer ( 233 ) of a second stressor material over the first sub-layer, said second stressor material containing silicon-nitrogen bonds and imparting tensile stress to the semiconductor structure; and (e) curing the second sub-layer of stressor material through exposure to a radiation source.

Claims (41)

1. A method for making a semiconductor device, comprising:

providing a semiconductor structure equipped with first and second gate structures and having channel regions associated with the gate structures;

depositing a first sub-layer of a first stressor material over the gate structures and channel regions, said first stressor material containing silicon-nitrogen bonds;

curing the first stressor material through exposure to a radiation source, thereby forming a first cured sub-layer;

depositing a second sub-layer of a second stressor material over the first cured sub-layer, said second stressor material containing silicon-nitrogen bonds;

curing the second stressor material through exposure to a radiation source, thereby forming a second cured sub-layer;

depositing a third sub-layer of a third stressor material between the first and second gate structures and in contact with the second sub-layer;

curing the third stressor material through exposure to a radiation source;

depositing a fourth sub-layer of a fourth stressor material between the first and second gate structures and in contact with the third sub-layer; and

curing the fourth stressor material through exposure to radiation source.

2. The method of claim 1 , wherein the first and second stressor materials impart tensile stress to the semiconductor structure.

3. The method of claim 1 , wherein the first and second stressor materials are different.

4. The method of claim 1 , wherein the radiation source is a UV radiation source.

5. The method of claim 1 , wherein the radiation source is an e-beam radiation source.

6. The method of claim 1 , wherein the first and second sub-layers are formed by plasma enhanced chemical vapor deposition (PECVD).

7. The method of claim 1 , wherein each of the first and second sub-layers has a thickness of less than about 250 Å.

8. The method of claim 1 , wherein each of the first and second sub-layers has a thickness within the range of about 200 Å to about 250 Å.

9. The method of claim 1 , wherein the radiation source is a UV radiation source, wherein the step of curing the first stressor material involves exposure to the UV radiation source for less than about 10 minutes, and wherein the step of curing the second stressor material involves exposure to the UV radiation source for less than about 10 minutes.

10. The method of claim 1 , wherein the radiation source is a UV radiation source, and wherein each of the first and second sub-layers is cured through exposure to UV radiation for a duration of time within the range of about 5 to about 10 minutes.

11. The method of claim 1 , wherein the radiation source is a UV radiation source, wherein the semiconductor structure comprises first and second gate structures, and wherein the third sub-layer of a third stressor material is deposited between the first and second gate structures and in contact with the second sub-layer and is cured through exposure to UV radiation.

12. The method of claim 11 , wherein each of the first, second and third sub-layers has a thickness of less than about 250 Å.

13. The method of claim 11 , wherein each of the first, second and third sub-layers has a thickness within the range of about 200 Å to about 250 Å.

14. The method of claim 11 , wherein each of the curing steps used to cure the first, second and third sub-layers involves exposure to UV radiation for less than about 10 minutes.

15. The method of claim 11 , wherein each of the curing steps used to cure the first, second and third sub-layers involves exposure of the sub-layer to UV radiation for a duration of time within the range of about 5 to about 10 minutes.

16. The method of claim 1 , further comprising:

exposing each of the first cured sub-layer and the second cured sub-layer to a further curing step.

17. The method of claim 1 , wherein the semiconductor device is a CMOS device, wherein the first and second sub-layers are disposed over the NMOS region of the CMOS device, and wherein the first and second sub-layers are not disposed over the PMOS region of the CMOS device.

18. The method of claim 1 , wherein the semiconductor device comprises a silicide layer, and wherein the first and second sub-layers are disposed over the silicide layer.

19. The method of claim 1 , wherein the first and second sub-layers of stressor material form a stressor film, and wherein the stressor film has a tensile stress of at least about 1.2 GPa.

20. The method of claim 1 , wherein the first and second sub-layers of stressor material form a stressor film, and wherein the stressor film has a tensile stress of at least about 1.4 GPa.

21. The method of claim 1 , wherein the first and second sub-layers of stressor material form a stressor film, and wherein the stressor film has a tensile stress of at least about 1.5 GPa.

22. A method for making a semiconductor device, comprising:

providing a semiconductor structure equipped with first and second gate structures and channel regions, said channel regions being associated with the gate structures;

depositing a first sub-layer of a stressor material over the semiconductor structure, said stressor material containing silicon-nitrogen bonds and imparting tensile stress to the semiconductor structure;

curing the first stressor material through exposure to a UV radiation source;

depositing a second sub-layer of the stressor material over the first sub-layer;

curing the second sub-layer of stressor material through exposure to a UV radiation source;

depositing a third sub-layer of a third stressor material between the first and second gate structures and in contact with the second sub-layer;

curing the third stressor material through exposure to a radiation source;

depositing a fourth sub-layer of a fourth stressor material between the first and second gate structures and in contact with the third sub-layer; and

curing the fourth stressor material through exposure to radiation source.

Assignments (26)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE PREVIOUSLY RECORDED AT REEL: 040632 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Sep 21, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 044209/0047 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 040632/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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