Plasma etching method
This invention relates to a method for conducting an etching process which uses a plasma of a process gas. This etching process is conducted on a wafer W including a substrate 101 , an underlying film 102, 103 formed on the substrate, and a film 104 to be etched that is formed on the underlying film. A main etching gas formed up of a chlorine-containing gas and an oxygen-containing gas, and a nitrogen-containing gas are used as the process gas. In this etching method, etching is conducted under a condition that an N 2 + /N 2 intensity ratio of N 2 + to N 2 , derived from emission spectra of the plasma, is at least 0.6.
1. An etching method comprising the steps of:
providing an object including a substrate, an underlying film made of a silicon-containing film formed on the substrate, and a film to be etched that is made of a tungsten-containing film formed on the underlying film; and
using a plasma of a process gas to carry out an etching process for the object, wherein:
a chlorine-containing gas, an oxygen-containing gas, and a nitrogen-containing gas are used as the process gas to etch the tungsten-containing film under a condition that an N 2 + /N 2 intensity ratio of N 2 + to N 2 , derived from emission spectra of the Plasma, is at least 0.6,
the chlorine-containing gas is a Cl 2 gas, the oxygen-containing gas is an O 2 gas, and the nitrogen-containing gas is an N 2 gas, and
the silicon-containing film is a polysilicon film, and the tungsten-containing film is a tungsten film of a stacked structure of a tungsten nitride film and a tungsten film.
2. The etching method according to claim 1 , wherein:
the plasma is generated by using microwaves.
3. The etching method according to claim 2 , wherein:
the plasma is generated by using the microwaves radiated from a planar antenna.
4. The etching method according to claim 3 , wherein:
the planar antenna is a radial line slot antenna.
5. The etching method according to claim 1 , wherein:
the process gas supplied into a processing vessel is activated to be changed into a plasma by using microwaves radiated from a radial line slot antenna at an electric power of at least 2000 W; and
a ratio of a flow rate of the N 2 gas to a flow rate of the Cl 2 gas is at least 200% in the process gas supplied into the processing vessel.