Method for collection of valuable metal from ITO scrap
View Patent ↗Proposed is a method for collecting valuable metal from an ITO scrap in which a mixture of indium hydroxide and tin hydroxide or metastannic acid is collected by subjecting the ITO scrap to electrolysis in pH-adjusted electrolyte, and roasting this mixture as needed to collect the result as a mixture of indium oxide and tin oxide. This method enables the efficient collection of indium hydroxide and tin hydroxide or metastannic acid, or indium oxide and tin oxide from an ITO scrap of an indium-tin oxide (ITO) sputtering target or an ITO scrap such as ITO mill ends arisen during the manufacture of such ITO sputtering target.
1. A method for collecting valuable metal from an ITO scrap including the steps of subjecting the ITO scrap to electrolysis as an anode and collecting the result as a mixture of indium hydroxide and tin hydroxide or as a mixture of indium hydroxide and metastannic acid.
2. A method for collecting valuable metal from an ITO scrap according to claim 1 , wherein the mixture of indium hydroxide and tin hydroxide or the mixture of indium hydroxide and metastannic acid obtained by electrolysis is roasted to obtain indium oxide and tin oxide, and the result is collected as a mixture of the indium oxide and tin oxide.
3. A method of collecting valuable metal from ITO scrap, comprising the steps of:
arranging a cathode and the ITO scrap as an anode in an electrolytic solution;
after said arranging step, subjecting the ITO scrap to electrolysis in the electrolytic solution and precipitating indium hydroxide (In(OH) 3 ) and tin hydroxide (Sn(OH) 4 ) or precipitating indium hydroxide (In(OH) 3 ) and metastannic acid (H 2 SnO 3 ) during the electrolysis; and
collecting the indium hydroxide (In(OH) 3 ) simultaneously with the tin hydroxide (Sn(OH) 4 ) as a mixture or collecting the indium hydroxide (In(OH) 3 ) simultaneously with the metastannic acid (H 2 SnO 3 ) as a mixture.
4. A method according to claim 3 , further comprising the step of roasting the mixture collected during said collecting step to obtain indium oxide (In 2 O 3 ) simultaneously with tin oxide (SnO 2 ) as a mixture.
5. A method according to claim 4 , wherein a roasting temperature used during said roasting step is in a range of 100 to 500° C.
6. A method according to claim 5 , wherein the roasting temperature used during said roasting step is in a range of 150 to 400° C.
7. A method according to claim 5 , further comprising the step of adjusting pH of the electrolytic solution before the electrolysis to 3 to 11.
8. A method according to claim 7 , further comprising the step of controlling a liquid temperature of the electrolytic solution during the electrolysis within a range of 0 to 100° C.
9. A method according to claim 8 , wherein the ITO scrap consists of 5 to 30 wt % tin oxide and a remainder of indium oxide.
10. A method according to claim 8 , wherein the ITO scrap consists of 9.7 wt % tin oxide and a remainder of indium oxide.
11. A method according to claim 7 , further comprising the step of controlling a liquid temperature of the electrolytic solution during the electrolysis within a range of 20 to 50° C.
12. A method according to claim 5 , further comprising the step of adjusting pH of the electrolytic solution before the electrolysis to 5 to 9.
13. A method according to claim 4 , wherein indium hydroxide (In(OH) 3 ) and tin hydroxide (Sn(OH) 4 ) are precipitated during the electrolysis, are collected during said collecting step, and are roasted during said roasting step.
14. A method according to claim 4 , wherein indium hydroxide (In(OH) 3 ) and metastannic acid (H 2 SnO 3 ) are precipitated during the electrolysis, are collected during said collecting step, and are roasted during said roasting step.