Liquid resin composition for electronic components and electronic component device
View Patent ↗The present invention provides a liquid resin composition for electronic components, which is excellent in migration resistance and also superior in formability and reliability, as well as an electronic component device sealed therewith, and relates to a liquid resin composition for electronic components, which comprises (A) an epoxy resin, (B) a cyclic acid anhydride which is liquid at ordinary temperature and has an acid anhydride equivalent of 200 or more, and (C) a coupling agent.
1. A liquid resin composition for electronic components, which comprises (A) an epoxy resin, (B) a cyclic acid anhydride which is liquid at 25° C. and has an acid anhydride equivalent ((molecular weight of the acid anhydride)/(number of acid anhydride groups in the acid anhydride molecule)) of 200 or more, (C) a coupling agent, and (D) a silicone-modified epoxy resin, said silicone-modified epoxy resin (D) having been obtained as a reaction product between (i) an organosiloxane having a functional group reacting with an epoxy group and (ii) an epoxy group.
2. The liquid resin composition for electronic components according to claim 1 , further comprising an inorganic filler, wherein the amount of the inorganic filler compounded is 10% by mass or less.
3. The liquid resin composition for electronic components according to claim 1 , which further comprises rubber particles.
4. The liquid resin composition for electronic components according to claim 1 , which further comprises an ion-trapping agent.
5. The liquid resin composition for electronic components according to any one of claims 1 - 3 and 4 , which further comprises a latent curing accelerator for accelerating the reaction between (A) and (B).
6. The liquid resin composition for electronic components according to any one of claims 1 - 3 and 4 , which is used for an electronic component device comprising an electronic component bump-bonded directly onto an interconnection substrate having a film as a base material.
7. An electronic component device sealed with the liquid resin composition for electronic components according to any one of claims 1 - 3 and 4 .
8. The liquid resin composition for electronic components according to claim 1 , which further comprises rubber particles and an ion trapping agent.
9. The liquid resin composition for electronic components according to claim 8 , which further comprises a latent curing accelerator for accelerating the reaction between (A) and (B).
10. The liquid resin composition for electronic components according to claim 8 , which is used for an electronic component device comprising an electronic component bump-bonded directly onto an interconnection substrate having a film as a base material.
11. An electronic component device sealed with the liquid resin composition for electronic components according to claim 8 .
12. The liquid resin composition for electronic components according to claim 5 , which is used for an electronic component device comprising an electronic component bump-bonded directly onto an interconnection substrate having a film as a base material.
13. An electronic component device sealed with the liquid resin composition for electronic components according to claim 5 .
14. The liquid resin composition for electronic components according to claim 1 , wherein said acid anhydride equivalent of said cyclic acid anhydride (B) is 200 to 400.
15. The liquid resin composition for electronic components according to claim 1 , wherein said acid anhydride equivalent of said cyclic acid anhydride (B) is 200 to 300.
16. The liquid resin composition for electronic components according to claim 1 , wherein said cyclic acid anhydride (B) is selected from the group consisting of trialkyl tetrahydrophthalic anhydride and dodecenyl succinic anhydride.
17. The liquid resin composition for electronic components according to claim 1 , wherein said cyclic acid anhydride (B) contains no halogen atoms or ester linkages.
18. The liquid resin composition for electronic components according to claim 4 , wherein said ion-trapping agent comprises a hydrotalcite represented by
Mg 1-x Al x (OH) 2 (CO 3 ) x/2 ·mH 2 O,
where 0<x≦0.5, and m is a positive number.
19. The liquid resin composition for electronic components according to claim 18 , wherein an amount of the hydrotalcite is 0.1 to 3.0 mass % based on the liquid resin composition.
20. The liquid resin composition for electronic components according to claim 1 , wherein said epoxy resin is a mixture of bisphenol F epoxy resin and naphthalene epoxy resin.
21. The liquid resin composition for electronic components according to claim 16 , wherein said acid anhydride equivalent of said cyclic acid anhydride (B) is 200 to 400.
22. The liquid resin composition according to claim 16 , wherein the weight-average molecular weight of the organosiloxane is in a range of 500 to 5,000.
23. The liquid resin composition according to claim 1 , wherein the weight-average molecular weight of the organosiloxane is in a range of 500 to 5,000.
24. The liquid resin composition for electronic components according to claim 20 , wherein said cyclic acid anhydride (B) is selected from the group consisting of trialkyl tetrahydrophthalic anhydride and dodecenyl succinic anhydride.