Method to minimize the impact of shunt currents through aqueous based coolants on PEM fuel cell bipolar plates
A fuel cell includes a first valve metal flow field plate. The first valve metal flow field plate has a first cooling channel adapted to receive an aqueous coolant and to contact the aqueous coolant at a position that inhibits the formation of shunt currents when the fuel cell is incorporated in a fuel cell stack. A field assembly includes a first metal flow field plate having a first cooling channel adapted to receive an aqueous coolant is also provided. A valve metal plate is disposed over the first metal flow field plate in the flow field assembly. Fuel cell stacks using the valve metal-containing flow field plates are also provided.
1. A fuel cell for inclusion in a fuel cell stack having a wet end, the fuel cell comprising:
a first valve metal flow field plate, the first valve metal flow field plate adapted to be positioned at the wet end of the fuel cell stack, the first valve metal flow field plate having a first cooling channel adapted to receive an aqueous coolant and an inlet port;
a precious metal layer disposed over a portion of the first valve metal flow field plate only in the vicinity of the inlet port;
a first catalyst layer disposed over the first valve metal flow field plate;
a first ion conductor layer disposed over the first catalyst layer;
a second catalyst layer disposed over the first ion conductor layer; and
a second flow field plate disposed over the second catalyst layer, the second flow field plate comprising stainless steel.
2. The fuel cell of claim 1 wherein the valve metal is selected from the group consisting of titanium, tantalum, niobium, and alloys thereof.
3. The fuel cell of claim 1 wherein the valve metal is titanium.
4. The fuel cell of claim 1 wherein the first valve metal flow field plate contacts the aqueous coolant at a position proximate to an entrance to the first cooling channel.
5. The fuel cell of claim 1 wherein the precious metal layer includes a precious metal selected from the group consisting of platinum, palladium, gold, and combinations thereof.
6. The fuel cell of claim 5 wherein the precious metal is gold.
7. The fuel cell of claim 1 wherein the precious metal layer has a thickness of 5 to 50 nm.
8. A fuel cell stack comprising the fuel cell of claim 1 .
9. A fuel cell for inclusion in a fuel cell stack having a wet end, the fuel cell comprising:
a first metal flow field plate, the first metal flow field plate having a first cooling channel adapted to receive an aqueous coolant and an inlet port;
a valve metal plate disposed over the first metal flow field plate, the valve metal plate adapted to be positioned at the wet end of a fuel cell stack;
a precious metal layer disposed over a portion of the valve metal plate only in the vicinity of the inlet port;
a first catalyst layer disposed over the valve metal plate;
a first ion conductor layer disposed over the first catalyst layer;
a second catalyst layer disposed over the first ion conductor layer; and
a second flow field plate disposed over the second catalyst layer.
10. The fuel cell of claim 9 wherein the valve metal is selected from the group consisting of titanium, tantalum, niobium, and alloys thereof.
11. The fuel cell of claim 9 wherein the valve metal is titanium.
12. The fuel cell of claim 9 wherein the precious metal layer includes a precious metal selected from the group consisting of platinum, palladium, gold, and combinations thereof.
13. The fuel cell of claim 12 wherein the precious metal is gold.
14. The fuel cell of claim 9 wherein the precious metal layer has a thickness of 5 to 50 nm.
15. The fuel cell of claim 9 wherein the valve metal plate contacts the aqueous coolant at a position proximate to an entrance to the first cooling channel.
16. A fuel cell stack comprising the fuel cell of claim 9 .
17. A fuel cell stack having a wet end, the fuel cell stack comprising:
a first fuel cell assembly comprising:
a first end plate assembly comprising a valve metal, the first end plate assembly adapted to be positioned at the wet end of the fuel cell stack and having a first end plate cooling channel and an inlet port;
a precious metal layer disposed over a portion of the valve metal only in the vicinity of the inlet port;
a first diffusion layer disposed over the first end plate assembly;
a first catalyst layer disposed over the first diffusion layer;
a first ion conductor layer disposed over the first catalyst layer;
a second catalyst layer disposed over the first ion conductor layer;
a second diffusion layer disposed over the second catalyst layer; and
a first bipolar plate disposed over the second diffusion layer;
a plurality of intermediate fuel cell assemblies, each intermediate fuel cell comprising:
a first intermediate fuel cell bipolar plate;
a first intermediate diffusion layer disposed over the first intermediate fuel cell bipolar plate;
a first intermediate catalyst layer disposed over the first intermediate diffusion layer;
a intermediate fuel cell ion conductor layer disposed over the first intermediate catalyst layer;
a second intermediate catalyst layer disposed over the intermediate fuel cell ion conductor layer;
a second intermediate diffusion layer disposed over the second intermediate catalyst layer; and
a second intermediate fuel cell bipolar plate disposed over the second diffusion layer,
a last fuel cell assembly comprising:
a last bipolar plate;
a first last cell diffusion layer disposed over the last bipolar plate;
a first last cell catalyst layer disposed over the first diffusion layer;
a last ion conductor layer disposed over the first diffusion layer;
a second last cell catalyst layer disposed over the last ion conductor layer;
a second last cell diffusion layer disposed over the second catalyst layer; and
a last end plate disposed over the second diffusion layer, the last end plate having a last end plate cooling channel; and
a cooling system in communication with the first end plate cooling channel and the last end plate cooling channel.
18. The fuel cell stack of claim 17 wherein the valve metal is selected from the group consisting of titanium, tantalum, niobium, and alloys thereof.
19. The fuel cell stack of claim 17 wherein the precious metal layer has a thickness of 5 to 50 nm.
20. The fuel cell stack of claim 17 wherein the precious metal layer comprises a component selected from the group consisting of platinum, palladium, gold, and combinations thereof.
21. The fuel cell stack claim 17 wherein the first end plate assembly comprises a flow field plate.
22. The fuel cell stack of claim 21 wherein the flow field plate comprises the valve metal.
23. The fuel cell stack of claim 22 wherein the first end plate assembly comprises a valve metal plate contacting the flow field plate.
24. The fuel cell stack of claim 17 wherein the cooling system provides an aqueous coolant to the first end plate cooling channel, intermediate bipolar plate cooling channel(s), the last end plate cooling channel, and the last end plate cooling channel.