IP Library Granted Patent US 7,947,589
Granted Patent B2
US 7,947,589 · App. 12/552,774 · Granted May 24, 2011

FinFET formation with a thermal oxide spacer hard mask formed from crystalline silicon layer

Assignee: Freescale Semiconductor, Inc.
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Quick Facts
Patent No.
US 7,947,589
App. No.
12/552,774
Granted
May 24, 2011
Kind
B2
Abstract

A semiconductor process and apparatus provide a FinFET device by forming a second single crystal semiconductor layer ( 19 ) that is isolated from an underlying first single crystal semiconductor layer ( 17 ) by a buried insulator layer ( 18 ); patterning and etching the second single crystal semiconductor layer ( 19 ) to form a single crystal mandrel ( 42 ) having vertical sidewalls; thermally oxidizing the vertical sidewalls of the single crystal mandrel to grow oxide spacers ( 52 ) having a substantially uniform thickness; selectively removing any remaining portion of the single crystal mandrel ( 42 ) while substantially retaining the oxide spacers ( 52 ); and selectively etching the first single crystal semiconductor layer ( 17 ) using the oxide spacers ( 52 ) to form one or more FinFET channel regions ( 92 ).

Claims (57)

1. A method for fabricating a semiconductor structure, comprising:

providing a substrate structure comprising a first single crystal semiconductor layer over an underlying first insulator layer, and a second single crystal semiconductor layer over the first single crystal semiconductor layer that is isolated from the first single crystal semiconductor layer by an underlying second insulator layer;

patterning and etching the second single crystal semiconductor layer to form a single crystal patterned structure having vertical sidewalls;

oxidizing the single crystal patterned structure to grow oxide spacers on the vertical sidewalls of the single crystal patterned structure;

selectively removing any remaining portion of the single crystal patterned structure while substantially retaining the oxide spacers; and

selectively etching the first single crystal semiconductor layer using the oxide spacers as a mask to leave one or more FinFET channel regions patterned as per the oxide spacers.

2. The method of claim 1 , where providing the substrate structure comprises providing a double semiconductor-on-insulator substrate structure.

3. The method of claim 1 , where patterning and etching the second single crystal semiconductor layer comprises:

depositing a first hard mask layer over the second single crystal semiconductor layer;

patterning and etching the first hard mask layer to form a mandrel etch mask; and

selectively etching the second single crystal semiconductor layer using the mandrel etch mask to form the single crystal patterned structure having vertical sidewalls.

4. The method of claim 1 , where patterning and etching the second single crystal semiconductor layer comprises:

depositing a first nitride layer over the second single crystal semiconductor layer;

patterning and etching the first nitride layer to form a nitride hard mask on the second single crystal semiconductor layer; and

applying a reactive ion etch to selectively etch the second single crystal semiconductor layer using the nitride hard mask to form the single crystal patterned structure having vertical sidewalls.

5. The method of claim 4 , further comprising removing the nitride hard mask from the second single crystal semiconductor layer after oxidizing the single crystal patterned structure and before selectively removing any remaining portion of the single crystal patterned structure.

6. The method of claim 1 , where selectively removing any remaining portion of the single crystal patterned structure comprises applying a wet etch process to selectively remove any remaining portion of the single crystal patterned structure while substantially retaining the oxide spacers.

7. The method of claim 1 , where selectively removing any remaining portion of the single crystal patterned structure comprises applying a reactive ion etch process to selectively remove any remaining portion of the single crystal patterned structure while substantially retaining the oxide spacers.

8. The method of claim 1 , further comprising selectively removing any remaining portion of the underlying second insulator layer with a reactive ion etch process before selectively etching the first single crystal semiconductor layer.

9. The method of claim 1 , further comprising:

forming a gate layer over the FinFET channel regions, and

selectively etching the gate layer to form one or more gate electrodes over the FinFET channel regions.

10. A method for forming a plurality of FinFET structures on a semiconductor structure, comprising:

providing a substrate structure comprising:

a first crystalline semiconductor substrate layer,

a second crystalline semiconductor layer over at least part of the first semiconductor substrate layer and electrically isolated therefrom by a first insulator layer, and

a third crystalline semiconductor layer over at least part of the second crystalline semiconductor layer and electrically isolated therefrom by a second insulator layer;

selectively etching the third crystalline semiconductor layer to form a plurality of crystalline patterned semiconductor structures having a predetermined minimum pitch;

oxidizing the plurality of crystalline patterned semiconductor structures to grow a plurality of oxide sidewall spacers on the plurality of crystalline patterned semiconductor structures; and

selectively etching the second crystalline semiconductor layer using the plurality of oxide sidewall spacers directly or indirectly as an etch mask to form a plurality of FinFET channel regions having a minimum pitch that is less than the predetermined minimum pitch.

11. The method of claim 10 , where the first crystalline semiconductor layer comprises a bulk semiconductor substrate layer and the second crystalline semiconductor layer comprises an SOI crystalline semiconductor layer.

12. The method of claim 10 , where providing the substrate structure comprises providing a double semiconductor-on-insulator substrate structure.

13. The method of claim 10 , where selectively etching the third crystalline semiconductor layer comprises:

depositing a first hard mask layer over the third crystalline semiconductor layer;

patterning and etching the first hard mask layer to form a mandrel etch mask; and

selectively etching the third crystalline semiconductor layer using the mandrel etch mask to form the plurality of crystalline patterned semiconductor structures having the predetermined minimum pitch.

14. The method of claim 10 , where oxidizing the plurality of crystalline patterned semiconductor structures comprises thermally oxidizing the plurality of crystalline patterned semiconductor structures in a controlled thermal oxidation process to form oxide sidewall spacers, each having a predetermined thickness on the plurality of crystalline patterned semiconductor structures to form the plurality of oxide sidewall spacers.

15. The method of claim 10 , where the plurality of crystalline patterned semiconductor structures are formed to have equal line widths and spaces therebetween.

16. The method of claim 10 , where the plurality of FinFET channel regions are formed to have a thickness of about 8-10 nanometers.

17. The method of claim 10 , where selectively etching the third crystalline semiconductor layer comprises:

depositing a first nitride layer over the third crystalline semiconductor layer;

patterning and etching the first nitride layer to form a nitride hard mask on the third crystalline semiconductor layer; and

applying a reactive ion etch to selectively etch the third crystalline semiconductor layer using the nitride hard mask to form the plurality of crystalline patterned semiconductor structures having vertical sidewalls.

18. The method of claim 17 , further comprising removing the nitride hard mask from the third crystalline semiconductor layer after oxidizing the plurality of crystalline patterned semiconductor structures and before selectively etching the second crystalline semiconductor layer.

19. The method of claim 10 , further comprising

forming a gate insulator layer over the plurality of FinFET channel regions;

forming a conductive gate layer over the gate insulator layer; and

selectively etching the conductive gate layer to form a one or more FinFET gate electrodes.

20. A method for forming a FinFET structure, comprising:

providing a double semiconductor-on-insulator (SOI) substrate comprising a monocrystalline top SOI layer and a monocrystalline bottom SOI layer;

patterning and etching the monocrystalline top SOI layer to form an etch mask comprising a plurality of monocrystalline dummy structures having a predetermined minimum pitch;

thermally oxidizing the plurality of monocrystalline dummy structures to form uniform oxide sidewall spacers;

removing any remaining portion of the plurality of monocrystalline dummy structures while substantially retaining the uniform oxide sidewall spacers;

selectively etching the monocrystalline bottom SOI layer using the uniform oxide sidewall spacers as an etch mask to form a plurality of FinFET channel regions having a minimum pitch that is less than the predetermined minimum pitch;

forming a gate insulator layer over the plurality of FinFET channel regions;

forming a conductive gate layer over the gate insulator layer; and

selectively etching the conductive gate layer to form one or more FinFET gate electrodes.

Assignments (16)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE PREVIOUSLY RECORDED AT REEL: 040632 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Sep 21, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 044209/0047 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 040632/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0854 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded Feb 3, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A.
Reel/Frame 023882/0834 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 2, 2009
From: KHATER, MARWAN H.
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 023184/0935 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 2, 2009
From: MURALIDHAR, RAMACHANDRAN
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 023184/0909 →
Continuity (1)
Related Publication 20110053361A1 · Mar 3, 2011